Effects of Nanofilled Particle Forms and Dispersion Modes on Properties of Carbon-Based Energy Storage Composites

Abstract

How to improve the thermal conductivity of phase change materials (PCMs) is always the key to thermal control technology. At present, the thermal conductivity of PCMs has two ways to improve: one is to fill the matrix with high thermal conductivity and the other is to fill nanoparticles. After combining the two methods, the choice of filled nano-SiO₂, carbon nanotubes (CNTs), or graphene (GNPs) has different effects on the performance of carbon-based energy storage composites. Filling paraffin with foamed carbon increased the thermal conductivity of pure paraffin from 0.25 W/(m·K) to 8.3083 W/(m·K), an increase of 33.2 times. When the nanoparticle mass fraction is 5%, the enthalpy of GNP composites is 10 J·g^-1 less than that of SiO₂ composites. Under the same mass fraction, compared with the thermal conductivity enhancement effect of SiO₂ composites, the thermal conductivity increase effects of CNTs and GNP composites are 6.7 and 15.8 times the thermal conductivity increase of SiO₂ composites, respectively. The comparison of theoretical and experimental values shows that different nanoparticle forms and dispersion modes have different effects on the performance of carbon-based energy storage composites, among which GNPs have the greatest improvement in the thermal conductivity of carbon-based composites.

This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

1. Instruction

Phase change energy storage materials are the basis of research on phase change energy storage technology [1, 2]. The selection of appropriate PCMs is of paramount importance. At present, paraffin with the advantages of chemical stability, no overcooling, no toxicity, high latent heat of phase change, cheapness, etc. has become a common PCM. However, paraffin has problems such as low thermal conductivity during the phase change process, which makes it poor in thermal conductivity. It cannot crystallize and release heat in time at the phase change temperature, which affects the performance of the phase change thermal control system. Seriously, it can even cause thermal control system failure [3].

Therefore, an important basic research work on energy storage technology is the development of phase change energy storage materials [4]. Using nanoparticles to fill phase change materials has made many achievements in improving thermal conductivity now. The first method is to fill the nanoparticles with PCMs [5, 6]. Amin et al. [7] studied the effect of nanoparticles on the physical and thermal properties of materials. DSC analysis showed that the latent heat of 0.3 wt.% beeswax/GNP increased by 22.5%. The thermal conductivity of 0.3 wt.% beeswax/GNP is 2.8 W/(m·K). The latent heat and thermal conductivity of beeswax were improved by the presence of GNP nanoflakes. Therefore, beeswax/GNP has the potential to reduce building energy consumption. Jesumathy et al. [8] designed an energy storage system using embedded nano copper oxide (CuO) particles to study the thermal properties of paraffin. In this study, 40 nm CuO particles with average particle sizes of 2%, 5%, and 10% are dispersed in PCMs. The results show that with the increase of the mass fraction of CNEPs, the thermal conductivity increases by 6.7% and 7.8% in the liquid state and 5.14% and 30% in the dynamic viscosity. The thermal conductivity of composite materials is increased by 1.3 times. At the maximum flow rate, the heat transfer coefficient during solidification increased by about 78%. This shows that adding copper oxide nanoparticles to paraffin promotes conduction and natural convection very effectively in composites and paraffin. The second method is to fill PCMs into a highly thermally conductive matrix (such as graphite foam (CF20) [9, 10], “vascular” resin-based composites [11]). Huang et al. [12] prepared a myristyl alcohol (MA)/metal foam composite phase change material by vacuum infiltration. MA is used as phase change material, and metal foam is used as a skeleton. Comparisons are made using foamed nickel and copper foam. The influence of the pore size of foam metal on its thermal properties is analyzed. Compared with pure MA, the latent heat of fusion of metal foam composite phase change materials (CPCMs) is reduced by 3-29%. In addition, the composite material has good thermal stability and the foam metal has a good adsorption effect on PCM. The thermal conductivity of the composite is tested with a thermal conductivity meter (TCM), and the results show that the MA/foam metal composite has good thermal conductivity. Both of the above methods have effectively improved the performance of PCMs.

