Pyrophyllite: An Economic Mineral for Different Industrial Applications

Abstract

Pyrophyllite (Al₂Si₄O₁₀(OH)₂) is a phyllosilicate often associated with quartz, mica, kaolinite, epidote, and rutile minerals. In its pure state, pyrophyllite exhibits unique properties such as low thermal and electrical conductivity, high refractive behavior, low expansion coefficient, chemical inertness, and high resistance to corrosion by molten metals and gases. These properties make it desirable in different industries such as refractory; ceramic, fiberglass, and cosmetic industries; as filler in the paper, plastic, paint, and pesticide industries; as soil conditioner in the fertilizer industry; and as a dusting agent in the rubber and roofing industries. Pyrophyllite can also serve as an economical alternative in many industrial applications to different minerals as kaolinite, talc, and feldspar. To increase its market value, pyrophyllite must have high alumina (Al₂O₃) content, remain free of any impurities, and possess as much whiteness as possible. This paper presented a review of pyrophyllite’s industrial applications, its important exploitable properties, and the specifications required for its use in industry. It also presents the most effective and economical techniques for enriching low-grade pyrophyllite ores to make them suitable for various industrial applications.

1. Introduction

Pyrophyllite is a hydrous aluminum silicate with the chemical formula Al₂Si₄O₁₀(OH)₂ and is commonly associated with other minerals such as quartz, mica, kaolinite, epidote, and rutile [1,2,3]. The pure pyrophyllite is composed of 28.3% Al₂O₃, 66.7% SiO₂, and 5% H₂O on weight bases [4]. Pyrophyllite, when pure, is desirable for many applications due to its unique properties [5]. For example, pyrophyllite provides low thermal and electrical conductivity; high refractive behavior; a low expansion coefficient; high corrosion resistance; low bulk density; and low hot-load deformation [6]. Therefore, this mineral is widely used in the refractory, ceramic, fiberglass, pesticide, fertilizer, paper, paint, plastic, rubber, cement, building-material, and pharmaceutical industries [7,8,9]. Furthermore, since pyrophyllite has a lower coefficient of expansion and thermal conductivity compared to clay, pyrophyllite is suitable for refractory applications [10,11]. Pyrophyllite, as a clay mineral, can be used as a substitute for kaolinite mineral group in many industrial applications, such as in the ceramic, and pottery, and filler industries, because kaolinite mineral group are rapidly depleting and expensive [12,13]. Furthermore, pyrophyllite can replace talc in many applications, especially as a filler pharmaceutical and medical applications, since pyrophyllite is safe and free from associated toxic minerals such as asbestos [14].

Determining the market price of pyrophyllite depends on the mineral’s Al₂O₃ content and the presence of impurities (Table 1) [15]. Since pyrophyllite is formed via hydrothermal alterations, it contains impurities such as iron, titanium, and alkalis [16,17]. The quality of pyrophyllite products is greatly affected by these impurities [18]. In addition, the presence of iron (Fe) and titanium (Ti) in pyrophyllite causes discoloration of the final product [19]. Accordingly, when pyrophyllite is used in the ceramic industry, this mineral stains the product’s surface due to the presence of these impurities [12,20]. Moreover, small amounts of iron lead to a decrease in the melting point of the refractory materials, affect the transparency of glass products, and reduce transmission in optical fibers [1,3,8]. Therefore, the most desirable percentage of iron in the pyrophyllite ore for use in industrial applications was determined in a previous study [8]. For example, in the refractory industry, the ore should contain less than 1% iron; in pottery and tile manufacturing, the ore should contain less than 0.5% iron; and in the paper industry, the ore should contain less than 1% iron [21]. It should be noted that alkalis are also deleterious because alkalis in the form of carbonates combine with silica (SiO₂) under firing temperatures and form silicates that are soluble in water [3]. The presence of these silicates in products is not desirable, especially in the ceramic industry. Furthermore, alkali ions are electrically conductive [22,23].

In 2017, a survey of the resource market showed significant growth in pyrophyllite production. High-grade pyrophyllite is produced in Korea, Japan, and China. Moreover, Japan and South Korea contribute more than 5% of the pyrophyllite produced globally [16,27]. Table 2 shows the world production of pyrophyllite (By Principal Countries) from 2015 to 2019. The increasing demand for high-grade pyrophyllite ores with low impurities for industrial applications led to a scarcity in the reserves of such ore [5,6]. Despite the presence of large quantities of low-grade pyrophyllite ores, the impurities in these ores limit their use. Thus, there is an imperative need for techniques to improve the purity of these low-grade ores [28].

Several techniques have been tested to remove impurities from industrial minerals, such as removing iron from dolomite [29], talc [30], and kaolin [31,32]. Moreover, several studies have used electrolysis, flotation, and electrification to remove sulfur, chlorine, iron, and titanium from non-metallic minerals [20,28,33]. For pyrophyllite, gravity separation techniques, flotation, magnetic separation, and leaching by ammonia and oxalic acid have been explored [1,8,18,28,34,35]. Furthermore, microwaves combined with sequential magnetic separation treatment have been used and considered as a promising method for upgrading low-grade pyrophyllite ore [19,36]. Under this background, the present study reviews the industrial applications of pyrophyllite and its required specifications in addition to reviewing the most effective and economical methods for enriching low-grade pyrophyllite ores.

2. Unique Properties of Pyrophyllite

The unique chemical and physical properties of pyrophyllite make it suitable for use in many industrial applications and as a substitute for several minerals such as talc and kaolinite [37]. These properties are addressed in the following sections.

2.1. Chemical Properties

Pure pyrophyllite contains 66.7% SiO₂, 28.30% Al₂O₃, and 5.00% H₂O⁺. However, high-purity pyrophyllite is rarely found in nature [38]. Table 3 shows the chemical composition of pure pyrophyllite in select deposits in South Korea and Russia [3]. One of the most important chemical properties that gives pyrophyllite a unique advantage in applied industries is that pyrophyllite is chemically inert and electrically neutral, making it highly resistant to the strongest acids and alkalis [39]. Pyrophyllite crystals can be either platy or fibrous (asbestine). Depending on their structures, these crystals break down into plates/flakes or fibers when ground. A sheet-like structure exists in each flake or folium, consisting of two silicate layers sandwiched by gibbsite [Al(OH)₃] layers. Pyrophyllite with a platy structure is desirable in industry, especially when used as a filler in the paint industry. This platy configuration, which is caused by the silicate structure of pyrophyllite sheets, increases resistance to film cracking, helps film dry, and promotes good dispersion [40].

2.2. Physical Properties

Pyrophyllite has a hardness of 1–2 on the Moh’s scale of hardness. Therefore, pyrophyllite is very soft and has a soapy and smooth surface, making it suitable for many industrial applications, such as in the pharmaceutical industry [7,43]. The high softness of pyrophyllite gives the mineral a high specific gravity of up to 2.9 [21]. Depending on the content of impurities such as iron oxide, the color of pyrophyllite varies from white to brownish green [43,44]. Moreover, it has a pearly luster in its foliated variety, with a refractive index that ranges from 1.55 to 1.60. Pyrophyllite also features good mechanical strength, thereby producing durable structures. Furthermore, pyrophyllite is a poor conductor of electricity and has high dielectric strength. One of the most important properties of pyrophyllite is its natural hydrophobicity [45]. This property is used to produce many roofing products such as sealing and waterproof materials and asphalt felts. In addition, ground pyrophyllite has a high oil absorption ability, especially the fibrous type of pyrophyllite. This property enables the use of pyrophyllite in the paint industry as an extender pigment [46].

2.3. Thermal Properties

Thermal properties represent the most important characteristic of pyrophyllite and combine the advantages of the thermal properties of both water and minerals. Like water (and unlike metal), pyrophyllite retains heat for a long time, radiating the heat slowly over an extended period, and, like metal, pyrophyllite heats up quickly. This behavior occurs because pyrophyllite combines poor thermal conductivity and high specific heat. Poor thermal conductivity means that the heat absorbed by the pyrophyllite does not flow quickly, while high specific heat means that if a unit rises in temperature, a mass of pyrophyllite can absorb a large amount of heat. These properties enhance the durability of refractory products that use pyrophyllite [12,47,48].

2.4. Pyrophyllite Thermal Phase Transformation

Pyrophyllite, when heated at different temperatures, passes through several thermal transformation phases (Table 4). One of the most critical transformations is the conversion of pyrophyllite into mullite at a temperature above 1200 °C. Mullite is an aluminum silicate with the chemical formula Al_4+2xSi_2−2xO_10−x and features distinctive technical properties. These properties include a low coefficient of expansion, low thermal conductivity, and resistance to corrosion from molten metals. Thus, mullite is used as a refractory material and as a substitute for feldspar and silica in ceramic applications, such as in floor and wall tiles [23,49].

3. Pyrophyllite’s Industrial Applications

Pyrophyllite is characterized by various chemical, physical, and thermal properties that make it suitable for several industrial applications. It has wide applications as a substitute for feldspar and silica due to its beneficial technical properties. The uses of pyrophyllite in industry include its application as a refractory material in the refractory industry and as a raw material in the ceramic, fiberglass, and cosmetic industries [51,52]. Moreover, pyrophyllite is used as filler in the paper, plastic, paint, and pharmaceutical industries [53]; as a soil conditioner in fertilizer applications; and as a dusting agent in the rubber and asphalt industries [54,55]. Figure 1 shows pyrophyllite consumption in different industries in the US [51]. This section discusses the applications, specifications, and grades of pyrophyllite ore required for different industries.

