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© 2017. This work is published under http://creativecommons.org/licenses/by/3.0/ (the “License”). Notwithstanding the ProQuest Terms and Conditions, you may use this content in accordance with the terms of the License.

Abstract

Since January 2004, the planetary Fourier spectrometer (PFS) on board the Mars Express satellite has been recording near-infrared limb spectra of high quality up to the tangent altitudes 150 km, with potential information on density and thermal structure of the upper Martian atmosphere. We present first results of our modeling of the PFS short wavelength channel (SWC) daytime limb spectra for the altitude region above 90 km. We applied a ro-vibrational non-LTE model based on the stellar astrophysics technique of accelerated lambda iteration (ALI) to solve the multi-species and multi-level CO2 problem in the Martian atmosphere. We show that the long-standing discrepancy between observed and calculated spectra in the cores and wings of 4.3 µm region is explained by the non-thermal rotational distribution of molecules in the upper vibrational states 10011 and 10012 of the CO2 main isotope second hot (SH) bands above 90 km altitude. The redistribution of SH band intensities from band branch cores into their wings is caused (a) by intensive production of the CO2 molecules in rotational states with j>30 due to the absorption of solar radiation in optically thin wings of 2.7 µm bands and (b) by a short radiative lifetime of excited molecules, which is insufficient at altitudes above 90 km for collisions to maintain rotation of excited molecules thermalized. Implications for developing operational algorithms for massive processing of PFS and other instrument limb observations are discussed.

Details

Title
Evidence of a significant rotational non-LTE effect in the CO2 4.3 µm PFS-MEX limb spectra
Author
Kutepov, Alexander A 1 ; Rezac, Ladislav 2 ; Feofilov, Artem G 3   VIAFID ORCID Logo 

 Space Weather Laboratory, NASA Goddard Space Flight Center, Greenbelt, MD, USA; Physics Department, The Catholic University of America, Washington, D.C., USA 
 Department of Planets and Comets, Max-Planck-Institut für Sonnensystemforschung, Justus-von-Liebig-Weg 3, 37077 Göttingen, Germany 
 Laboratoire de Météorologie Dynamique, IPSL/CNRS, UMR8539, Ecole Polytechnique, Paris, France 
Pages
265-271
Publication year
2017
Publication date
2017
Publisher
Copernicus GmbH
ISSN
18671381
e-ISSN
18678548
Source type
Scholarly Journal
Language of publication
English
ProQuest document ID
2414426010
Copyright
© 2017. This work is published under http://creativecommons.org/licenses/by/3.0/ (the “License”). Notwithstanding the ProQuest Terms and Conditions, you may use this content in accordance with the terms of the License.