The combined use of the two methods synergistically increases the thermal conductivity of composite PCM [13]. Nada et al. [14] added multiwalled CNTs to a paraffin-CF20 matrix to achieve a synergistic increase in thermal conductivity. However, little research has been done on the effect of nanoparticles in different particle forms on the thermal conductivity of composite PCMs. The mechanism by which nanoparticles enhance synergistic PCM thermal conductivity is still unclear. Here, we explore this scientific issue by analyzing the effect of nanoparticle form and dispersion on the thermal conductivity of composite PCMs. It is found that under the same mass fraction, the solidification and melting enthalpy of SiO₂ composite and GNP composite are different and that SiO₂, CNTs, and GNPs have very different thermal conductivity enhancement of the composite, and with the increase of the content, the increase in the respective thermal conductivity is also significantly different. Therefore, under the same mass fraction, the different particle forms and dispersion modes of the nanoparticles will have a great impact on the change of the thermal conductivity of the composite material, which will serve as a reference for future research.

2. Materials

After the paraffin with purity of 99% is melted, 0 wt.%, 0.5 wt.%, 1 wt.%, 2 wt.%, and 5 wt.% nanoparticles are filled therein, and the modified PCM is obtained by shaking and mixing uniformly. The template method is used to prepare porous foamed carbon with a porosity of 85% and an average pore size of 400 μm. The modified paraffin is well impregnated into CF20 under the vacuum and the adsorption of the foamed carbon pores, and the paraffin-nanoparticles are prepared by solidification of CF20 samples, namely, shaped phase change energy storage composites.

The relevant parameters of the selected nanomaterials are shown in Table 1.

Table 1

Selected materials and material data.

Material	The average particle size (nm)	Purity	Particle shape	Loose density (g·cm-3)	Density (g·cm-3)
Nano-SiO2	15	99.5%	Spherical	0.05	2.2
CNTs	15	99.5%	Chain	0.05	2.2
GNPs	5 μm	≥99.5%	Two-dimensional flake	$$0.065\pm 0.020$$	2.0

The dispersion of nanoparticles is characterized by field emission scanning electron microscopy. The thermal conductivity of the composite is measured by the laser method. Nanoparticle materials are mixed with each other evenly.

3. Results and Discussion

3.1. Effect of Particle Form on Properties of Carbon-Based Composites

The effect of nanoparticle form on the properties of paraffin-CF20 composites is mainly reflected in thermal conductivity and solidification melting enthalpy. Figure 1(a) shows that the microstructure of SiO₂ is mainly spherical. CNTs are mainly two-dimensional tubular structures in Figure 1(b). Theoretically, heat flow will rapidly propagate in the radial direction of the nanotube, similar to the rapid transmission of current along the direction of copper wires with low resistance.

[figures omitted; refer to PDF]

GNP has a sheet structure with wrinkles in Figure 1(c). Compared to CNTs, both the front and back of GNPs are in contact with a large number of GNP molecules, which greatly reduces the contact thermal resistance. The GNPs normally will wrinkle in the composites [15, 16]. GNP is easy to form a connected network structure in PCM and has good dispersion, which helps to improve the thermal conductivity of the composite. The direction of high thermal conductivity of GNPs is along the layer extension direction. This means that heat can be transferred quickly on GNPs, which greatly improves thermal conductivity. But in fact, although their theoretical thermal conductivity is very high, the thermal conductivity measured after filling with paraffin/CF20 (uniform) is not as high as expected. One of the reasons is the difference in particle form. In order to illustrate the effect of particle form on thermal conductivity, MD (molecular dynamics) simulations are performed.

First, a paraffin molecular model is established, as shown in Figure 2. The melting point of paraffin is 58-60°C. Therefore, C₂₇H₅₆, an alkane with a carbon number of 27, is created as a simulation molecule in the material studio, with a space volume of $35\text{Å}\ast 5\text{Å}\ast 5\text{Å}$.

[figure omitted; refer to PDF]

Then, Packmol software was used to create a box of appropriate size to fill the molecules. For paraffin molecules, the appropriate box is a 5 nm cube unit cell (both the length, the width, and the height are greater than the original molecules). When creating a mixture system, the nanoparticles should be first created in a certain area in this cubic space; the experiments done this time are rectangular coordinate systems, and the nanoparticles are placed in the center area of the entire cubic unit cell.

