1. Introduction
Ammonia (NH3) is an inorganic compound composed of nitrogen and hydrogen, widely used in various sectors such as agriculture, the refrigeration industry, and chemical plants. In modern agriculture, ammonia is a key component in the production of nitrogen-based fertilizers, such as urea, ammonium nitrate, and ammonium sulfate. These fertilizers are essential for global agriculture, supporting food production and security. In the refrigeration industry, ammonia is used due to its high latent heat of vaporization, meaning that it can absorb large amounts of heat during phase change. This characteristic allows the use of a smaller amount of refrigerant compared to other substances, reducing acquisition costs and equipment size, thereby lowering the energy consumption and operational costs of these systems. Additionally, unlike many synthetic refrigerants, ammonia does not contribute to global warming or ozone layer depletion. Its use is aligned with international environmental regulations, making it a sustainable alternative for the industrial sector [1,2].
Other applications of ammonia include chemical synthesis and neutralization. Ammonia is used as a precursor in the production of nitric acid, which is further utilized to make explosives and plastics [3]. It is also a key ingredient in the synthesis of caprolactam, a raw material for nylon production [4], and it serves as a base to neutralize strongly acidic solutions, such as sulfuric acid, resulting in the formation of ammonium salts like ammonium sulfate [5].
Despite its utility, ammonia is a common pollutant found in wastewater, typically originating from agricultural runoff, industrial discharges, and domestic sewage [6]. Furthermore, ammonia poses significant risks, such as flammability, toxicity, and reactivity, which require rigorous measures to protect workers’ health and ensure facility safety [7].
From a flammability perspective, ammonia is classified as a flammable fluid, although its flammability occurs within a very limited range. Under atmospheric pressure, the flammability limits of ammonia in air range between 15–16% (Lower Flammability Limit—LFL) and 25–28% (Upper Flammability Limit—UFL), with an ignition temperature of 651 °C. These limits, combined with ammonia’s low heat of combustion, significantly reduce its flammable potential. According to the ANSI/ASHRAE 34-2007 standard, ammonia is classified in Group B2, which includes highly toxic and low-flammability fluids [8]. Additionally, the flammable potential of an ammonia-air mixture can be altered by various factors, including pressure, temperature, turbulence, the power of the ignition source, and the presence of other components [9].
Ammonia is a highly volatile substance, and when released into the environment, it can quickly form vapors that are dangerous if inhaled at high concentrations; it can also cause harm through skin or eye contact. Exposure to low concentrations, such as in poorly ventilated industrial environments, can cause irritation to the eyes, nose, and throat, accompanied by coughing and difficulty breathing. At higher concentrations, ammonia can cause severe lung damage, leading to pulmonary edema, asphyxiation, and even death. The World Health Organization (WHO) and other regulatory agencies define occupational exposure limits for ammonia. For example, the Permissible Exposure Limit (PEL) set by OSHA (Occupational Safety and Health Administration) is 50 ppm (parts per million) as an eight-hour time-weighted average. Exposures above 300 ppm are considered Immediately Dangerous to Life and Health (IDLH) [10].
Another critical aspect is ammonia’s reactivity with specific materials, such as metals and oxidizing agents. Violent chemical reactions can occur if it comes into contact with incompatible substances, releasing heat and toxic gases. Therefore, proper storage and prevention of cross-contamination are essential to avoid accidents [11].
Moreover, although ammonia itself does not contribute to global warming or ozone depletion, its production process can have a carbon footprint, and its indirect effects (e.g., formation of N2O) must be considered. The production of ammonia is primarily done through the Haber-Bosch process, which combines nitrogen from the air with hydrogen derived from natural gas (methane, CH4). This process is highly energy-intensive and relies heavily on fossil fuels, which release CO2 during combustion. As a result, the production of ammonia is associated with significant carbon emissions. For example, the global ammonia industry is responsible for approximately 2% of global CO2 emissions, making it a contributor to climate change indirectly through its production process [12].
