Abstract

The synthesis and structural characterization of new derivatives of [B12H12]2− is of fundamental interest and is expected to allow for extended applications. Herein we report on the synthesis of a series of amidine, amide, urea and isocyanate derivatives based on the amino-closo-dodecaborate anion [B12H11NH3]−. Their structures have been confirmed by spectroscopic methods, and nine crystal structures are presented.

Details

Title
Synthesis and Structural Characterization of Amidine, Amide, Urea and Isocyanate Derivatives of the Amino-closo-dodecaborate Anion [B12H11NH3]−
Author
Zhang, Yuanbin 1 ; Sun, Yuji 2 ; Wang, Tao 2 ; Liu, Jiyong 2 ; Spingler, Bernhard 3   VIAFID ORCID Logo  ; Duttwyler, Simon 2 

1  Department of Chemistry, Zhejiang University, 38 Zheda Road, Hangzhou 310027, China; Key Laboratory of Biomass Chemical Engineering of Ministry of Education, Department of Chemical and Biological Engineering, Zhejiang University, 38 Zheda Road, Hangzhou 310027, China 
2  Department of Chemistry, Zhejiang University, 38 Zheda Road, Hangzhou 310027, China 
3  Department of Chemistry, University of Zurich, Winterthurerstrasse 190, 8057 Zurich, Switzerland 
First page
3137
Publication year
2018
Publication date
2018
Publisher
MDPI AG
e-ISSN
14203049
Source type
Scholarly Journal
Language of publication
English
DOI
https://doi.org/10.3390/molecules23123137
ProQuest document ID
2582829865
Copyright
© 2018 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/). Notwithstanding the ProQuest Terms and Conditions, you may use this content in accordance with the terms of the License.