Iron phthalocyanine on Au(111) is a “non-Landau” Fermi liquid

Abstract

The paradigm of Landau’s Fermi liquid theory has been challenged with the finding of a strongly interacting Fermi liquid that cannot be adiabatically connected to a non-interacting system. A spin-1 two-channel Kondo impurity with anisotropy D has a quantum phase transition between two topologically different Fermi liquids with a peak (dip) in the Fermi level for D < D_c (D > D_c). Extending this theory to general multi-orbital problems with finite magnetic field, we reinterpret in a unified and consistent fashion several experimental studies of iron phthalocyanine molecules on Au(111) that were previously described in disconnected and conflicting ways. The differential conductance shows a zero-bias dip that widens when the molecule is lifted from the surface (reducing the Kondo couplings) and is transformed continuously into a peak under an applied magnetic field. We reproduce all features and propose an experiment to induce the topological transition.

Single molecules on metal surfaces are paradigmatic systems for the study of many-body phenomena. Here, the authors show that several spectroscopic experiments on iron phthalocyanine on Au(111) surface can be described in a unified way in terms of a strongly interacting topologically non-trivial (non-Landau) Fermi liquid.