As discussed, the use of ammonia presents several challenges, particularly related to its toxicity and flammability. Ammonia leaks can pose risks to human health and the environment, requiring robust safety systems that include continuous ammonia detectors, appropriate ventilation systems, and training for operational teams to handle emergencies. Given these challenges, the precise, continuous, and reliable monitoring of ammonia has become a priority for industries and regulatory authorities. For example, the guiding document for refrigeration system design, ANSI/ASHRAE Standard 15-2007, establishes safety requirements for refrigeration systems [13]. According to the standard, it is recommended to use ammonia detectors within the machinery room to protect personnel and property. Through continuous monitoring of ammonia concentration in the machinery room, alarms and protective control actions can be triggered when certain levels are reached. Proper selection, location, and operation/maintenance of ammonia detectors are essential for machinery room safety.
In this context, the Internet of Things (IoT) emerges as a revolutionary technology capable of monitoring ammonia and other toxic gases in real time [14]. IoT integrates smart sensors, wireless connectivity, real-time data processing, and advanced analytics to create autonomous and integrated monitoring systems. For gas monitoring, an IoT architecture is typically structured into three layers: the perception layer, the network layer, and the application layer. The perception layer comprises gas sensors, microcontrollers, and auxiliary sensors (e.g., for temperature and humidity). The network layer encompasses communication technologies such as Wi-Fi, Bluetooth, and LoRaWAN. Finally, the application layer includes IoT platforms for user interfaces, data visualization, data storage, and control logic. These systems enable the continuous collection of environmental data, the transmission of information to centralized platforms, and the generation of immediate alerts in case of dangerous ammonia concentrations.
Due to the importance of ammonia sensors, a large number of scientific publications are reported in the literature, and their classification has been developed considering, for example, types of sensors [15,16,17], materials [18,19,20,21], and applications [22,23]. However, to our knowledge, there is no comprehensive review available of ammonia monitoring systems based on the IoT. This systematic review article aims to provide a comprehensive and up-to-date overview of the use of IoT technologies for ammonia sensing, highlighting recent advancements, practical applications, and the challenges faced. The review covers studies published in recent years, focusing on sensors, microcontrollers, wireless communication techniques, IoT platforms, and applications across various sectors. By exploring the state of the art in ammonia sensing through IoT, this article seeks to contribute to the advancement of industrial safety, environmental protection, and operational efficiency. This systematic review provides valuable insights for researchers, engineers, and managers interested in implementing IoT solutions for ammonia monitoring, highlighting best practices, technological innovations, and opportunities for improvement. In an increasingly connected and data-driven world, IoT represents a powerful tool to address the challenges associated with ammonia management, promoting a safer and more sustainable future for industries and the communities that depend on them.
2. Materials and Methods
The methodology employed in this work was adapted from the Preferred Reporting Items for Systematic Reviews and Meta-Analyses (PRISMA) guidelines [24]. The process consisted of formulating research questions, followed by identification, screening, and eligibility stages. In the identification stage, relevant databases and keywords were selected. The screening stage involved applying inclusion and exclusion criteria based on titles and abstracts. Finally, in the eligibility stage, the full texts of the remaining papers were analyzed. Answers to the initial research questions were synthesized to identify limitations and gaps in the current knowledge and to propose directions for future research.
2.1. Research Questions
The research questions were formulated to identify the main technologies employed for IoT-based ammonia detection. The synthesized information provides an overview of these technologies, highlighting the main challenges and opportunities, and suggests directions for future research.
The review is guided by the following questions: Query 1: What types of sensors are employed for the detection and monitoring of ammonia gas? Query 2: Which microcontrollers are typically utilized to interface with ammonia gas sensors and facilitate data acquisition? Query 3: What communication technologies are commonly implemented to transmit data from these sensor systems? Query 4: What IoT platforms are predominantly used for the visualization and analysis of data collected from ammonia gas sensor systems? Query 5: What are the primary applications of ammonia gas sensors integrated with IoT technologies?
