Electrochemical Impedance Spectroscopy study on ammonia-fed Solid Oxide Fuel Cells

Abstract

The use of ammonia as a fuel is one of the promising pathways to decarbonize the energy sector. When ammonia is converted into power in the so-called “Ammonia-to-Power”, the most interesting technology is the Solid Oxide Fuel Cell (SOFC) that can operate directly with ammonia and reach high performance in terms of efficiency. SOFCs are a high-efficiency and, potentially, low-cost technology, but still suffer from degradation issues related to internal losses. An innovative experimental technique to evaluate losses evolution caused by degradation is electrical impedance spectroscopy (EIS), followed by measurement data post-processing through the Distribution of Relaxation Times (DRT) analysis. In this study, a single SOFC is studied with a combined EIS and DRT methodology, when operating with a gas mixture of hydrogen, nitrogen and ammonia. The results identify the contribution to DRT of fuel dilution and the internal ammonia decomposition reaction.