Method validation for the determination of aniline and 3,3’-dichlorobenzidine by gas chromatography-mass spectrometry

Abstract

This article uses and validates the analytical methods for the determination of aniline and 3,3’-dichlorobenzidine in soil by gas chromatography-mass spectrometry, and discusses the determination of semi volatile organic compounds in soil by gas chromatography-mass spectrometry. The feasibility of the application. The results showed that the semi volatile organic compounds aniline and 3,3’-dichlorobenzidine target corresponding to the internal standard response value and concentration showed a good linear relationship, the correlation coefficient was between 0.9997 and 0.9983 respectively; the detection limit was 0.04 mg, respectively/kg and 0.04mg/kg, the limits of quantification are 0.2mg/kg and 0.2mg/kg; the relative standard deviations of the two semi-volatile organic compounds in the precision are 2.5∼16.9% and 3.6∼6.2%, respectively; the accuracy is 2 The recovery rates of these volatile organic compounds were 64.5-83.9% and 72.6-74.3%, respectively. The verification results show that the linear relationship, detection limit, precision and accuracy all meet the requirements of “Determination of Semi-volatile Organic Compounds in Soils and Sediments by Gas Chromatography-Mass Spectrometry” (HJ 834-2017). Using gas chromatography-mass spectrometry technology can achieve fast, accurate and sensitive detection of target substances, and can meet the detection requirements of trace semi-volatile organic compounds, so this method can be better applied to the detection of soil and other environments.