2.2. Search Process
The search was conducted using several databases, including IEEE Xplore, Scopus, and Web of Science. The Boolean operator “AND” was used with the keywords “ammonia” and “IoT”. The following filters were applied directly within each database’s search engine: (a) Publication date between 2015 and 2025, as key IoT standards were consolidated at the beginning of this period [25]. (b) Document type limited to research articles and conference papers. (c) Language restricted to English.
The search, performed in August 2025, yielded 612 records: 188 from IEEE Xplore, 282 from Scopus, and 127 from Web of Science. An additional 15 publications were identified via Google Scholar.
2.3. Inclusion and Exclusion Criteria
Further inclusion and exclusion criteria were applied during the screening stage, as detailed in Table 1. The records from the initial search were exported to Zotero 7.0.22 (64-bit) software, and duplicates were removed, resulting in 403 publications for screening. The titles and abstracts of these publications were analyzed. Papers focused solely on the chemical synthesis and characterization of sensors, or on monitoring gases other than ammonia using IoT, were excluded as they did not address the research questions. Following this stage, 291 publications focused on monitoring ammonia using IoT technologies were selected for the eligibility assessment.
2.4. Study Selection
From the collected publications, the full text manuscripts were assessed for eligibility. During the analysis of the publications, it was observed that not all the paper reported all details about the IoT technology to answer the research questions raised in this review. For this reason, papers that were out of the scope of the research questions were excluded. In this way, 148 publications were included in the revision as shown in Figure 1.
The full texts of the 291 publications were assessed for eligibility. Many publications did not report sufficient information to answer the research questions and were consequently excluded. Papers that reported answers for at least three of the five research questions were included. A final set of 148 publications was included in the qualitative synthesis, as illustrated in the PRISMA flow diagram shown in Figure 1.
2.5. Risk of Bias
Although this systematic review followed the structured PRISMA methodology, several potential sources of bias are discussed. First, the selection of keywords may introduce bias. Using the “AND” operator with many keywords can limit the search, while using “OR” can make it unmanageably broad. To mitigate this, few keyword were tested. Second, the choice of databases (IEEE Xplore, Scopus, Web of Science) may have led to the omission of relevant studies from other sources. To address this, a supplementary search was conducted using Google Scholar. Future reviews could be improved by including additional databases. Finally, bias may arise from the subjective application of inclusion/exclusion criteria during screening and eligibility assessments. All decisions were discussed among the authors in accordance with PRISMA guidelines to minimize this risk.
2.6. Data Extraction and Synthesis
Data were extracted from the 148 included papers to answer the research questions. The extracted information included: sensor type, microcontroller, communication technology, IoT platform, and application domain. The publication type (journal or conference proceeding) and year of publication were also recorded.
Of the publications included, 94 (63.5%) were journal articles and 54 (36.5%) were conference papers as shown in Figure 2a. The earliest relevant publication was from 2017, with the annual number of publications peaking in 2023. The distribution of publications by year from 2017 to 2025 is shown in Figure 2b.
3. Results and Discussion
3.1. Types of Sensors
Ammonia gas sensing methods can be categorized as solid-state, optical, and others. Solid-state sensors are based on changes in the conductivity of a thin film of metal oxide or conducting polymer upon gas exposure. Optical methods rely on the analysis of optical absorption, with tunable diode laser absorption spectroscopy (TDLAS) and cavity ringdown spectroscopy (CRDS) being well-developed techniques. Other sensors, such as electrochemical sensors, surface acoustic wave sensors (SAWS), and field-effect transistor (FET) sensors, are also reported in the literature [16]. Additional methods and reviews on ammonia sensor technology are available [15,17,18].
Methods for sensing ammonia in water, typically for agricultural purposes, can be similarly categorized as electrochemical or spectrometric. Electrochemical methods are based on changes in an electrical variable (resistance, potential, current) due to the absorption of NH3 by a sensing material. Spectrometric methods include optical techniques to analyze absorption, fluorescence, color, and photoacoustic waves [22]. Reviews on electrochemical [26] and spectroscopic methods [27] are available.
