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Abstract
Ecologically friendly wood electronics will help alleviating the shortcomings of state-of-art cellulose-based “green electronics”. Here we introduce iron-catalyzed laser-induced graphitization (IC-LIG) as an innovative approach for engraving large-scale electrically conductive structures on wood with very high quality and efficiency, overcoming the limitations of conventional LIG including high ablation, thermal damages, need for multiple lasing steps, use of fire retardants and inert atmospheres. An aqueous bio-based coating, inspired by historical iron-gall ink, protects wood from laser ablation and thermal damage while promoting efficient graphitization and smoothening substrate irregularities. Large-scale (100 cm2), highly conductive (≥2500 S m−1) and homogeneous surface areas are engraved single-step in ambient atmosphere with a conventional CO2 laser, even on very thin (∼450 µm) wood veneers. We demonstrate the validity of our approach by turning wood into highly durable strain sensors, flexible electrodes, capacitive touch panels and an electroluminescent LIG-based device.
Ecologically friendly wood electronics will help alleviating the shortcomings of state-of-art cellulose-based green electronics. Here, the authors introduce iron-catalyzed laser-induced graphitization (IC-LIG) as an innovative approach for engraving large-scale electrically conductive structures on wood with high quality and efficiency.
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1 Wood Materials Science, Institute for Building Materials, ETH Zürich, Zürich, Switzerland (GRID:grid.5801.c) (ISNI:0000 0001 2156 2780); Cellulose & Wood Materials Laboratory, Empa, Dübendorf, Switzerland (GRID:grid.7354.5) (ISNI:0000 0001 2331 3059)
2 Wood Materials Science, Institute for Building Materials, ETH Zürich, Zürich, Switzerland (GRID:grid.5801.c) (ISNI:0000 0001 2156 2780)
3 Laboratory of Adhesives and Polymer Materials, Institute of Materials and Process Engineering, ZHAW Zürich University of Applied Sciences, Winterthur, Switzerland (GRID:grid.19739.35) (ISNI:0000000122291644); ETH Zürich, Multifunctional Materials, Department of Materials, Zürich, Switzerland (GRID:grid.5801.c) (ISNI:0000 0001 2156 2780)
4 ETH Zürich, Complex Materials, Department of Materials, Zürich, Switzerland (GRID:grid.5801.c) (ISNI:0000 0001 2156 2780); University of Stuttgart, High Enthalpy Flow Diagnostics Group, Institute of Space Systems, Stuttgart, Germany (GRID:grid.5719.a) (ISNI:0000 0004 1936 9713)