After the crystal cell box is determined, the density of C₂₇H₅₆ is 0.88 g/cm³, so the number of paraffin molecules in the 5 nm cube of the solid is calculated: $$\begin{array}{}\text{(1)}& N=\frac{880\times {\left(5\times {10}^{-9}\right)}^3}{1.66\ast {10}^{-27}\times 380}\approx 174.\end{array}$$

In this paper, the hot wire method is used to measure the thermal conductivity when the test piece is solid, and when PCM melts into liquid, the flow of liquid will greatly improve the thermal conductivity, which is beyond the scope of micro heat transfer simulation. Therefore, this paper uses the molecular dynamics of solid paraffin to simulate.

Building nanoparticle models was continued, as shown in Figure 3.

[figures omitted; refer to PDF]

To build a 5 nm cube, it needs to extend in the $X$-direction again. CNTs or GNP molecular crystal nanoparticles have a length of more than 30 Å. In order to avoid molecules exceeding the box size in subsequent experiments, the simulation box size must be expanded to $150\text{Å}\ast 50\text{Å}\ast 50\text{Å}$.

The mixture model is obtained after extension, as shown in Figure 4.

[figure omitted; refer to PDF]

The two sides of the simulated box are, respectively, equipped with a constant temperature heat source and constant temperature cold source. The heat of particles simulated by this nonequilibrium state will be transferred along the $X$-direction, generating an irreversible heat flow. To calculate such directional heat flow, use the definition of thermal conductivity of Fourier [17, 18]: $$\begin{array}{}\text{(2)}& k=-\frac{1}{V_c}\frac{Q\left(\omega \right)}{\nabla T}=-\frac{Jx}{\partial T/\partial x}=\frac{\varphi A}{\left(T_h-T_1\right)/Lx},\end{array}$$where $J$ is the heat flow density in the $X$-direction, $T$ is the temperature, $Lx$ is the thickness, $\varphi$ is the heat flow, and $A$ is the cross-sectional area perpendicular to the heat flow.

The thermal conductivity of the previously created box is simulated in Lammps with an integration step of 0.5 timesteps and a total time of 2000000 timesteps. The simulation temperature of the PCM is 300 K (solid state) at room temperature. After 500000 timesteps, the calculated thermal conductivity tended to be stable, which proved that the relaxation equilibrium particle energy method with 500000 timesteps is feasible. According to the calculation of 2000000 timesteps, the thermal conductivity of paraffin is 0.1306 W/(m·K), and that of CNTs and GNPs is 0.2733 W/(m·K) and 0.3425 W/(m·K) at 5 wt.%, respectively.

A hot area is set on the left side of the simulation box, and a cold area is set on the right side. The temperature distribution will not converge if the temperature difference is too low. In this simulation, the temperature difference between the left and right sides is 85 K, the left side is 190.8 K, and the right side is 115.5 K. Paraffin can maintain solid shape at this temperature, and the system temperature tends to be stable after 2000000 timesteps.

The results of thermal conductivity obtain by applying a heat source at one end are simulated in Figure 5.

[figure omitted; refer to PDF]

The simulated paraffin-GNP thermal conductivity is 1.5 times the thermal conductivity of paraffin-CNTs and 2.5 times the thermal conductivity of paraffin-SiO₂ at 5 wt.%, indicating that the specific particle form affects the thermal conductivity of paraffin-nanoparticles.

On the other hand, the filling of nanoparticles also affects the phase change enthalpy of PCMs during solidification and melting. The traditional nucleation theory [19, 20] is based on the Gibbs theory which describes the formation of new phases in a homogeneous single phase. This theory has been successful in explaining many experimental phenomena.

Critical nucleus radius $r\ast =2\sigma M/\rho RT\ln \left(c/c_0\right)$, and nucleation energy $\Delta G\ast =16{\pi \sigma }^3{M}^2/3R^2{T}^2{\rho }^2\left(\ln c/c_0\right)$. It shows that different particles have different molar masses $M$, different saturation concentrations $c_0$, and different densities. The required nucleation energies are also different. Relatively, the enthalpy of the composite PCM during solidification or melting will be changed. Here, we compare the enthalpy values of SiO₂ and GNP fill composites with the same mass fraction to illustrate the effect of different particle forms on the performance of composite phase change energy storage materials.