3.1. Pyrophyllite as a Refractory Material

Refractory Industry

Refractory materials are resistant to high temperatures and have a melting temperature of no less than 1580 °C, which is provided by pyrophyllite. Since pyrophyllite can be converted into mullite, pyrophyllite is suitable for producing relatively low-cost refractories, as mullite can withstand high temperatures up to 1810 °C [56]. Furthermore, pyrophyllite is highly resistant to chemical attacks by many silicates and gas oxides. In addition to its resistance to decrepitation, abrasion, and thermal shocks, pyrophyllite has high electrical resistance, compressive strength, tensile strength, and impact strength [57]. Therefore, pyrophyllite-based refractories are used in iron and steel furnaces for lining purposes. There are many ways to make pyrophyllite-based refractories. For example, (1) pyrophyllite can be crushed, bonded to sodium silicate, formed into bricks, and fired and (2) small amounts of pyrophyllite can be combined with fireclay, zirconia, or bauxite to make high-alumina refractories. Refractory products made from pyrophyllite include tile refractories, cement-fired bricks, fired brick-roofing tiles, and special refractories [45,58]. The specifications, grades, and properties of pyrophyllite required in the refractory industry are shown in Table 5.

3.2. Pyrophyllite as a Raw Material

3.2.1. Ceramic Industry

Clay minerals are the most important components in ceramic products. Moreover, several ceramic products can be prepared using different types of clay with different proportions in the mixture and different firing temperatures [59]. Since pyrophyllite becomes mullite under firing temperatures, which affords beneficial technical properties, pyrophyllite is used as a component in certain ceramic products. Ceramic products containing pyrophyllite include tiles, sanitary ware, white ware, and electrical components (e.g., insulators, vacuum gaskets, resistors, and transducers) [12,48]. The use of pyrophyllite in the ceramic industry improves mechanical properties, translucence, chemical resistance, resistance to thermal shocks; this mineral also provides high dielectric strength and promotes the crack-free glazing of the finished products. Further, pyrophyllite complements the silica in raw-material mixtures. Moreover, pyrophyllite’s ability to heat quickly and convert into mullite at a lower temperature (1100 °C) enables faster firing cycles than similar materials [21].

According to the industrial specifications of ceramics, the percentages of impurities such as iron oxide, titanium oxide, and alkalis should remain within the permissible percentages because of their deleterious effects on products (Table 5) [51,60]. Iron and titanium also have a coloring effect on the final product. In addition, iron oxide with titanium forms a low-melting iron-titanate glass, which causes increased porosity in the final product through the formation of blisters [3,21,61]. Alkalis are also deleterious because alkalis in the form of carbonates combine with silica under firing temperatures to form water-soluble silicates. Additionally, alkali ions are electrically conductive [62].

3.2.2. Fiber Glass Industry

Pyrophyllite is used as an alternative to feldspar in the glass industry as a source of aluminum. Pure feldspar contains 18–19% alumina. Although pyrophyllite is used as a source of aluminum in the glass industry, it contains high alkali content, which causes problems in glass products, especially if the glass product is to be used in electrical and electronic devices [37]. Naturally occurring pyrophyllite contains about 19% alumina and is comparable to the content in feldspar. Moreover, pyrophyllite has low alkali content compared to feldspar, supporting its use in the glass industry. Pyrophyllite is used to prepare fiberglass batches and allows sand to be removed from the batch, thus improving the batch-to-melt conversion efficiency and reducing conversion energy [63]. Further, pyrophyllite provides excellent mechanical properties and low melting temperatures. The pyrophyllite used in fiberglass production should be high in alumina content; low in iron oxide, titanium, and alkalis; and high in chemical stability, as shown in Table 5 [64,65].

3.2.3. Cosmetic Industry

Historically, talc has been used in the medical and pharmaceutical fields, especially in cosmetics, due to talc’s desirable properties, such as chemical inertness and the lack of an environment conducive to the growth of bacteria [66]. However, concerns have been raised about talc being a carcinogen. These concerns stem from the fact that talc is naturally found in co-deposits with asbestos [67,68]. Pyrophyllite, with its unique properties suitable for the cosmetic industry, represents a safe alternative. Pyrophyllite has a natural white color, chemical inertness, smoothness, softness, and hydrophobic properties. The hydrophobic nature of pyrophyllite prevents the absorption of sweat and causes sticking. Accordingly, high-quality pyrophyllite is used as a base in various face and body powders [9,14,21]. The pyrophyllite used for this purpose should be very white, free from iron and other colored minerals, and lacking grit and calcite since these properties affect the smoothness of the final product (Table 5) [9].

3.3. Pyrophyllite as Filler

Mineral filler is ground rock added to a specific mixture to enhance performance and properties and reduce cost. Cost is reduced by replacing more expensive components with less expensive, more efficient mineral fillers that take up space in the product matrix. When choosing a filler material, factors that should be considered include the filler’s chemical properties, cost, refractive index properties, particle size and shape, color, and hardness [69,70]. The most common mineral fillers are talc, pyrophyllite, mica, dolomite, calcium carbonate, wollastonite, and kaolin clay [70,71]. These fillers all provide cost savings but differ in their applications based on their properties. Due to its chemical and physical properties, pyrophyllite is very suitable as a filler and is thus used in the paper, plastic, paint, insecticide, and pharmaceutical industries.

3.3.1. Paper Industry

Papermakers seek to reduce costs and increase product quality through the use of fillers. The benefits of using fillers vary according to the product to be made. The most important characteristics of the final paper product are smoothness, brightness, opacity, print quality, dimensional stability, and low total cost. There are different types of fillers used in the manufacture of paper and can be either natural or synthetic. Natural fillers include ground limestone (ground chalk), kaolin, talc, and pyrophyllite, while synthetic fillers include precipitated calcium carbonate (PCC), precipitated aluminum silicate, titanium dioxide, and gypsum. Finely ground pyrophyllite is used as a filler in the paper industry because it is cheap and has excellent properties that improve the product quality, such as chemical inertness, softness, high reflectance, a strong particle shape, and hydrophobicity [3,72,73]. For this grade, the pyrophyllite should have high alumina content, low silica content, and a high degree of whiteness (Table 5).

3.3.2. Plastic Industry

Pyrophyllite is used in the plastic industry as a filler in various applications, such as in polyvinyl chloride (PVC), low-density polyethylene (LDPE), and high-density polyethylene (HDPE). In these applications, the various properties of pyrophyllite are exploited, such as its chemical inertness, high specific heat, high electrical resistance, platy structure, high oil absorption, greasiness, and good mechanical strength. These improved plastic materials are used in garden chairs and computer cases, which require high specific heat and electrical resistance, and under conditions that require high mechanical strength, such as in bumpers and automobile dashboards. In all these applications, pyrophyllite improves the smoothness and greasiness of the product. The platy structure of pyrophyllite gives the product a smooth finish. Further, pyrophyllite’s high oil-absorption properties offer an excellent mixture between pyrophyllite and oleo-resinous materials [9,21,74]. Moreover, pyrophyllite’s chemical inertness prevents a chemical reaction from occurring between the materials. The industry in question will determine the size of the ultra-fine particles needed to achieve uniform dispersion within the matrix; the other specifications are shown in Table 5.

3.3.3. Paint Industry

High-quality finely ground pyrophyllite is used in paints as a pigment extender and suspending agent. Using pyrophyllite as an extender enhances the nature of a product by increasing the volume of paint when mixed with the product and increases resistance to film cracking. Moreover, pyrophyllite helps film dry and promotes good dispersion. The main properties of pyrophyllite exploited in the paint industry as an extender are the mineral’s high refractive index, platy structure, softness, smooth surface, white color, chemical inertness, mechanical strength, and pearly luster. Another application of pyrophyllite in the paint industry is as a suspending agent in powder form. The fibrous crystalline type of pyrophyllite is used as a substitute for other, more expensive materials such as China clay. The fine fibers of pyrophyllite trap the primary pigment particles and keep them suspended long enough to facilitate brushing. In this way, the use of pyrophyllite ensures the pearly appearance, luster, and smooth brightness of the painted surface. Recently, finely ground paint-grade pyrophyllite has been used in wallboard joint cement and mastics to increase crack resistance and control rheology [3,51,53,87]. All these applications must consider the effects of iron oxide content, moisture, and volatile substances on the quality of the coating, along with the other specifications shown in Table 5.

3.3.4. Insecticide Industry

Pyrophyllite is used as a carrier in insecticides because it is cheap, fluffy, nonhygroscopic, and neutral in pH, making pyrophyllite compatible with both acid and alkaline ingredients. Other properties of pyrophyllite also make it desirable in this industry, such as the mineral’s low water content, high specific gravity, and inertness. Further, pyrophyllite can be easily blown through a nozzle and quickly sticks to the leaves and stems of plants. When passing through the blower of a machine, an electrostatic charge is picked up, which attracts pyrophyllite to the undersides of the leaves and exposed upper plant surfaces [9,24,54,79,80,81]. The most important industrial specifications for pyrophyllite to be used in insecticides are shown in Table 5.

