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Abstract
In this work, synthesis of two novel donor-acceptor small molecules based on donor 9-phenyl-9H-carbazole and acceptor hexyl-dicyanovinyl units was carried out. A comparative analysis of these molecules differing in the position of bithiophene π-spacer at the carbazole block only showed that changing the position allows to fine-tune absorption spectra, HOMO value, bandgap and phase behaviour of the materials.
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1 Enikolopov Institute of Synthetic Polymeric Materials of the Russian Academy of Sciences, Profsoyuznaya st. 70, Moscow 117393, Russia
2 Enikolopov Institute of Synthetic Polymeric Materials of the Russian Academy of Sciences, Profsoyuznaya st. 70, Moscow 117393, Russia; Chemistry Department, Moscow State University, Leninskie Gory 1-3, Moscow 119991, Russia