In the DSC curve, the upper curve is the material melting process, and the lower curve is the material solidification process. The “pure” in the icon represents pure PCM, and the percentage represents the composite phase change material containing the nanoparticles of the mass fraction. The melting enthalpy of pure paraffin is 207.2 J/g, and the enthalpy of solidification is 206.0 J/g. Figures 6(a) and 6(b) show that the melting enthalpy and solidification enthalpy of the GNP-filled composites are the smallest, respectively, 176.2 J/g and 178.9 J/g.

[figures omitted; refer to PDF]

Figures 6(c) and 6(d) show the DSC curves of the paraffin-nanoparticle-GNP samples and the composite PCM still maintain good melt-solidification properties. With the addition of CF20, the phase change latent heat of the sample is significantly reduced, and with the increase of nanoparticle content, the phase change latent heat further decreases. Without nanoparticles, the melting enthalpy of the paraffin-CF20 samples is 155.6 J/g, and the freezing enthalpy is 153.1 J/g. After adding nanoparticles, the melting enthalpy and solidification enthalpy of the composites filled with GNPs are the lowest, which are 146.3 J/g and 145.9 J/g, respectively.

The results show that when paraffin is filled into CF20, the enthalpy of the composite energy storage material is reduced by about 50 J/g, because CF20 does not participate in energy storage. Similarly, after filling nano-SiO₂ and GNPs, the enthalpy of the composite material will also be reduced, but when the mass fraction is 5%, the enthalpies of paraffin-GNPs-CF20 are lower than the two; the values are 10 J/g. The paraffin-GNPs-CF20 enthalpy decreases even more. This is because when the composite PCM is solidified, the nanoparticles will crystallize and need to absorb energy; when the composite PCM is melted, the nanoparticle crystals disperse and also need to absorb energy. Because the two participate in the process of solidification or melting of PCM, the required nucleation energy is different, and GNPs need more energy to nucleate paraffin.

3.2. Effect of Dispersion Modes on Thermal Conductivity of Carbon-Based Composites

The dispersion of nanoparticles in modified PCM/CF20 under the same mass fraction is mainly reflected in the uneven distribution of particles and the distribution of different particles. In order to explain the effect of the dispersion mode on the thermal conductivity of paraffin-nanoparticle-CF20, we chose the “island-network” thermal conductivity composite model and the Maxwell model [21, 22] to predict the thermal conductivity of the paraffin-nanoparticle-CF20 composite. The “island-network” model equation formula is as follows: $$\begin{array}{}\text{(3)}& \frac{1}{\lambda }=\frac{V}{{\lambda }_{\text{f}}}+\frac{1-V}{{\lambda }_{\text{p}}}.\end{array}$$

In the formula, ${\lambda }_{\text{p}}$ is the thermal conductivity of polymers, ${\lambda }_{\text{f}}$ is the thermal conductivity of filler, $\lambda$ is the thermal conductivity of composite materials, and $V$ is the volume fraction of the particle. For low-filling thermally conductive polymer-based composites, it has no interaction between the fillers and they are distributed in the matrix in the form of “islands,” which is the “island” model.

The Maxwell model formula is as follows: $$\begin{array}{}\text{(4)}& \lambda ={\lambda }_1\frac{{\lambda }_2+2{\lambda }_1+2V{\left({\lambda }_2‐\lambda \right)}_1}{{\lambda }_2+2{\lambda }_1‐V\left({\lambda }_2‐{\lambda }_1\right)}.\end{array}$$

In the formula, ${\lambda }_1$ is the thermal conductivity of polymers, ${\lambda }_2$ is the thermal conductivity of filler, $\lambda$ is the thermal conductivity of composite materials, and $V$ is the volume fraction of the particle. The Maxwell-Eucken model characterizes the thermal conductivity of composites formed by particles that have no interaction with each other and are uniformly dispersed in the matrix. This model is suitable for predicting the thermal conductivity of composites with filler contents below 30 vol.%. The volume of the composite energy storage material is measured to be 50 cm³, the density of paraffin is 0.88 g·cm^-3, the density of foamed carbon is taken to be 2.2 g·cm^-3, and the density of the nanoparticle material is shown in Table 1. The experimental data and prediction data obtained are as follows.