3.4. As a Soil Conditioner

Recently, there has been increasing global interest in using aluminosilicate minerals to improve and maintain soil productivity. It is known that clay minerals can increase the ability of the soil to retain nutrients. The unique properties of pyrophyllite, such as its adsorption, ion exchange, and talc-like structure, have led to pyrophyllite’s use in agriculture as a soil conditioner [54]. Pyrophyllite is used as a fertilizer carrier in agriculture, where it improves the ability of the soil to hold nutrients and reduces leaching. Furthermore, pyrophyllite, as an aluminosilicate mineral, is used to retain heavy metals in the soil due to the mineral’s high surface area, high cation-exchange capacity, and large pore volume, allowing heavy metals to enter and be retained in its inner layers. Several studies have proven the ability of pyrophyllite to reduce the mobility of heavy metals in the soil, including Cu, Mn, Zn, Ni, Pb, Cd, and Cr. Pyrophyllite also contains certain amounts of potassium, calcium, magnesium, and iron, contributing significantly to plant growth and development. This grade of clay should contain a nearly neutral pH when mixed with other chemicals to provide stability over time (Table 5) [88].

3.5. As a Dusting Agent

3.5.1. Rubber Industry

Low-grade pyrophyllite is used as a dusting agent in the rubber industry to reduce costs, lubricate molds, and prevent surfaces from adhering together during production. Several properties of pyrophyllite are exploited in these applications, such as its platy structure, chemical inertness, smoothness, and greasy feel, as these combined properties affect the quality and smoothing of rubber tires [9,21,55,89]. One of the most important specifications that must be considered is the fineness of the grains, and grit is highly undesirable (Table 5).

3.5.2. Roofing Industry

Low-grade pyrophyllite is also used in the roofing industry. Pyrophyllite is added to asphalt roofing materials (i.e., in shingles and roll roofing) to prevent adhesion during manufacturing and storage and improve the materials’ resistance to weathering. The size, fineness, chemical inertness, and high absorbency of pyrophyllite are among the most crucial criteria to be considered for this application (Table 5) [71].

4. Enrichment of Low-Grade Pyrophyllite Ore

Since high-grade pyrophyllite ores are rare globally, to be suitable for industry, low-grade pyrophyllite ores must be enriched to remove impurities such as Fe and Ti and increase the alumina content [37,38,39,52]. Techniques for upgrading low-grade pyrophyllite ore vary depending on the characterization of the outcomes; these methods include physical separation techniques, chemical separation techniques, and separation techniques that combine the two [8,19]. Physical separation techniques include dry/wet magnetic separation, attrition-scrubbing, and flotation. Chemical separation techniques include calcination/roasting and leaching using oxalic acid and an ammonia solution. Separation techniques that combine chemical and physical separation techniques include sequential calcination or roasting followed by magnetic separation [90,91,92,93,94]. These techniques are discussed based on researchers’ contributions to the processing of low-grade pyrophyllite ore.

4.1. Magnetic Separation

Fe is a component in pyrophyllite that causes a decrease in the mineral’s grade and affects the quality of the final product in terms of coloring and mechanical properties [95,96]. A magnetic separation process is one of the most important methods for removing Fe from low-grade pyrophyllite ore [27]. This technique can be performed either dry or wet. The most important parameters considered when applying the magnetic separation method for low-grade pyrophyllite ore are the feed rate, feed% of solids, particle size, and magnetic intensity [97]. Several studies have investigated the use of magnetic separation to remove ferro and paramagnetic iron-bearing minerals from pyrophyllite. One study proved the efficiency of using magnetic separation to remove Fe from low-grade pyrophyllite. The studied samples contained pyrite and hematite phases, increased silicate content, and low alumina content. When high-intensity magnetic separation was applied, 97.6~98.8% Fe was removed from the treated samples [27]. In another study, dry magnetic separation with an intensity of 4000 Gauss was applied to low-grade pyrophyllite ore samples containing pyrite, hematite, and rutile phases (Table 6). The Fe removal rates obtained were 96% and 93% [36].

4.2. Flotation

The main objective of enrichment by flotation is to recover pyrophyllite from the associated minerals, thus increasing the Al₂O₃ content and decreasing the SiO₂ content [98,99]. Several studies have found that pyrophyllite responds to cationic collectors because of its lower aluminum: silica ratio, and its crystal structure contains the greatest number of cleavable planes. The most common flotation-based cationic collector for pyrophyllite is dodecylamine due to its satisfactory ability to collect aluminosilicate minerals at specific pH ranges [10,100,101]. The flotation of pyrophyllite was studied using dodecylamine and found to recover 96% of pyrophyllite. In a previous study, flotation was applied to pyrophyllite. In this study, the main associated minerals were quartz and feldspars (Table 6), and the collector was dodecylamine [101]. The study concluded that the Al₂O₃ content increased from 26.2 to 29.5%, the SiO₂ content decreased from 63.62% to 55.71%, and the product’s brightness was enhanced [10]. Flotation of the pyrophyllite was also carried out using 3-diaminoprpopane and N-dodecyl-1, with a recovery rate higher than 80%. There were also attempts to use an anionic collector for the flotation of pyrophyllite ore containing quartz as a gangue mineral. It was found that using sodium oleate (SO) as a collector can improve the flotation efficiency of pyrophyllite [38].

It should be highlighted that the hydrophobic surfaces of pyrophyllite serve as natural adsorption sites for non-polar organic molecules. As a result of its hydrophobicity, pyrophyllite can be easily separated from quartz and feldspar using collectorless flotation and a single type of frother. Based on this phenomenon, a study was conducted using a collectorless froth flotation to enrich pyrophyllite using Methyl Isobutyl Carbinol (MIBC) as a frother reagent. The associated minerals were quartz and kaolinite (Table 6). The study concluded that using collectorless flotation to upgrade the pyrophyllite with different doses of MIBC produced an increase in Al₂O₃ content between 25% and 27% and decreased the SiO₂ content from 73.41% to 65.56% [94]. The XRD analysis in Figure 2 shows that the major crystalline phase was pyrophyllite, which increased via flotation with MIBC compared to raw pyrophyllite in which quartz was a major phase.

In other cases, the flotation of pyrite from pyrophyllite was studied using N-dodecyl mercaptan as a collector along with a novel depressant (i.e., glucan) to achieve the selective flotation of pyrite and depress the pyrophyllite minerals. The studies demonstrated that a high recovery of Fe up to 98.51% could be obtained [98,102].

4.3. Attrition-Scrubbing

The Attrition-scrubbing technique is a simple beneficiation process in which the mineral particle is scrubbed under a high-slurry-flow speed, which also allows the particles to be affected by each other. This attrition leads to friction and collisions between the particles themselves. The attrition cell walls, impellers, and deflectors cause scrubbing, abrasion, and particle disintegration. This technique has wide applications for removing clay minerals from low-grade ores and has proven to be efficient in enriching several mineral ores, such as uranium and sand [103]. Moreover, this technique was shown to effectively concentrate low-grade pyrophyllite ore by significantly increasing the Al₂O₃ content and decreasing the SiO₂ content [104]. In another study, the attrition-scrubbing method was used to upgrade pyrophyllite ore that contains quartz and kaolinite as gangue minerals (Table 6). The study showed a significant improvement in the Al₂O₃ grade, where a very high Al₂O₃ grade of 29.33% was obtained for the finest size (−75 microns) compared to 21% for the Al₂O₃ grade in the feed, alongside a decrease in SiO₂ content to 61%, indicating high purity rates for pyrophyllite. Further, this study indicated that the attrition-scrubbing technique is effective for separating quartz and kaolinite from pyrophyllite [94]. Figure 3 presents an XRD analysis showing that the pyrophyllite was concentrated at a size of 75 microns under attrition-scrubbing. The major crystalline phase was pyrophyllite, which was increased via scrubbing compared to raw pyrophyllite, in which quartz was a major phase. Attrition-scrubbing clearly gives excellent results in separating clay minerals associated with pyrophyllite, which in turn improves the processing economy and energy consumption at the level of industry.

4.4. Leaching

In some cases, chemical treatment is used when physical treatment does not remove iron contaminants effectively from low-grade pyrophyllite ore. Leaching is the most important chemical treatment process for clay minerals and can use either organic acids (e.g., citric acid and oxalic acid) or inorganic acids (e.g., hydrochloric acid, sulfuric acid, and sodium hypochlorite). However, there are limitations when using inorganic acids with clay minerals due to environmental pollution and the contamination of products with Cl and SO₄⁻². Therefore, organic acids are more widely used. Oxalic acid is preferred for dissolving iron contaminants in clay minerals because of its high leachability under different conditions [105,106]. The effectiveness of oxalic acid in dissolving Fe from low-grade pyrophyllite ore to improve the quality of pyrophyllite was investigated in previous studies [8,107,108]. The critical parameters affecting the dissolution of Fe from pyrophyllite ore are the particle size, acid concentration, solid/liquid ratio, leaching time, temperature, and stirring speed. A study was also conducted to remove iron from pyrophyllite using oxalic acid leaching. The main gangue minerals were quartz, muscovite, and orthoclase (Table 6). Fe, mostly goethite, was present as inclusions or intergranular spaces within the silicates. When oxalic acid was used to dissolve iron using a concentration of 0.3 M, a temperature of 90 °C, a pulp density of 5%, a particle size below 100 microns, and a leaching time of 60 min, it was able to remove up to 99.3% of the iron in the pyrophyllite [8]. Oxalic acid is utilized with other chemical processes such as calcination, filtering, and drying to improve the quality of pyrophyllite by increasing its whiteness and brightness. These processes were applied to pyrophyllite micro powder with a particle size of 325–1200 meshes, and whiteness of greater than 87% was obtained [107,108].

