Abstract

Addition of Lanthanide shift reagents Pr(fod)3 to 2-hydroxynaphthylideneaniline in non polar solvents and slightly polar solvent showed for the first time a keto-enol tautomerism. KT values= ([keto]/[enol]) were calculated in the chosen solvents. KT at fixed con centration of the shift reagent was determined at different temperatures and the thermodynamic parameters (?H0,??G0, ?S0) were obtained.

Details

Title
Keto- Enol Tautomerism Of 2-Hydroxy Naphthylideneaniline With Lanthanide Shift Reagent Pr(Fod)3 In Different Solvents
Author
Saleem, L M N; Sultan, R H
Pages
1189-1193
Publication year
2012
Publication date
2012
Publisher
Oriental Scientific Publishing Company
ISSN
0970020X
e-ISSN
22315039
Source type
Scholarly Journal
Language of publication
English
ProQuest document ID
2121996410
Copyright
© 2012. This work is published under http://creativecommons.org/licenses/by-nc-sa/4.0/ (the “License”). Notwithstanding the ProQuest Terms and Conditions, you may use this content in accordance with the terms of the License.