It is clearly seen in Figures 7(a) and 8(a) that the two models are more accurate for predicting the thermal conductivity of nano-SiO₂ composites. However, the predicted values of paraffin-SiO₂-CF20 and paraffin-CNTs-CF20 in Figure 7(b) do not match, and both are higher than the experimental values. The experimental values of paraffin-GNPs-CF20 are higher. This is because the “island-network” model (tandem model) considers that it has no interaction between the fillers and that the distribution is uniform, and it is basically used to predict the lower limit of the thermal conductivity of the composite. Because of the presence of paraffin and CF20 in the composite, the overall structure is more complicated. From the model formula, it shows that with the increase of ${\lambda }_{\text{f}}$ and the decrease of $V/{\lambda }_{\text{f}}$, the predicted value of the thermal conductivity of the composite material will be more biased to the calculation result of $1‐V/{\lambda }_{\text{p}}$, so the predicted increase of the thermal conductivity of paraffin-GNPs-CF20 has no actual increase in thermal conductivity of modified GNPs.

[figures omitted; refer to PDF]

[figures omitted; refer to PDF]

In Figure 8(b), the thermal conductivity of composites predicted by the Maxwell-Eucken model is obviously higher than that of the experimental value. This is because the Maxwell-Eucken model is applicable to the thermal conductivity model without uniform distribution of homogeneous spheres in the homogeneous matrix, but in practice, the distribution of nanoparticles is not uniform, and the interaction between nanoparticles and CF20 also exists. For example, when CNTs are filled in paraffin and then immersed in CF20, the CNTs with their irregularly distributed cloth will entangle themselves, as shown in Figure 8(b), which greatly reduces the prediction effect of the Maxwell-Eucken model.

The CF20 structure increases the thermal conductivity of paraffin wax from 0.25 W/(m·K) to 8.3083 W/(m·K), an increase of 33.2 times. The thermal conductivity of paraffin-SiO₂-CF20 in Figure 7(b) decreases by 0.02% from 0 wt.% to 5 wt.% and then increases with the increase of mass fraction. This is because when SiO₂ nanoparticles are just added, a small number of particles will increase the contact thermal resistance, and the gap between the particles becomes large, which does not achieve the effect of increasing the thermal conductivity. As the mass fraction increases, the gap becomes smaller, the contact thermal resistance decreases, and the thermal conductivity starts to increase, but the thermal conductivity of the final composite material does not increase significantly due to the low thermal conductivity of the nano-SiO₂ particles. With the increase of CNTs from 0 wt.% to 2 wt.%, the thermal conductivity increases by 0.0142 W/(m·K), but when the content is increased from 2 wt.% to 5 wt.%, the thermal conductivity only increases by 0.0107 W/(m·K). The theoretical thermal conductivity of GNPs should be very high, but the actual percentage increase in thermal conductivity is only 4.71% on the premise that Figure 7(b) changes from 0 wt.% to 5 wt.%.

4. Conclusion

Based on the composite energy storage material paraffin-CF20, different nanoparticles are filled in to obtain three new composite materials. The experimental data and the simulation data of the two models are compared to obtain conclusions that under the same mass fraction of nanoparticles, different particle forms and dispersion modes have different effects on the properties of the composite.

4.1. Particle Form

With simulation MD, the simulated paraffin-GNP thermal conductivity is 1.5 times the thermal conductivity of paraffin-CNTs and 2.5 times the thermal conductivity of paraffin-SiO₂ at 5 wt.%, indicating that the specific particle form affects the thermal conductivity of paraffin-nanoparticles. At the same time, the nucleation theory is used to explain the effect of particle form on the enthalpy of composite phase change energy storage materials. When the mass fraction is 5%, the enthalpies of paraffin-GNPs-CF20 are lower than the other two; the values are 10 J/g.