There were previous attempts to use ammonia as a solvent to improve the quality of low-grade pyrophyllite ore via the dissolution of iron because ammonia is characterized by a low rinsing cost, low toxicity, and high efficiency in separating iron components [35]. In a previous study, the effectiveness of using an ammonia solution to remove iron from pyrophyllite was further investigated. The associated gangue minerals were quartz and dickite, and euhedral cubic pyrites were also observed (Table 6). The effect of variables such as the ammonium sulfate amount, particle size, addition of hydrogen peroxide, and sulfuric acid concentration were investigated. The study concluded that iron removal using an ammonia leaching solution could be effective [35].

4.5. Microwave Roasting and Magnetic Separation

Chemical separation methods are often applied alongside physical separation methods to obtain a higher-purity product [109]. Recently, the efficiency of using microwave heating and magnetic separation in removing impurities (e.g., Fe and Ti) from pyrophyllite was investigated and considered a promising and environmentally friendly method for enriching low-grade pyrophyllite ore [36]. Through previous studies, the use of microwave roasting and magnetic separation removed up to 96% of pyrophyllite impurities based on operating variables such as irradiation time and magnetic field intensity [36]. An increase in impurity removal efficiency was caused by phase changes of the impurities, which became magnetized during microwave roasting. Additionally, the impurity-removal efficiency can be improved by adjusting the operating conditions related to roasting and magnetic separation. Another study confirmed that sequential microwave roasting and magnetic separation could remove Fe and Ti with high efficiency. Kaolinite, quartz, and dickite were the main gangue minerals, and impurities in pyrophyllite occurred in the form of oxide and sulfide minerals. The study results indicated that Fe and Ti were removed from pyrophyllite with 86% and 68% efficiency, respectively, under 30 min of microwave irradiation and a magnetic field intensity of 2000 Gauss. Moreover, the study found that extending the microwave irradiation time and increasing the magnetic field intensity could improve impurity-removal efficiency, especially for paramagnetic Ti impurities [19]. This method can effectively upgrade low-grade pyrophyllite ore and clay minerals, which can then be exploited after removing impurities. However, to use this technique in industry, more studies are needed to better optimize the mineral-phase changes to achieve effective separation and energy consumption.

5. Conclusions

Pyrophyllite is a hydrated silicate mineral with unique properties that make it easily processable and suitable as a substitute for several clay minerals, such as kaolinite, talc, and feldspar, in many industrial applications. The properties of pyrophyllite can be exploited to use the mineral as a refractory material in the refractory industry; as a raw material in the ceramic, fiberglass, and cosmetic industries; as a filler in the paper, plastic, paint, and pesticide industries; as a soil conditioner in the fertilizer industry; and as a dusting agent in the rubber and roofing industries. These industries require particular specifications of pyrophyllite to use the mineral, the most important of which is the grade of Al₂O₃ and the content of impurities. The grade of Al₂O₃ and the content of impurities determine the price of pyrophyllite, so obtaining high-alumina and low-impurity pyrophyllite is a goal for industrial applications. Since high-grade pyrophyllite is rare worldwide, low-grade pyrophyllite beneficiation is necessary to obtain a suitable product for industry. Enrichment methods for pyrophyllite aim to increase the alumina content and remove objectionable impurities (e.g., Fe and Ti). Techniques for improving low-grade pyrophyllite ore vary depending on the characterization outcomes and include physical separation techniques, chemical separation techniques, and separation techniques that combine the two. The most vital and efficient physical separation methods to remove impurities from low-grade pyrophyllite are magnetic separation, flotation, and attrition-scrubbing, mainly when the gangue minerals are quartz and clay minerals. Previous studies found that these physical separation techniques are more efficient and commercially viable for low-grade pyrophyllite ores. In terms of chemical methods, dissolution with oxalic acid works to remove iron efficiently and increase the degree of whiteness of the pyrophyllite when the process is carried out alongside other chemical processes, such as calcination. Finally, based on previous studies, it is clear that sequential microwave roasting with magnetic separation is a promising, environmentally friendly, and economical method for enriching low-grade pyrophyllite ore and other clay minerals.

Author Contributions

Conceptualization, M.A.A. and H.A.M.A.; formal analysis, M.A.A.; resources, H.M.A.; data curation, M.A.A., H.A.M.A., H.M.A. and M.H.; writing—original draft preparation, M.A.A.; writing—review and editing, H.A.M.A., H.M.A. and M.H.; visualization, H.A.M.A., H.M.A. and M.H.; supervision, H.A.M.A.; funding acquisition, H.A.M.A., H.M.A. and M.H. All authors have read and agreed to the published version of the manuscript.

Funding

This work was supported by the Deanship of Scientific Research (DSR), King Abdulaziz University, Jeddah, under grant No. D1434-135-002. The authors, therefore, gratefully acknowledge the DSR’s technical and financial support.

Institutional Review Board Statement

Not applicable.

Informed Consent Statement

Not applicable.

Data Availability Statement

Not applicable.

Acknowledgments

This project was funded by the Deanship of Scientific Research (DSR), King Abdulaziz University, Jeddah, under Grant No. (No. D1434-135-002). The authors, therefore, gratefully acknowledge DSR technical and financial support.

Conflicts of Interest

The authors declare no conflict of interest.

Publisher’s Note: MDPI stays neutral with regard to jurisdictional claims in published maps and institutional affiliations.

Figures and Tables

Figure 1. Pyrophyllite consumption by different industries in the US [51].

Figure 2. Comparison of the XRD patterns of raw pyrophyllite and the selected pyrophyllite concentrate obtained via collectorless froth flotation. P: pyrophyllite; Q: quartz; K: kaolinite [94].

Figure 3. Comparison of the XRD patterns of raw pyrophyllite and selected pyrophyllite concentrates obtained by attrition-scrubbing. P: pyrophyllite; Q: quartz; K: kaolinite [94].

Table 1

Pyrophyllite different grades [3,24,25,26].

Grade	Main Specifications [3,24]	Price, US$/t [24,25,26]
Filler grade	300 mesh, milled, 21–27% Al2O3	150–480
Ceramic grade	15–19% Al2O3	27–44
Fiberglass grade	18%-21% Al2O3	59–65
Refractory grade	18%-21% Al2O3	59–65

Table 2

World pyrophyllite production in 2015–2019 in thousand metric tonnes (By principal countries) [26].

Country	2015	2016	2017	2018	2019
Korea, Rep. of	596.86	590.00	431.458	346.76	327.62
Japan	160.00	160.00	160.00	160.00	160.00
India	167.00	170.00	170.00	170.00	170.00
Turkey	50.00	50.00	50.00	50.00	50.00
Thailand	45.50	96.80	54.00	50.92	6.50
Peru	26.21	17.87	22.76	26.67	25.03
South Africa	17.35	19.11	55.04	98.24	134.45
Saudi Arabia	40.00	42.00	44.00	46.00	48.00

Table 3

Pure pyrophyllite chemical composition in select deposits in South Korea and Russia [3,41,42].

Chemical Composition %	South Korea			Russia
	Heanam	Gussi	Nohawado	Chistugor	Polar Urol	Kul-Yurt-Tau
SiO2	66.0	66.2	67.6	67.0	66.9	66.5
Al2O3	28.6	28.7	28.9	28.2	27.7	28.6
FeO	0.2	0.1	0.3	NA	0.3	NA
K2O	0.3	NA *	0.1	0.1	NA	0.1
Na2O	0.2	0.2	0.2	NA	NA	0.2

* NA: Not Available.

Table 4

Pyrophyllite thermal phase transformation [50].

Thermal Transformation Phase	Heating Temperature
Removal of water whether surface, in pores, and/or adsorbed	<450 °C
Dehydroxylation	780 °C < T < 1100 °C
Formation of amorphous SiO2	950 °C < T < 1100 °C
Formation of mullite and crystallization of cristobalite from amorphous SiO2	T > 1200 °C

Table 5

Specifications of pyrophyllite ore for different applications.

