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Estuaries are excellent containers for the prehistorical and historical pollution that develops in their river basins. This paper studies the Au contents obtained by inductively coupled plasma spectrometry of two cores extracted from the Doñana National Park (Guadalquivir Estuary, SW Spain). Concentrations of this precious metal have been associated with the different prehistoric and historical stages of exploitation of the Iberian Pyritic Belt. The three detected peaks correspond to the first mining operations in the area around the park, the first systematic Tartessian mining and strong exploitation during the Roman period. Consequently, Au is an appropriate marker of the contamination phases prior to its current extraordinary biological diversity.
Details
National parks;
River basins;
Spectrometry;
Holocene;
Gold;
Recent sediments;
Heavy metals;
Estuaries;
Soil erosion;
Mining;
Laboratories;
Estuarine dynamics;
Water analysis;
Metal concentrations;
Sediments;
Pollution;
Historical metallurgy;
Geology;
Inductively coupled plasma;
Tracers;
Exploitation;
Tsunamis;
Biodiversity
; González-Regalado, María Luz 1 ; Carretero, María Isabel 3 ; Pozo, Manuel 4
; Monge Guadalupe 4
; Cáceres, Luis Miguel 1
; Vidal, Joaquín Rodríguez 5 ; Abad, Manuel 6
; Izquierdo, Tatiana 6
; Toscano, Antonio 1 ; Gómez, Paula 1 ; Gómez, Gabriel 1 1 Departamento de Ciencias de la Tierra, Universidad de Huelva, Avda. 3 de Marzo, s/n, 21720 Huelva, Spain; [email protected] (V.R.); [email protected] (M.L.G.-R.); [email protected] (L.M.C.); [email protected] (J.R.V.); [email protected] (A.T.); [email protected] (P.G.); [email protected] (G.G.)
2 Departamento de Ciencias de la Tierra, Universidad de Huelva, Avda. 3 de Marzo, s/n, 21720 Huelva, Spain; [email protected] (V.R.); [email protected] (M.L.G.-R.); [email protected] (L.M.C.); [email protected] (J.R.V.); [email protected] (A.T.); [email protected] (P.G.); [email protected] (G.G.), Centro de Investigación en Patrimonio Histórico, Cultural y Natural, Universidad de Huelva, Campus Universitario de El Carmen, 21720 Huelva, Spain
3 Departamento de Cristalografía, Mineralogía y Química Agrícola, Universidad de Sevilla, C/Profesor García González, s/n, 41012 Sevilla, Spain; [email protected]
4 Departamento de Geología y Geoquímica, Universidad Autónoma de Madrid, 28049 Madrid, Spain; [email protected] (M.P.); [email protected] (G.M.)
5 Departamento de Ciencias de la Tierra, Universidad de Huelva, Avda. 3 de Marzo, s/n, 21720 Huelva, Spain; [email protected] (V.R.); [email protected] (M.L.G.-R.); [email protected] (L.M.C.); [email protected] (J.R.V.); [email protected] (A.T.); [email protected] (P.G.); [email protected] (G.G.), Gibraltar Natural Museum, Parson’s Lodge Battery, Rosia Rd, Gibraltar GX11 1AA, Gibraltar
6 Departamento de Biología y Geología, Física y Química Inorgánica, Escuela Superior de Ciencias Experimentales y Tecnología (ESCET), Universidad Rey Juan Carlos, c/Tulipán s/n, 28933 Móstoles, Spain; [email protected] (M.A.); [email protected] (T.I.)