Content area

Abstract

Chemically cross-linked composite gels based on bentonite clay from Manyrak deposit (Kazakhstan Republic) and nonionic polymers, i.e., poly(hydroxyethylacrylate) and poly(acrylamide), were polymerized in situ after preliminary intercalation of monomers in an aqueous suspension of bentonite clay. By means of cryo-scanning electron microscopy, it was shown that bentonite clay is well incorporated into the gel network structure with pore sizes up to 1.5 [mu]m. The intercalated bentonite clay can adsorb cationic surfactants as well as heavy metal ions due to electrostatic interactions. Conductometric and surface tension measurements indicate not only the adsorption of surfactants and heavy metals inside the hydrogel, but also the displacement of the critical micellization concentration (CMC) of the surfactants.

Details

Title
Interactions of bentonite clay in composite gels of non-ionic polymers with cationic surfactants and heavy metal ions
Author
Beisebekov, M M; Serikpayeva, S B; Zhumagalieva, Sh N; Beisebekov, M K; Abilov, Zh A; Kosmella, S; Koetz, J
Pages
633-639
Publication year
2015
Publication date
Feb 2015
Publisher
Springer Nature B.V.
ISSN
0303402X
e-ISSN
14351536
Source type
Scholarly Journal
Language of publication
English
ProQuest document ID
1663763947
Copyright
Springer-Verlag Berlin Heidelberg 2015