Industry (Role)	Specifications		Ref.
	Chemical	Physical
Refractory (as refractory material)	SiO2       60% Max Al2O3    18–21% Fe2O3     <1% TiO2       1% Max Alkalis   1% Max CaO       <0.5% MgO      <0.5% LOI          4%	Required size >150 mm (special refractory). >15 mm (tile refractory). >5 mm (cement brick). Density 2.8–2.9 g/cm3 Pyrometric Cone Equivalent (PCE) 28–30%	[3,8,9,45]
Ceramic (as raw material)	SiO2       64 ± 2% Al2O3    15–19% Fe2O3     1% Max TiO2       1% Max Alkalis   1% Max CaO       <0.5% MgO      <0.5% LOI        4.5 ± 1%	Required size 44 Microns	[2,3,9,22]
Fiber glass (as raw material)	SiO2       <70% Al2O3    18–21% Fe2O3     >0.5% TiO2       >1% Alkalis   >1% CaO       <0.5% MgO      <0.5% LOI          4%	Required size −45 microns	[4,9,63,65]
Cosmetic (as raw material)	SiO2       <70% Al2O3    <21% Fe2O3     >0.5% TiO2       >0.5% Alkalis   >1% CaO       <0.5% MgO      <0.5% LOI          4%	Required size Very fine (5 microns). Softness Smoothness	[3,14,21]
Paper (as filler)	SiO2       55–70% Al2O3    21–27% Fe2O3     >0.5% TiO2       >0.5% Alkalis   >1% CaO       1% Max MgO      <0.5%	Required size −45 microns Whiteness ≥ 85% Moisture 3% (min) Stable particle distribution	[3,9,21,72,75,76]
Plastic (as filler)	SiO2        <70% Al2O3      21–27% Fe2O3      >0.5% TiO2        >1% Alkalis    1% Max CaO         >1% MgO       <0.5%	Required size −5 microns Density 2.8–2.9 g/cm3 Mohs hardness, 1–2	[3,9,51,72]
Paint (as filler)	SiO2       <65% Al2O3    <21% Fe2O3     >0.5% TiO2       >1% Alkalis   >0.5% CaO       <0.5% MgO      <0.5%	Required size −53 microns Density 2.8–2.9 g/cm3 Mohs hardness, 1–2 Brightness < 85% Oil absorption < 24%	[3,9,21,77,78]
Insecticide (as filler)	SiO2       <70% Al2O3     19–21% Fe2O3     1.5 Max TiO2       >1% Alkalis    >0.5% CaO       <0.5% MgO      <0.5% LOI          −7%	Required size −75 microns	[9,24,79,80,81]
Fertilizer (As soil conditioner)	SiO2       <70% Al2O3    19–21%	Required size 5 to 0.1 mm Mohs hardness 1.5	[3,10,54,82,83]
Rubber (as dusting agent)	SiO2       >70% Al2O3     <19%	Required size −75 microns (Max) Smooth, greasy feel	[7,9,51,71,84]
Roofing (as dusting agent)	SiO2       >70% Al2O3     <19%	Required size −45 microns	[7,9,51,85,86]

Table 6

Methods of beneficiation for low-grade pyrophyllite ores, description, and results obtained from the literature review.

Ore Country	ROM Chemical Composition	Main Gangue Minerals	Treatment Methods	Major Concentrate Features	Ref.
South Korea	SiO2       78.02% Al2O3    10.12% Fe2O3     2.99% TiO2       2.33% Alkalis   0.54	Hematite and pyrite phases	Magnetic separation (Dry high intensity magnetic separation)	The Fe removal rates obtained were 96% and 93%.	[98]
India	SiO2       63.62% Al2O3    21.36% Fe2O3     0.26% TiO2       0.12% Alkalis   5.57%	Quartz and feldspars	Flotation (Direct)	The Al2O3 content increased between 26.2 and 29.5%. The SiO2 content decreased to 55.71% The product’s brightness was enhanced.	[10]
Turkey	SiO2       73.41% Al2O3    20.64% Fe2O3     0.06% TiO2       0.42% Alkalis   0.92%	Quartz and kaolinite	Collectorless Froth flotation (Direct)	The Al2O3 content increased between 25 and 27%. The SiO2 content decreased to 65.56%.	[94]
Turkey	SiO2       73.41% Al2O3    20.64% Fe2O3     0.06% TiO2       0.42% Alkalis   0.92%	Quartz and kaolinite	Attrition-scrubbing	A high Al2O3 grade of 29.33% was obtained alongside a decrease in SiO2 content to 61%	[94]
India	SiO2       68.13% Al2O3    21.6% Fe2O3     2.5% Alkalis   1.5%	Quartz, muscovite, orthoclase, and goethite	Leaching by oxalic acid	The Fe removal rate obtained was 99.3%.	[8]
South Korea	SiO2       71.64% Al2O3    18.56% Fe2O3     3.57% TiO2       0.57% Alkalis   0.48%	Quartz and dickite. Euhedral cubic pyrites were observed	Ammonia leaching solution	A high Fe removal rate was obtained.	[35]
South Korea	SiO2       72.37% Al2O3    17.93% Fe2O3     2.77% TiO2       1.39% Alkalis   1%	Impurities appear in the form of pyrite, hematite, and rutile. Kaolinite, quartz, and dickite.	Sequential microwave roasting and magnetic separation	Iron and Ti were removed from the pyrophyllite ore with 86.3% and 68.3% efficiency, respectively.	[19]

References

1. Abdrakhimova, E.S. Physicochemical studies of pyrophyllite of the Nikol’sk deposit. Refract. Ind. Ceram.; 2010; 51, pp. 6-8. [DOI: https://dx.doi.org/10.1007/s11148-010-9244-2]

2. Jeong, Y.; Lee, S.; Hong, S.; Park, C. Preparation, characterization and application of low-cost pyrophyllite-alumina composite ceramic membranes for treating low-strength domestic wastewater. J. Membr. Sci.; 2017; 536, pp. 108-115. [DOI: https://dx.doi.org/10.1016/j.memsci.2017.04.068]

3. Kogel, J.E.; Trivedi, N.C.; Barker, J.M.; Krukowski, S.T. Industrial Minerals & Rocks: Commodities, Markets, and Uses; SME: Southfield, MI, USA, 2006; Volume 44.

4. Bentayeb, A.; Amouric, M.; Olives, J.; Dekayir, A.; Nadiri, A. XRD and HRTEM characterization of pyrophyllite from Morocco and its possible applications. Appl. Clay Sci.; 2003; 22, pp. 211-221. [DOI: https://dx.doi.org/10.1016/S0169-1317(03)00066-8]

5. Evans, B.W.; Guggenheim, S. Talc, Pyrophyllite, and Related Minerals. Hydrous Phyllosilicates; Bailey, S.W. De Gruyter: Berlin, Germany, 2018.

6. Zelazny, L.W.; White, G.N. The Pyrophyllite-Talc Group. Minerals in Soil Environments; Dixon, J.B.; Weed, S.B. John Wiley & Sons, Ltd.: Hoboken, NJ, USA, 2018; pp. 527-550.

7. Harben, P.W. The Industrial Minerals Handybook: A Guide to Markets, Specifications and Prices; 4th ed. Industrial Minerals Information: Surrey, UK, 2002; ISBN 1904333044

8. Jena, S.K.; Singh, S.; Rao, D.S.; Dhawan, N.; Misra, P.K.; Das, B. Characterization and removal of iron from pyrophyllite ore for industrial applications. Min. Met. Explor.; 2015; 32, pp. 102-110. [DOI: https://dx.doi.org/10.1007/BF03402427]

9. Pradhan, A.A.; Das, M.; Goswami, A.S. Economic Potential of Pyrophyllite Deposits of Keonjhar as Industrial Mineral. VISTAS Geol. Res.; 2015; 13, pp. 86-90.

10. Das, B.; Mohanty, J. Mineralogical Characterization and Beneficiation Studies of Pyrophyllite from Orissa, India. J. Miner. Mater. Charact. Eng.; 2009; 8, pp. 329-338. [DOI: https://dx.doi.org/10.4236/jmmce.2009.84029]

11. Dolley, T. Minerals Yearbook 2011. MineralsYearbook2011; USGS: Reston, VG, USA, 2013; Volume 1, pp. 1-8.

12. Mukhopadhyay, T.; Ghatak, S.; Maiti, H. Pyrophyllite as raw material for ceramic applications in the perspective of its pyro-chemical properties. Ceram. Int.; 2010; 36, pp. 909-916. [DOI: https://dx.doi.org/10.1016/j.ceramint.2009.10.026]

13. Perezmaqueda, L. Thermal transformations of sonicated pyrophyllite. Appl. Clay Sci.; 2004; 24, pp. 201-207. [DOI: https://dx.doi.org/10.1016/j.clay.2003.03.003]

14. Kostadinović, A.; Balaban, M.; Senatore, A.; Sarno, M.; Cirillo, C.; Massiani, P.; Baghdad, K.; Launay, F.; Atlagić, P.G. Natural Pyrophyllite as a Substitute for Talc in Medical and Pharmaceutical Applications. Proceedings of the Conference: International Conference on Medical and Biological Engineering, Banja Luka, Bosnia and Herzegovina; Pokvić, A.B.Š.G. Springer: Cham, Switzerland, 2019.

