Effect of Freeze-thaw Cycles on Microstructure and Mechanical Properties of Limestone

Abstract

In studying the effect of freeze-thaw cycles on the microstructure and mechanical properties of limestone, scanning electron microscope, low-field nuclear magnetic resonance, and uniaxial compression tests are carried out on the limestone samples dried and subject to 5, 10, 15, and 20 freeze-thaw cycles. Through analysis and discussion, it was found that the number of freeze-thaw cycles has a significant effect on the microstructure of the limestone samples. Compared to the dry samples, the number of microcracks of the limestone samples subjected to freeze-thaw cycles is increased. Moreover, the crack width is positively correlated to the number of freeze-thaw cycles. With an increase in freeze-thaw cycles, the signal intensity of the T₂ spectrum is considerably increased, and the connectivity of the micropores and fissures is increased. In addition, the peak compressive strength and elastic modulus showed a significant negative correlation with the number of freeze-thaw cycles. Again, compared to the dry samples, the peak compressive strength of the samples subject to 5, 10, 15, and 20 freeze-thaw cycles decreased by 14.7%, 22.0%, 28.7%, and 37.5%, respectively. The elastic modulus also decreased by 8.0%, 11.4%, 11.7%, and 21.5%, respectively. Therefore, these findings provide basic parameters for the stability evaluation of rock slopes in Northwest Guizhou.