Mineralogical Characteristics and Color Genesis of Vesuvianite Jade from Hanzhong, Shaanxi Province, China

Abstract

A new type of vesuvianite jade has recently been discovered in Hanzhong City, Shaanxi Province, China. However, a systematic investigation into its mineralogical characteristics and the origin of its color is currently lacking. In this study, the gemological, mineralogical, and spectroscopic properties of the Hanzhong vesuvianite jade were comprehensively analyzed using a suite of modern analytical techniques, including standard gemological testing, polarizing microscopy, X-ray powder diffraction, Fourier-transform infrared spectroscopy, laser Raman spectroscopy, UV-visible absorption spectroscopy, and X-ray fluorescence spectroscopy. The origin of the jade’s color was also preliminarily investigated. The results indicate that the samples are primarily composed of vesuvianite, with associated minerals including minor amounts of grossular, chlorite, and diopside, and trace amounts of calcite, epidote, chromite, and titanite. The pale green patches consist mainly of chlorite and grossular, the dark green bands are predominantly chlorite, and the dark brown patches are composed of abundant, disseminated microcrystalline chromite intermixed with uvarovite (calcium chromium garnet). The major chemical components of the vesuvianite jade matrix are SiO₂, Al₂O₃, and CaO. Specifically, SiO₂ ranges from 37.01 to 38.54 wt.%, Al₂O₃ from 18.48 to 22.84 wt.%, and CaO from 37.16 to 40.04 wt.%. Minor amounts include MgO (0.76–4.39 wt.%) and FeO_T (total iron expressed as FeO, 0.56–2.09 wt.%). The yellowish-green color of the matrix originates from a combination of ligand-to-metal charge transfer of Fe³⁺, crystal field transitions of Fe³⁺, and intervalence charge transfer between Fe²⁺ and Fe³⁺ in vesuvianite. The emerald-green color of the patches results from the synergistic effect of Fe and Cr; Fe provides a yellowish-green background color, upon which the crystal field transitions of Cr³⁺ (indicated by a doublet at 686/696 nm) impose strong absorption in the red region, resulting in a more vivid green hue.