15. Decleer, J.G.M. Introduction to Industrial Minerals; 1st ed. Chapman & Hall: London, UK, 1996; Volume 10.

16. Harvey, C.C.; Murray, H.H. Industrial clays in the 21st century: A perspective of exploration, technology and utilization. Appl. Clay Sci.; 1997; 11, pp. 285-310. [DOI: https://dx.doi.org/10.1016/S0169-1317(96)00028-2]

17. Phillips, G.N.; Powell, R. Hydrothermal alteration in the Witwatersrand goldfields. Ore Geol. Rev.; 2015; 65, pp. 245-273. [DOI: https://dx.doi.org/10.1016/j.oregeorev.2014.09.031]

18. Ambikadevi, V.; Lalithambika, M. Effect of organic acids on ferric iron removal from iron-stained kaolinite. Appl. Clay Sci.; 2000; 16, pp. 133-145. [DOI: https://dx.doi.org/10.1016/S0169-1317(99)00038-1]

19. Kim, B.-J.; Cho, K.H.; Chang, B.; Kim, H.-S.; Lee, S.-G.; Park, C.-Y.; Lee, S.; Choi, N.-C. Sequential microwave roasting and magnetic separation for removal of Fe and Ti impurities in low-grade pyrophyllite ore from Wando mine, South Korea. Miner. Eng.; 2019; 140, 105881. [DOI: https://dx.doi.org/10.1016/j.mineng.2019.105881]

20. Mowla, D.; Karimi, G.; Ostadnezhad, K. Removal of hematite from silica sand ore by reverse flotation technique. Sep. Purif. Technol.; 2008; 58, pp. 419-423. [DOI: https://dx.doi.org/10.1016/j.seppur.2007.08.023]

21. Chatterjee, K.K. Uses of Industrial Minerals, Rocks and Freshwater; Nova Science Publishers: Hauppage, NY, USA, 2009.

22. Kizilkaya, N.; Onal, M.; Depci, T.; Yucel, A. Usability of Malatya Pyrophyllite in the Traditional Ceramic Industry. Proceedings of the IOP Conference Series: Earth and Environmental Science; Prague, Czech Republic, 5–9 September 2016; Volume 44.

23. Li, G.; Zeng, J.; Luo, J.; Liu, M.; Jiang, T.; Qiu, G. Thermal transformation of pyrophyllite and alkali dissolution behavior of silicon. Appl. Clay Sci.; 2014; 99, pp. 282-288. [DOI: https://dx.doi.org/10.1016/j.clay.2014.07.011]

24. Indian Bureau of Mines. Indian Minerals Yearbook 2016 (Part-III: Mineral Reviews); IBM: Nagpur, India, 2017.

25. India MART Pyrophyllite at Best Price in India. Available online: https://dir.indiamart.com/impcat/pyrophyllite.html (accessed on 12 November 2021).

26. U.S. Geological Survey. Talc and Pyrophyllite Statistics and Information; USGS: Reston, VA, USA, 2020.

27. Cho, K.; Jo, J.; Bak, G.; Choi, N.; Park, C. The Fe removal in pyrophyllite by physical method. Geophys. Res. Abstr.; 2015; 17, pp. 2015-4465.

28. Perepelitsyn, V.A.; Proshkin, V.A.; Rytvin, V.M.; Ignatenko, V.G.; Yarosh, I.A.; Abyzov, A. Non-traditional domestic refractory materials for aluminum metallurgy. Refract. Ind. Ceram.; 2008; 49, pp. 257-260. [DOI: https://dx.doi.org/10.1007/s11148-008-9090-7]

29. Liu, X.; Bai, M. Effect of chemical composition on the surface charge property and flotation behavior of pyrophyllite particles. Adv. Powder Technol.; 2017; 28, pp. 836-841. [DOI: https://dx.doi.org/10.1016/j.apt.2016.12.009]

30. Barani, K.; Aghazadeh, V. Removal of impurities from talc ore by leaching method. J. Chem. Technol. Metall.; 2018; 53, pp. 296-300.

31. Arslan, V.; Bayat, O. Removal of Fe from kaolin by chemical leaching and bioleaching. Clays Clay Miner.; 2009; 57, pp. 787-794. [DOI: https://dx.doi.org/10.1346/CCMN.2009.05706011]

32. Guo, M.-R.; He, Q.-X.; Li, Y.-M.; Lu, X.-Q.; Chen, Z. Removal of Fe from Kaolin Using Dissimilatory Fe(III)-Reducing Bacteria. Clays Clay Miner.; 2010; 58, pp. 515-521. [DOI: https://dx.doi.org/10.1346/CCMN.2010.0580406]

33. Ohkawa, M.; Yamashita, Y.; Inoue, M.; Kitagawa, R.; Takeno, S. Hematite in pyrophyllite ore deposits, Shobara district, southwestern Japan. Miner. Pet.; 2000; 70, pp. 15-23. [DOI: https://dx.doi.org/10.1007/s007100070010]

34. Bozkaya, Ö.; Yalçin, H.; Başibüyük, Z.; Bozkaya, G.; Yalçın, H. Metamorphic-hosted pyrophyllite and dickite occurrences from the hydrous Al-silicate deposits of the Malatya-Pütürge region, central eastern Anatolia, Turkey. Clays Clay Miner.; 2007; 55, pp. 423-442. [DOI: https://dx.doi.org/10.1346/CCMN.2007.0550409]

35. Kim, B.J.; Cho, K.H.; Choi, N.C.; Park, C.Y. The Efficiency of Fe Removal for Pyrophyllite by Ammonia Leaching Solution, and Their Dissolution Kinetics. J. Miner. Soc.; 2014; 27, pp. 53-62. [DOI: https://dx.doi.org/10.9727/jmsk.2013.27.1.53]

36. Cho, K.-H.; Kim, B.-J.; Choi, N.-C.; Park, C.-Y. The Mineralogical and Chemical Characteristics of Fe Impurities and the Efficiency of their Removal Using Microwave Heating and Magnetic Separation in the Pyrophyllite Ore. J. Miner. Soc. Korea; 2016; 29, pp. 47-58. [DOI: https://dx.doi.org/10.9727/jmsk.2016.29.2.47]

37. Seo, J.; Kim, S.; Bae, I.-K.; Kim, W. Roasting of pyrophyllite for application in aluminoborosilicate glass production. Geosystem Eng.; 2020; 23, pp. 123-130. [DOI: https://dx.doi.org/10.1080/12269328.2020.1719904]

38. Seo, J.; Choi, J.; Kim, W.; Kim, S.B.; Bae, I.-K. Enhanced Pyrophyllite Flotation Performance Using Sodium Oleate as an Anionic Collector in the Presence of Ammonium Ion. Mater. Trans.; 2020; 61, pp. 1645-1650. [DOI: https://dx.doi.org/10.2320/matertrans.MT-M2019284]

39. Qin, X.; Zhao, J.; Wang, J.; He, M. Atomic Structure, Electronic, and Mechanical Properties of Pyrophyllite under Pressure: A First-Principles Study. Minerals; 2020; 10, 778. [DOI: https://dx.doi.org/10.3390/min10090778]

40. Wypych, G. Fillers—Origin, Chemical Composition, Properties, and Morphology. Handbook of Fillers; ChemTec Publishing: Scarborough, ON, Canada, 2021.

41. Son, Y.-S.; Kang, M.-K.; Yoon, W.-J. Pyrophyllite mapping in the Nohwa deposit, Korea, using ASTER remote sensing data. Geosci. J.; 2014; 18, pp. 295-305. [DOI: https://dx.doi.org/10.1007/s12303-014-0007-9]

42. Jige, M.; Kitagawa, R.; Zaykov, V.; Sinyakovskaya, I.; Udachin, V.; Hwang, J.-Y. Surface Microtopography of Pyrophyllite from Different Modes of Occurrence. 2001 A Clay Odyssey; Elsevier: Amsterdam, The Netherlands, 2003.

43. Demez, A.; Karakoç, M.B. Mechanical properties of high strength concrete made with pyrophyllite aggregates exposed to high temperature. Struct. Concr.; 2020; 22, pp. E769-E778. [DOI: https://dx.doi.org/10.1002/suco.201900381]

44. Lee, H.; Kim, W. Ball Mill Grinding Characteristics with Respect to the Chemical Composition of Pyrophyllite. Mater. Trans.; 2018; 59, pp. 1805-1810. [DOI: https://dx.doi.org/10.2320/matertrans.M2018157]

45. Shayakhmetov, U.S.; Shayakhmetov, A.U.; Zakharov, A.V.; Khamidullin, A.R.; Gazizova, A.T. Refractory Composites Based on Pyrophyllite Raw Materials. Refract. Ind. Ceram.; 2018; 59, pp. 241-246. [DOI: https://dx.doi.org/10.1007/s11148-018-0214-4]

46. Murray, H.H. Overview—Clay mineral applications. Appl. Clay Sci.; 1991; 5, pp. 379-395. [DOI: https://dx.doi.org/10.1016/0169-1317(91)90014-Z]

47. And, J.J.F.; Hamza, A.I.; Dec, S.F.; Bronnimann†, C.E. Solid-State 27Al and 29Si NMR and H CRAMPS Studies of the Thermal Transformations of the 2:1 Phyllosilicate Pyrophyllite. J. Phys. Chem.; 1996; 100, pp. 17351-17360. [DOI: https://dx.doi.org/10.1021/jp961499f]

48. González-Miranda, F.D.M.; Garzón, E.; Reca, J.; Pérez-Villarejo, L.; Martínez-Martínez, S.; Sánchez-Soto, P.J. Thermal behaviour of sericite clays as precursors of mullite materials. J. Therm. Anal. Calorim.; 2018; 132, pp. 967-977. [DOI: https://dx.doi.org/10.1007/s10973-018-7046-9]

49. Birincia, M.; Uysala, T.; Erdemoğlua, M.; Porgalıb, E.; Barry, T.S. Acidic leaching of thermally activated pyrophyllite ore from acidic leaching of thermally activated pyrophyllite ore from pütür-ge (malatya-turkey) deposit. Proceedings of the XVII Balkan Mineral Processing Congress; Antalya, Turkey, 1–3 November 2017.

