Abstract

Silicon nanocrystals (SiNPs) are an extensively studied light-emitting material due to their inherent biocompatibility and easy integration with silicon-based technology. Although low luminescence quantum yields of as-prepared SiNPs, the exploitation of the surface chemistry of SiNPs plays a key role in tuning their luminescence. In this work, the development of SiNPs as active materials for innovative LEDs was investigated. SiNPs were synthesized by using laser pyrolysis, a very flexible tool for lab-scale production in developmental quantities. The synthesized SiNPs have dimensions from 5 to 15 nm and high purity grade but show weak luminescence. For this reason, chemical treatments were performed on SiNPs: surface modifications lead to an improvement of their luminescence properties. Chemical and optical characterization were performed by conventional and advanced techniques, such as FTIR, BET, UV-VIS absorption and emission, XPS, TEM and confocal Raman. A Life Cycle Assessment (LCA) study of laser synthesis of SiNPs was conducted with the aim to identify the potential environmental impacts coming from this production method.

Details

Title
Silicon nanoparticles as active materials for LED: laser synthesis and functionalization for tuning luminescence
Author
R D’Amato 1 ; S Dello Iacono 2 ; Santoni, A 1 ; Reale, P 1 ; Limosani, F 1 ; Terranova, G 1 ; Botti, S 1 ; Bonfigli, F 1 ; Migliori, A 3 ; Scalbi, S 4 

 Photonics Micro and Nanostructures Laboratory, Fusion and Technologies for Nuclear Safety and Security Department, Physical Technologies for Safety and Health Division , ENEA, C.R. Frascati , Italy 
 Photonics Micro and Nanostructures Laboratory, Fusion and Technologies for Nuclear Safety and Security Department, Physical Technologies for Safety and Health Division , ENEA, C.R. Frascati , Italy; Institute of Applied Sciences & Intelligent System “Eduardo Caianiello” (ISASI) , CNR, Napoli , Italy 
 Institute for microelectronics and microsystems (IMM) , CNR, Bologna , Italy 
 Laboratory Resources valorization, Department for Sustainability, Division Resource Efficiency , ENEA C.R. Bologna , Italy 
First page
012002
Publication year
2022
Publication date
Jul 2022
Publisher
IOP Publishing
ISSN
17426588
e-ISSN
17426596
Source type
Scholarly Journal
Language of publication
English
ProQuest document ID
2696122622
Copyright
Published under licence by IOP Publishing Ltd. This work is published under http://creativecommons.org/licenses/by/3.0/ (the “License”). Notwithstanding the ProQuest Terms and Conditions, you may use this content in accordance with the terms of the License.