4.2. Diffusion Modes

The different distribution modes lead to uneven distribution and different distribution conditions, and their effects on thermal conductivity are also different. Filling paraffin with foamed carbon increases the thermal conductivity of pure paraffin from 0.25 W/(m·K) to 8.3083 W/(m·K), an increase of 33.2 times. The thermal conductivity of paraffin-SiO₂-CF20 decreases by 0.02% from 0 wt.% to 5 wt.% and then increases with the increase of mass fraction. Under 5 wt.%, compared with the thermal conductivity enhancement effect of SiO₂ composites, the thermal conductivity increase effects of CNTs and GNP composites are 6.7 and 15.8 times the thermal conductivity increase of SiO₂ composites, respectively. The experimental data of thermal conductivity of SiO₂, CNTs, and GNP composites are different from the data obtained from the “island” model and Maxwell model theory. GNP composites have the highest thermal conductivity and are higher than the theoretical thermal conductivity of the two models, indicating that the different ways of dispersing nanoparticles have a significant effect on thermal conductivity.

Authors’ Contributions

Hui Li put forward the idea that different dispersion modes of nanoparticles will affect the thermal conductivity of the PCM composite. Jia Yu proposed that different forms of nanoparticles would also affect thermal conductivity. Hui Li and Qingshan Zhu collected relevant literature. Hui Li and Li Kong contacted and obtained SEMs of these nanoparticles. Hui Li, Li Kong, and Hongji Zhu designed the PCM with SiO₂, CNTs, and GNPs and measured the thermal conductivity experiments. The experiment was carried out by Hui Li, Haoqing Wang, and Qingshan Zhu. Hui Li and Haoqing Wang verified the experimental data. Hui Li collated the experimental data and analyzed them to get the conclusion of the experiment. Finally, Hui Li wrote this paper. Jia Yu reviewed the paper and agreed to submit it.

Acknowledgments

We gratefully acknowledge the financial support of this study by the National Natural Science Foundation of China (Project No. 51672054).

References

[1] B. Chalmers, Principles of Solidification, 1964.

[2] H. Zhang, J. Baeyens, G. Cáceres, J. Degrève, Y. Lv, "Thermal energy storage: recent developments and practical aspects," Progress in Energy and Combustion Science, vol. 53,DOI: 10.1016/j.pecs.2015.10.003, 2016.

[3] S. Shaikh, K. Lafdi, K. Hallinan, "Carbon nanoadditives to enhance latent energy storage of phase change materials," Journal of Applied Physics, vol. 103 no. 9, article 094302,DOI: 10.1063/1.2903538, 2008.

[4] J. P. Hadiya, A. K. N. Shukla, "Experimental thermal behavior response of paraffin wax as storage unit," Journal of Thermal Analysis and Calorimetry, vol. 124 no. 3, pp. 1511-1518, DOI: 10.1007/s10973-016-5276-2, 2016.

[5] A. Elgafy, K. Lafdi, "Effect of carbon nanofiber additives on thermal behavior of phase change materials," Carbon, vol. 43 no. 15, pp. 3067-3074, DOI: 10.1016/j.carbon.2005.06.042, 2005.

[6] X. Fang, L.-W. Fan, Q. Ding, X. Wang, X.-L. Yao, J.-F. Hou, Z.-T. Yu, G.-H. Cheng, Y.-C. Hu, K.-F. Cen, "Increased thermal conductivity of Eicosane-based composite phase change materials in the presence of graphene nanoplatelets," Energy & Fuels, vol. 27 no. 7, pp. 4041-4047, DOI: 10.1021/ef400702a, 2013.

[7] M. Amin, N. Putra, E. A. Kosasih, E. Prawiro, R. A. Luanto, T. M. I. Mahlia, "Thermal properties of beeswax/graphene phase change material as energy storage for building applications," Applied Thermal Engineering, vol. 112, pp. 273-280, DOI: 10.1016/j.applthermaleng.2016.10.085, 2017.

[8] S. Jesumathy, M. Udayakumar, S. Suresh, "Experimental study of enhanced heat transfer by addition of CuO nanoparticle," Heat and Mass Transfer, vol. 48 no. 6, pp. 965-978, DOI: 10.1007/s00231-011-0945-y, 2012.

[9] K. Lafdi, O. Mesalhy, A. Elgafy, "Graphite foams infiltrated with phase change materials as alternative materials for space and terrestrial thermal energy storage applications," Carbon, vol. 46 no. 1, pp. 159-168, DOI: 10.1016/j.carbon.2007.11.003, 2008.