From the analysis of the included papers, 122 used commercial sensors, 8 reported non-commercial sensors, and 18 did not specify the sensor type. The results are summarized in Table 2. The non-commercial sensors employed various techniques and materials. Solid-state sensors were fabricated using composites such as antimony-doped tin dioxide (Sb-doped SnO2) with polyaniline (PANI), and reduced graphene oxide (RGO) with tungsten trioxide (WO3) to enhance the sensitivity and selectivity to NH3 and NO2 gases under real mining conditions [28]; an array of 64 chemiresistive sensors based on semiconducting single-walled carbon nanotubes (sc-SWCNTs) [29]; a PANi solution deposited on a copper-clad chip [30]; a MEMS device based on a sputtered SnO2 thin film [31]; graphene decorated with zinc oxide (Graphene@ZnO) and laser-induced graphene decorated with polypyrrole (LIG@Ppy) [32]; and a silicon corrole-functionalized TiZnN2 (SipC-TiZnN)/p-Si heterostructure [33]. An electrochemical sensor (ammonium ion-selective electrode, ISE) was fabricated using poly (vinyl chloride) (PVC), potassium tetrakis (4-chlorophenyl)borate (KtpCIPB), ammonium ionophore I (nonactin), and bis (2-ethylhexyl) sebacate (BEHS) [34]. Finally, a spectrometric method was employed to analyze the color of sodium salicylate [35].
It means that, among the papers reporting the type of sensor—whether commercial or non-commercial—123 papers used solid-state sensors and 6 used electrochemical sensors, representing approximately 83.1% and 4.0% of the total, respectively. Only one paper employed spectroscopic techniques, and 18 papers did not report the sensor technology, representing 0.7% and 12.2%, respectively.
It is important to note that some papers employed more than one type of sensor. The prevalence of solid-state sensors is largely due to their ease of installation and low cost for the reported applications, which are mostly proof-of-concept studies. However, in industrial applications, the use of MQ-family sensors is limited due to operational constraints defined by their specifications. For instance, industrial systems require sensors with high selectivity, low power consumption, low detection limits, and minimal baseline drift. The MQ-135 is an air quality sensor with high sensitivity to ammonia, sulfides, benzene vapors, smoke, and other toxic gases, while the MQ-137 shows high sensitivity to NH3 and can also detect organic amines such as trimethylamine and cholamine. However, these sensors require heating of the metal oxide (SnO2) surface to enable adsorption/desorption reactions. Their typical detection range is 10 to 10,000 ppm, with a limit of detection of about 10 ppm and significant baseline drift over time due to variations in humidity and temperature, thus requiring frequent calibration and temperature compensation [36,37].
In comparison, electrochemical sensors offer better selectivity than solid-state sensors, do not require heating, and can achieve detection limits from low ppm to sub-ppm levels, with lower baseline drift than metal oxide sensors under many conditions, although they still require periodic calibration [38,39,40]. Moreover, electrochemical sensors are widely used in regulatory and occupational monitoring or integrated into professional instruments. In contrast, MQ-family sensors are considerably less expensive than electrochemical sensors.
As shown, the main technology used for ammonia detection is based on commercial SnO2 sensors. However, detection technologies and materials developed for other gases could also be explored for ammonia sensing. For example, in the detection of NOx gases, memristor-based gas sensors—also known as gasistors—have attracted researchers’ attention due to their low energy consumption, compact size, and high response [41,42]. The integration of a filament-based memristor heater with a carbon nanotube sensor for humidity control has resulted in ultra-low power consumption and high sensing accuracy [43]. Furthermore, for the detection of inorganic gases and volatile compounds, thin films of metal oxides such as ZnO and WO3, conducting polymers, and carbon nanotubes, among other materials, have been widely investigated [44,45]. Some of these materials were identified in the present review for ammonia detection; however, several others have not yet been explored. This suggests that future research should include the characterization of new sensing materials and the adaptation of technologies previously used for other gases to improve ammonia detection performance.
