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Abstract
Optoelectronic memory plays a vital role in modern semiconductor industry. The fast emerging requirements for device miniaturization and structural flexibility have diverted research interest to two-dimensional thin layered materials. Here, we report a multibit nonvolatile optoelectronic memory based on a heterostructure of monolayer tungsten diselenide and few-layer hexagonal boron nitride. The tungsten diselenide/boron nitride memory exhibits a memory switching ratio approximately 1.1 × 106, which ensures over 128 (7 bit) distinct storage states. The memory demonstrates robustness with retention time over 4.5 × 104 s. Moreover, the ability of broadband spectrum distinction enables its application in filter-free color image sensor. This concept is further validated through the realization of integrated tungsten diselenide/boron nitride pixel matrix which captured a specific image recording the three primary colors (red, green, and blue). The heterostructure architecture is also applicable to other two-dimensional materials, which is confirmed by the realization of black phosphorus/boron nitride optoelectronic memory.
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Details

1 Department of Chemistry, National University of Singapore, Singapore, Singapore; Centre for Advanced 2D Materials and Graphene Research Centre, National University of Singapore, Singapore, Singapore
2 Centre for Advanced 2D Materials and Graphene Research Centre, National University of Singapore, Singapore, Singapore; Department of Physics, National University of Singapore, Singapore, Singapore
3 State Key Laboratory of Luminescence and Applications, Changchun Institute of Optics, Fine Mechanics and Physics, Chinese Academy of Sciences, Changchun, People’s Republic of China
4 Centre for Advanced 2D Materials and Graphene Research Centre, National University of Singapore, Singapore, Singapore
5 Institute of Materials Research and Engineering (IMRE), Singapore, Singapore
6 Department of Chemistry, National University of Singapore, Singapore, Singapore; Centre for Advanced 2D Materials and Graphene Research Centre, National University of Singapore, Singapore, Singapore; Department of Physics, National University of Singapore, Singapore, Singapore; National University of Singapore (Suzhou) Research Institute, Jiang Su, China