[10] D. L. Vrable, M. D. Vrable, "Space-based radar antenna thermal control," AIP Conference Proceedings,DOI: 10.1063/1.1357935, .

[11] D. C. Lagoudas, P. Cizmas, X.-L. Gao, "Synthesis, characterization and prognostic modeling of functionally graded hybrid composites for extreme environments," 2009. http://muri18.tamu.edu/Assets/TechPublications/MURINewsletterNo1.pdf

[12] X. Huang, Y. Lin, G. Alva, G. Fang, "Thermal properties and thermal conductivity enhancement of composite phase change materials using myristyl alcohol/metal foam for solar thermal storage," Solar Energy Materials and Solar Cells, vol. 170, pp. 68-76, DOI: 10.1016/j.solmat.2017.05.059, 2017.

[13] L. Xia, P. Zhang, "Thermal property measurement and heat transfer analysis of acetamide and acetamide/expanded graphite composite phase change material for solar heat storage," Solar Energy Materials and Solar Cells, vol. 95 no. 8, pp. 2246-2254, DOI: 10.1016/j.solmat.2011.03.031, 2011.

[14] S. A. Nada, W. G. Alshaer, "Experimental investigation of thermal conductivity enhancement of carbon foam saturated with PCM and PCM/MWCNTs composite for energy storage systems," Heat and Mass Transfer, vol. 55 no. 9, pp. 2667-2677, DOI: 10.1007/s00231-019-02610-4, 2019.

[15] Y. Zhou, Y. Chen, B. Liu, S. Wang, Z. Yang, M. Hu, "Mechanics of nanoscale wrinkling of graphene on a non-developable surface," Carbon, vol. 84 no. 1, pp. 263-271, DOI: 10.1016/j.carbon.2014.11.055, 2015.

[16] J. Shang, Y. Chen, Y. Zhou, L. Liu, G. Wang, X. Li, J. Kuang, Q. Liu, Z. Dai, H. Miao, L. Zhi, Z. Zhang, "Effect of folded and crumpled morphologies of graphene oxide platelets on the mechanical performances of polymer nanocomposites," Polymer, vol. 68, pp. 131-139, DOI: 10.1016/j.polymer.2015.05.003, 2015.

[17] Y. Zhou, X. Zhang, M. Hu, "Quantitatively analyzing phonon spectral contribution of thermal conductivity based on nonequilibrium molecular dynamics simulations. I. From space Fourier transform," Physical Review, vol. 92 no. 19,DOI: 10.1103/physrevb.92.195204, 2015.

[18] Y. Zhou, M. Hu, "Full quantification of frequency-dependent interfacial thermal conductance contributed by two- and three-phonon scattering processes from nonequilibrium molecular dynamics simulations," Physical Review B, vol. 95 no. 11,DOI: 10.1103/PhysRevB.95.115313, 2017.

[19] W. Yu, S. U. S. Choi, "The role of interfacial layers in the enhanced thermal conductivity of nanofluids: a renovated Maxwell model," Journal of Nanoparticle Research, vol. 5 no. 1/2, pp. 167-171, DOI: 10.1023/a:1024438603801, 2003.

[20] J. Buongiorno, .D. C. Venerus, N. Prabhat, T. McKrell, J. Townsend, R. Christianson, Y. V. Tolmachev, P. Keblinski, L. W. Hu, J. L. Alvarado, I. C. Bang, "A benchmark study on the thermal conductivity of nanofluids," Journal of Applied Physics, vol. 106 no. 9, article 094312, 2009.

[21] Y. Agari, A. Ueda, M. Tanaka, S. Nagai, "Thermal conductivity of a polymer filled with particles in the wide range from low to super-high volume content," Journal of Applied Polymer Science, vol. 40 no. 56, pp. 633-941, DOI: 10.1002/app.1990.070400526, 1990.

[22] J. Yu, X. Chen, X. Ma, Q. Song, Y. Zhao, J. Cao, "Influence of nanoparticles and graphite foam on the supercooling of acetamide," Journal of Nanomaterials, vol. 2014,DOI: 10.1155/2014/313674, 2014.