50. Erdemoğlu, M.; Birinci, M.; Uysal, T. Thermal Behavior of Pyrophyllite Ore during Calcination for Thermal Activation for Aluminum Extraction by Acid Leaching. Clays Clay Miner.; 2020; 68, pp. 89-99. [DOI: https://dx.doi.org/10.1007/s42860-019-00061-w]

51. McGonigle, F.; Ciullo, P.A. Industrial Minerals and Their Uses: A Handbook and Formulary; 1st ed. Ciullo, P.A. Noyes Publications: Westwood, NJ, USA, 1996.

52. Terzić, A.; Radulović, D.; Pezo, M.; Stojanović, J.; Pezo, L.; Radojević, Z.; Andrić, L. Prediction model based on artificial neural network for pyrophyllite mechano-chemical activation as an integral step in production of cement binders. Constr. Build. Mater.; 2020; 258, 119721. [DOI: https://dx.doi.org/10.1016/j.conbuildmat.2020.119721]

53. Canada: Trinity Resources—Pyrophyllite pigments/fillers. Focus Pigment.; 2014; 2014, pp. 3-4. [DOI: https://dx.doi.org/10.1016/S0969-6210(14)70099-2]

54. Hasanbegović, E.; Huremović, J.; Žero, S. Adsorption capacity of nitrate from artificial fertilizers and soil on pyrophyllite. Int. J. Environ. Sci. Technol.; 2021; 18, pp. 3731-3738. [DOI: https://dx.doi.org/10.1007/s13762-021-03135-2]

55. Zhang, J.F.; Tian, Y.G.; Lin, S.E.; Weng, X.J.; Liu, H.T. Effect of properties of SBR/N330 nanocomposites for N330 partially replaced by pyrophyllite based modified composite powder. Cailiao Gongcheng J. Mater. Eng.; 2010; 11, pp. 35-56.

56. Chen, R.; Li, Y.; Xiang, R.; Li, S.; Fan, X.; Li, Y.; Sang, S. Effect of pyrophyllite addition on properties of lightweight insulation refractory materials. Chinas Refract.; 2017; 26, pp. 38-42.

57. Shymanskaya, H.N.; Dyatlova, E.M.; Popov, R.Y. Refractory clay raw materials of republic of belarus for production of the porcelain tile. Izv. Vysshikh Uchebnykh Zaved. Khimiya Khimicheskaya Tekhnologiya; 2019; 62, pp. 39-44. [DOI: https://dx.doi.org/10.6060/ivkkt.20196212.6018]

58. Trương, M.T.; Pham, T.M.; Phan, N.H.; Nguyen, T.D.; Nguyen, T.X.Q.; Dang, M.T.; Le, V.T.; Nguyen, H.T. Manufacturing of Chamotte Refractory Brick from Clay Sources in Vietnam. J. Eng. Sci. Technol. Rev.; 2018; 11, pp. 25-30. [DOI: https://dx.doi.org/10.25103/jestr.114.03]

59. Kairakbaev, A.K.; Abdrakhimov, V.Z.; Abdrakhimova, E.S. Study of the Influence of Nanotechnogenic Raw Materials and Pyrophyllite on the Orientation of Clay Particles and the Water Permeability of Acid-Resistant Materials. Glas. Ceram.; 2021; 77, pp. 348-354. [DOI: https://dx.doi.org/10.1007/s10717-021-00305-z]

60. ASTM-C126-16. Standard Specification for Ceramic Glazed Structural Clay Facing Tile, Facing Brick, and Solid Masonry Units 1; ASTM Int.: West Conshohocken, PA, USA, 2011.

61. Salar-García, M.; Walter, X.; Gurauskis, J.; Fernández, A.D.R.; Ieropoulos, I. Effect of iron oxide content and microstructural porosity on the performance of ceramic membranes as microbial fuel cell separators. Electrochim. Acta; 2020; 367, 137385. [DOI: https://dx.doi.org/10.1016/j.electacta.2020.137385]

62. Kurnia, A.; Mufti, N.; Adem, U. Electrocaloric effect of alkali co-substituted Sr0.6Ba0.4Nb2O6 ceramics. J. Alloy. Compd.; 2020; 844, 156132. [DOI: https://dx.doi.org/10.1016/j.jallcom.2020.156132]

63. Li, H. Alumina and silica sources for E-Glass fibre manufacturing—Melting energy aspects. Glas. Technol. Eur. J. Glas. Sci. Technol. Part. A; 2014; 55, pp. 7-13.

64. Elsandika, G.; Fuad, A.; Diantoro, M.; Zulaika, S.; Subakti, . Preparation and characterization of superhydrophobic glass surface using pyrophyllite nanosilica coating. In Proceedings of the AIP Conference Proceedings; Jatinangor, Indonesia, 2–3 September 2015; Volume 1712.

65. ASTM D5685-19. Standard Specification for “Fiberglass” (Glass-Fiber-Reinforced Thermosetting-Resin) Pressure Pipe Fittings 2019; ASTM Int.: West Conshohocken, PA, USA, 2019.

66. Pi-Puig, T.; Animas-Torices, D.Y.; Solé, J. Mineralogical and Geochemical Characterization of Talc from Two Mexican Ore Deposits (Oaxaca and Puebla) and Nine Talcs Marketed in Mexico: Evaluation of Its Cosmetic Uses. Minerals; 2020; 10, 388. [DOI: https://dx.doi.org/10.3390/min10050388]

67. Steffen, J.E.; Tran, T.; Yimam, M.; Clancy, K.M.; Bird, T.B.; Rigler, M.; Longo, W.; Egilman, D.S. Serous Ovarian Cancer Caused by Exposure to Asbestos and Fibrous Talc in Cosmetic Talc Powders—A Case Series. J. Occup. Environ. Med.; 2020; 62, pp. e65-e77. [DOI: https://dx.doi.org/10.1097/JOM.0000000000001800]

68. Fiume, M.M.; Boyer, I.; Bergfeld, W.F.; Belsito, D.V.; Hill, R.A.; Klaassen, C.D.; Liebler, D.; Marks, J.J.G.; Shank, R.C.; Slaga, T.J. et al. Safety Assessment of Talc as Used in Cosmetics. Int. J. Toxicol.; 2015; 34, pp. 66S-129S. [DOI: https://dx.doi.org/10.1177/1091581815586797]

69. Zhao, X.; Ouyang, J.; Tan, Q.; Tan, X.; Yang, H. Interfacial characteristics between mineral fillers and phenolic resin in friction materials. Mater. Express; 2020; 10, pp. 70-80. [DOI: https://dx.doi.org/10.1166/mex.2020.1596]

70. Katz, H.S.; Milewski, J.V. Mineral Fillers. Handbook of Fillers for Plastics; Springer: Berlin/Heidelberg, Germany, 2016; pp. 166-196. [DOI: https://dx.doi.org/10.13140/RG.2.1.3559.0005]

71. Chen, Y.; Xu, S.; Tebaldi, G.; Romeo, E. Role of mineral filler in asphalt mixture. Road Mater. Pavement Des.; 2020; pp. 1-40. [DOI: https://dx.doi.org/10.1080/14680629.2020.1826351]

72. Hubbe, M.A.; Gill, R.A. Fillers for Papermaking: A Review of their Properties, Usage Practices, and their Mechanistic Role. BioResources; 2015; 11, pp. 2886-2963. [DOI: https://dx.doi.org/10.15376/biores.11.1.2886-2963]

73. Song, S.; Wu, Z.; Nie, J. Paper fillers innovations: From design of particles to preparing filler composites. BioResources; 2020; 15, 2117. [DOI: https://dx.doi.org/10.15376/biores.15.2.2117-2118]

74. DeArmitt, C. Functional Fillers for Plastics. Applied Plastics Engineering Handbook: Processing, Materials, and Applications; Kutz, M. Elsevier Inc.: Amsterdam, The Netherlands, 2017.

75. Hubbe, M.A.; Gill, R.A. Filler particle shape vs. paper properties—A review. Proceedings of the Spring Technical and International Environmental Conference; Altlanta, GA, USA, 3–5 May2004.

76. Ningbo Jiahe New Materials Technology Ltd. Pyrophyllite Powder Used as fillers for Rubber and Paper Production for sale. Available online: http://nbjiahe.sell.everychina.com/p-107503386-pyrophyllite-powder-used-as-fillers-for-rubber-and-paper-production.html (accessed on 13 June 2021).

77. McHaffie, I.W.; Buckley, R.W. Industrial Minerals and Rocks of Victoria; Department of Agriculture, Energy & Minerals: Victoria, Australia, 1995.

