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Abstract
It is shown that for all the essential bond forming and bond breaking reactions on metal surfaces, the reactivity of the metal surface correlates linearly with the reaction energy in a single universal relation. Such correlations provide an easy way of establishing trends in reactivity among the different transition metals.
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Title
Universal Brønsted-Evans-Polanyi Relations for C–C, C–O, C–N, N–O, N–N, and O–O Dissociation Reactions
Author
Wang, Shengguang 1 ; Temel, Burcin 2 ; Shen, Juan 1 ; Jones, Glenn 1 ; Grabow, Lars C 1 ; Studt, Felix 3 ; Bligaard, Thomas 1 ; Abild-Pedersen, Frank 3 ; Christensen, Claus H 2 ; Nørskov, Jens K 4
1 Center for Atomic-Scale Materials Design, Department of Physics, Technical University of Denmark, Lyngby, Denmark
2 Lyngby, Denmark
3 Center for Atomic-Scale Materials Design, Department of Physics, Technical University of Denmark, Lyngby, Denmark; SUNCAT Center for Interface Science and Catalysis, SLAC National Accelerator Laboratory, Menlo Park, CA, USA
4 Center for Atomic-Scale Materials Design, Department of Physics, Technical University of Denmark, Lyngby, Denmark; SUNCAT Center for Interface Science and Catalysis, SLAC National Accelerator Laboratory, Menlo Park, CA, USA; Department of Chemical Engineering, Stanford University, Stanford, CA, USA
1 Center for Atomic-Scale Materials Design, Department of Physics, Technical University of Denmark, Lyngby, Denmark
2 Lyngby, Denmark
3 Center for Atomic-Scale Materials Design, Department of Physics, Technical University of Denmark, Lyngby, Denmark; SUNCAT Center for Interface Science and Catalysis, SLAC National Accelerator Laboratory, Menlo Park, CA, USA
4 Center for Atomic-Scale Materials Design, Department of Physics, Technical University of Denmark, Lyngby, Denmark; SUNCAT Center for Interface Science and Catalysis, SLAC National Accelerator Laboratory, Menlo Park, CA, USA; Department of Chemical Engineering, Stanford University, Stanford, CA, USA
Pages
370-373
Publication year
2011
Publication date
Mar 2011
ISSN
1011372X
e-ISSN
1572879X
Source type
Scholarly Journal
Language of publication
English
ProQuest document ID
2258921084
Copyright
Catalysis Letters is a copyright of Springer, (2010). All Rights Reserved.