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Abstract

Well-killing operations in water-sensitive hydrophilic formations are often complicated by extended well clean-up periods and, in some cases, failure to restore the well’s production potential post-kill. Typical development targets exhibiting these properties include the Neocomian and Jurassic deposits of fields in Western Siberia and Western Kazakhstan. This paper proposes a well-killing method incorporating simultaneous near-wellbore treatment. In cases where heavy oil components (asphaltenes, resins, or paraffins) are deposited in the near-wellbore zone, their removal with a solvent results in post-operation flow rates that exceed pre-restoration levels. For wells not affected by asphaltene, resin, and paraffin deposits, killing is performed using a blocking pill of invert emulsion stabilized with an emulsifier and hydrophobic nanosilica. During filtration into the formation, this emulsion does not break but rather reforms according to the pore throat sizes. Flow rates in such wells typically match pre-restoration levels. The described engineering solution proves less effective when the well fluid water cut exceeds 60%. For wells exhibiting premature water breakthrough that have not yet produced their estimated oil volume, the water source is identified, and water shutoff operations are conducted. This involves polymer-gel systems crosslinked with resorcinol and paraform, reinforced with inorganic components such as chrysotile microdispersions, micro- and nanodispersions of shungite mineral, and gas black. Oscillation testing identified the optimal additive concentration range of 0.6–0.7 wt%, resulting in a complex modulus increase of up to 25.7%. The most effective polymer-inorganic composite developed by us, incorporating gas black, demonstrates high water shutoff capability (residual resistance factor ranges from 12.5 to 65.0 units within the permeability interval of 151.7 to 10.5 mD). Furthermore, the developed composites exhibit the ability to selectively reduce water permeability disproportionately more than oil permeability. Filtration tests confirmed that the residual permeability to oil after placing the blocking composition with graphene is 6.75 times higher than that to water. Consequently, such treatments reduce the well water cut. Field trials confirmed the effectiveness of the developed polymer-inorganic composite systems.

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Title
Engineering and Technological Approaches to Well Killing in Hydrophilic Formations with Simultaneous Oil Production Enhancement and Water Shutoff Using Selective Polymer-Inorganic Composites
Author
Meshalkin Valery 1   VIAFID ORCID Logo  ; Asadullin Rustem 2 ; Vezhnin Sergey 3 ; Voloshin, Alexander 4   VIAFID ORCID Logo  ; Gallyamova Rida 4   VIAFID ORCID Logo  ; Annaguly, Deryaev 5   VIAFID ORCID Logo  ; Dokichev Vladimir 4   VIAFID ORCID Logo  ; Eshmuratov Anvar 6   VIAFID ORCID Logo  ; Lenchenkova Lyubov 2   VIAFID ORCID Logo  ; Pavlik Artem 2   VIAFID ORCID Logo  ; Politov Anatoly 7 ; Ragulin Victor 3 ; Danabek, Saduakassov 8   VIAFID ORCID Logo  ; Safarov Farit 3   VIAFID ORCID Logo  ; Maksat, Tabylganov 8   VIAFID ORCID Logo  ; Telin Aleksey 3   VIAFID ORCID Logo  ; Yakubov Ravil 2   VIAFID ORCID Logo 

 Department of Logistics and Economic Informatics, International Institute of Resource Saving Logistics and Technological Innovation, Dmitry Mendeleev University of Chemical Technology of Russia, 9 Miusskaya Square, 125047 Moscow, Russia, World-Class Laboratory “LaMiUr”, Saint-Petersburg State Institute of Technology, Moscow Prosp. 24-26/49, 190013 Saint-Petersburg, Russia 
 Faculty of Mining and Petroleum, Ufa State Petroleum Technological University, 1 Kosmonavtov Street, 450064 Ufa, [email protected] (A.P.); 
 Ufa Scientific and Technical Center, LLC, 99/3 Kirova Street, 450078 Ufa, Russia 
 Ufa Institute of Chemistry, Ufa Federal Research Center, Russian Academy of Sciences, 71 Oktyabrya Avenue, 450054 Ufa, Russia; [email protected] (A.V.); [email protected] (R.G.); 
 Department of Well Drilling, Scientific Research Institute of Natural Gas of the State Concern “Turkmengas”, Ashgabat 744000, Turkmenistan 
 Department of Geodesy, Cartography and Natural Resources, Karakalpak State University, Nukus 230100, Uzbekistan 
 Institute of Solid State Chemistry and Mechanochemistry of Siberian Branch RAS, 18 Kutateladze Street, 630128 Novosibirsk, Russia 
 Department of Petrochemical Engineering, S. Yessenov Caspian University of Technologies and Engineering, 1 Microdistrict 32, Aktau 130000, Kazakhstan; [email protected] (D.S.); 
Publication title
Energies; Basel
Volume
18
Issue
17
First page
4721
Number of pages
28
Publication year
2025
Publication date
2025
Publisher
MDPI AG
Place of publication
Basel
Country of publication
Switzerland
Publication subject
e-ISSN
19961073
Source type
Scholarly Journal
Language of publication
English
Document type
Journal Article
Publication history
 
 
Online publication date
2025-09-04
Milestone dates
2025-07-29 (Received); 2025-09-03 (Accepted)
Publication history
 
 
   First posting date
04 Sep 2025
ProQuest document ID
3249685020
Document URL
https://www.proquest.com/scholarly-journals/engineering-technological-approaches-well-killing/docview/3249685020/se-2?accountid=208611
Copyright
© 2025 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/). Notwithstanding the ProQuest Terms and Conditions, you may use this content in accordance with the terms of the License.
Last updated
2025-09-12
Database
ProQuest One Academic