78. Vanderbilt Minerals LLC. Filler Minerals Reference A Guide to Filler Properties and Uses; Vanderbilt Minerals LLC: Norwalk, CT, USA, 2013.

79. Indian Bureau of Mines. Indian Minerals Yearbook 2019 (Part-III: Mineral Reviews); IBM: Nagpur, India, 2019.

80. Indian Bureau of Mines. Indian Minerals Yearbook 2017; IBM: Nagpur, India, 2018; Volume 2017.

81. Belzunces, B.; Hoyau, S.; Benoit, M.; Tarrat, N.; Bessac, F. Theoretical study of the atrazine pesticide interaction with pyrophyllite and Ca2+-montmorillonite clay surfaces. J. Comput. Chem.; 2016; 38, pp. 133-143. [DOI: https://dx.doi.org/10.1002/jcc.24530]

82. Murtić, S.; Zahirović, Ć.; Karić, L.; Jurković, J.; Čivić, H.; Sijahović, E. Use of pyrophyllite as soil conditioner in lettuce production. Nat. Environ. Pollut. Technol.; 2020; 19, pp. 355-359.

83. Murtić, S.; Čivić, H.; Sijahović, E.; Koleška, I.; Jurković, J.; Tvica, M. Use of pyrophyllite to reduce heavy metals mobility in a soil environment. Agron. Res.; 2020; 18, pp. 194-205. [DOI: https://dx.doi.org/10.15159/AR.20.009]

84. Djakfar, L.; Bowoputro, H.; Zaika, Y. Evaluation of the use of steel slag and pyrophyllite materials in the porous asphaltmix. Middle East J. Sci. Res.; 2013; 18, pp. 1524-1529. [DOI: https://dx.doi.org/10.5829/idosi.mejsr.2013.18.11.12423]

85. Statistik, B.P. Surface and Interface Chemistry of Clay Minerals. Developments in Clay Science; Elsevier B.V.: Amsterdam, The Netherlands, 2014; Volume 9, pp. 1-410.

86. Xu, X.; Tang, Z.; Zhang, S.; Mo, S. Application of Modified pyrophyllite in rubber. China Synt. Rubber Ind.; 1998; 21, 3.

87. Erdemoğlu, M.; Erdemoğlu, S.; Sayılkan, F.; Akarsu, M.; Şener, Ş.; Sayılkan, H. Organo-functional modified pyrophyllite: Preparation, characterisation and Pb(II) ion adsorption property. Appl. Clay Sci.; 2004; 27, pp. 41-52. [DOI: https://dx.doi.org/10.1016/j.clay.2003.12.005]

88. Adamović, M.J.; Stojanović, M.D.; Harbinja, M.M.; Maslovarić, M.D.; Bočarov-Stančić, A.S.; Pezo, L.L. Efficiency investigation of the use of pyrophyllite in ensiling maize plant. Food Feed. Res.; 2020; 47, pp. 109-118. [DOI: https://dx.doi.org/10.5937/ffr47-29445]

89. Surya, I.; Muniyadi, M.; Ismail, H. A review on clay-reinforced ethylene propylene diene terpolymer composites. Polym. Compos.; 2021; [DOI: https://dx.doi.org/10.1002/pc.25956]

90. Zhai, J.; Chen, P.; Wang, H.; Hu, Y.; Sun, W. Flotability Improvement of Ilmenite Using Attrition-Scrubbing as a Pretreatment Method. Minerals; 2017; 7, 13. [DOI: https://dx.doi.org/10.3390/min7010013]

91. El Gaidoumi, A.; Rodríguez, J.M.D.; Melián, E.P.; González-Díaz, O.M.; Santos, J.A.N.; El Bali, B.; Kherbeche, A. Synthesis of sol-gel pyrophyllite/TiO2 heterostructures: Effect of calcination temperature and methanol washing on photocatalytic activity. Surf. Interfaces; 2018; 14, pp. 19-25. [DOI: https://dx.doi.org/10.1016/j.surfin.2018.10.003]

92. Huang, Z.; Zhong, H.; Wang, S.; Xia, L.; Zhao, G.; Liu, G. Gemini trisiloxane surfactant: Synthesis and flotation of aluminosilicate minerals. Miner. Eng.; 2014; 56, pp. 145-154. [DOI: https://dx.doi.org/10.1016/j.mineng.2013.11.006]

93. Erdemoğlu, M.; Birinci, M.; Uysal, T.; Tüzer, E.P.; Barry, T.S. Mechanical activation of pyrophyllite ore for aluminum extraction by acidic leaching. J. Mater. Sci.; 2018; 53, pp. 13801-13812. [DOI: https://dx.doi.org/10.1007/s10853-018-2606-8]

94. Erdemoğlu, M.; Birinci, M. Enrichment of pütürge (malatya, turkey) low-grade pyrophyllite ore by attrition-scrubbing and flotation. Proceedings of the 15th International Mineral Processing Symposium; Istanbul, Turkey, 19–21 October 2016.

95. Andji, J.; Toure, A.A.; Kra, G.; Jumas, J.; Yvon, J.; Blanchart, P. Iron role on mechanical properties of ceramics with clays from Ivory Coast. Ceram. Int.; 2009; 35, pp. 571-577. [DOI: https://dx.doi.org/10.1016/j.ceramint.2008.01.007]

96. Ferreira, D.P. Structural Iron Removal from Clays Used in Ceramic Industries; University of Coimbra: Coimbra, Portugal, 2017.

97. Lin, R.; Howard, B.H.; Roth, E.; Bank, T.L.; Granite, E.J.; Soong, Y. Enrichment of rare earth elements from coal and coal by-products by physical separations. Fuel; 2017; 200, pp. 506-520. [DOI: https://dx.doi.org/10.1016/j.fuel.2017.03.096]

98. Zhao, K.; Wang, X.; Wang, Z.; Yan, W.; Zhou, X.; Xu, L.; Wang, C. A novel depressant for selective flotation separation of pyrite and pyrophyllite. Appl. Surf. Sci.; 2019; 487, pp. 9-16. [DOI: https://dx.doi.org/10.1016/j.apsusc.2019.04.252]

99. Zhao, K.; Wang, X.; Yan, W.; Gu, G.; Wang, C.; Wang, Z.; Xu, L.; Peng, T. Depression mechanism of pyrophyllite by a novel polysaccharide xanthan gum. Miner. Eng.; 2018; 132, pp. 134-141. [DOI: https://dx.doi.org/10.1016/j.mineng.2018.11.047]

100. Zhao, S.; Wang, D.; Hu, Y.; Liu, B.; Xu, J. The flotation behaviour of N-(3-aminopropyl)-dodecanamide on three aluminosilicates. Miner. Eng.; 2003; 16, pp. 1391-1395. [DOI: https://dx.doi.org/10.1016/j.mineng.2003.09.002]

101. Erdemoǧlu, M.; Sarikaya, M.; Sarıkaya, M.; Erdemoglu, M. The effect of grinding on pyrophyllite flotation. Miner. Eng.; 2002; 15, pp. 723-725. [DOI: https://dx.doi.org/10.1016/S0892-6875(02)00210-8]

102. Zhao, K.; Gu, G.; Yan, W.; Wang, X.; Wang, C.; Xu, L. Flotation of fine pyrite by using N-dodecyl mercaptan as collector in natural pH pulp. J. Mater. Res. Technol.; 2019; 8, pp. 1571-1575. [DOI: https://dx.doi.org/10.1016/j.jmrt.2018.05.002]

103. Jiang, X.; Zhou, L.; Liu, J.; Han, X. A model on attrition of quartzite particles as a bed material in fluidized beds. Powder Technol.; 2009; 195, pp. 44-49. [DOI: https://dx.doi.org/10.1016/j.powtec.2009.05.009]

104. Adelsmayr, T. Investigations on Raw Material Samples of European Deposits for the Application in Plastics; Montanuniversität Leoben University: Leoben, Austria, 2014.

105. Lee, S.-O.; Kim, W.-T.; Oh, J.-K.; Shin, B.-S. Iron-removal of Clay Mineral with Oxalic Acid. Shigen-to-Sozai; 1997; 113, pp. 847-851. [DOI: https://dx.doi.org/10.2473/shigentosozai.113.847]

106. Kar, B.; Sahoo, H.; Rath, S.S.; Rao, D.S.; Das, B. Characterization and beneficiation studies for the removal of iron from a china clay from India. Clay Miner.; 2013; 48, pp. 759-769. [DOI: https://dx.doi.org/10.1180/claymin.2013.048.5.08]

107. Das, M.; Chakrabarti, S.; Ghosh, S.; Ghatak, T.K.; Mukhopadhaya, A. Process of Beneficiation of Pyrophyllite for Increasing Brightness Value Above 80; Springer: Cham, Switzerland, 2003.

108. Jian, Z. Process for Whitening Pyrophyllite Micro Powder. Patent; CN102061108A, 19 November 2010.

109. Arslan, V. A study on the dissolution kinetics of iron oxide leaching from clays by oxalic acid. Physicochem. Probl. Miner. Process.; 2021; 57, pp. 97-111. [DOI: https://dx.doi.org/10.37190/ppmp/135749]