Table 2Sensors used in ammonia detectors.
| Sensor Name | Type | Datasheet | References |
|---|---|---|---|
| MQ-135 | Metal Oxide | [36] | [46,47,48,49,50,51,52,53,54,55,56,57,58,59,60,61,62,63,64,65,66,67,68,69,70,71,72,73,74,75,76,77,78,79,80,81,82,83,84,85,86,87,88,89,90,91,92,93,94,95,96,97,98,99,100,101,102,103,104,105,106,107,108,109,110,111,112,113,114,115] |
| MQ-137 | Metal Oxide | [37] | [62,116,117,118,119,120,121,122,123,124,125,126,127,128,129,130,131,132,133,134,135,136,137,138,139,140,141,142,143,144,145,146] |
| MQ-2 | Metal Oxide | [147] | [49,148,149] |
| MQ | [150,151,152,153] | ||
| MiCS-6814 | Metal oxide | [154] | [116,155,156,157,158,159] |
| MiCS-5524 | Metal Oxide | [160] | [161,162] |
| TGS 2602 | Metal Oxide | [163] | [164,165,166] |
| TGS-2444 | Metal Oxide | [167] | [168] |
| ZE03 | Electrochemical | [38] | [169] |
| ME3-NH3 | Electrochemical | [40] | [73] |
| MIX8415 | Electrochemical | [170] | |
| N11 board. NH3 sensor GS +4NH3100 | Electrochemical | [39] | [171,172] |
| Self developed | [28,29,30,31,32,33,34,35] | ||
| N/A | [173,174,175,176,177,178,179,180,181,182,183,184,185,186,187,188,189,190] |
3.2. Microcontrollers
A microcontroller is an integrated circuit comprising a processor, memory, and I/O peripherals on a single chip, designed to control operations in an embedded system. For IoT applications, microcontrollers require wireless capabilities. It is important to note that some microcontrollers lack native wireless technologies, necessitating the use of specific shields or additional modules for IoT applications.
Microprocessors can be classified by various parameters, but classification by core architecture indicates which have native wireless technology embedded. Table 3 classifies the microcontrollers from the selected papers based on core architecture and wireless technology. Of the 148 selected papers, 4 did not specify the microcontroller type, 84 used microcontrollers without native wireless technology, and 60 used those with native wireless technology, representing 2.7%, 56.8%, and 40.5%, respectively. As all papers described IoT systems, this indicates that at least 56.8% employed hybrid configurations using shields or additional modules for wireless communication. Microcontrollers based on the Xtensa (ESP32 and ESP8266) and ARM Cortex-A (Raspberry Pi 3B+/4) architectures were the most employed, either directly or coupled with other microcontrollers, due to their native wireless capabilities.
As observed, the distinction between technologies with and without native wireless connectivity is crucial for understanding trends in microcontroller usage. The Arduino platform, well known since its release during the 2003–2005 period, was commonly used for IoT applications around 2017 through the integration of external shields for wireless communication. This hybrid configuration combined Arduino’s ease of use with the wireless capabilities of other microcontrollers. However, this approach has several disadvantages: the boards are mechanically coupled, increasing overall size and system complexity, and leading to higher energy consumption compared with native wireless technologies, making it a suboptimal option for industrial applications.
At that time, Espressif microcontrollers had already become available on the market, and their use has since become widespread. Among them, the ESP32 has emerged as the most popular choice for IoT and semi-industrial applications due to its low cost, integrated wireless features, and reduced energy consumption, as reported in this literature review for ammonia gas monitoring.
Although there are industrial applications of ESP32 and Arduino in Programmable Logic Controllers (PLCs) [191,192] and Human–Machine Interfaces (HMIs) [193], there remains a gap between the use of these microcontrollers and their integration into industrial gas monitoring systems. It is expected that newer microcontrollers such as the Arduino Portenta (Arduino S.r.l., Monza, Italy) [194], ESP32-S3 (Espressif Systems, Shanghai, China) [195], and STM32 (WB and WL series) (STMicroelectronics, Geneva, Switzerland) [196]—designed to overcome limitations related to reliability, ease of use, and energy efficiency—may increasingly include edge intelligence capabilities, making them a promising area for future research.
3.3. Communication Technology
Communication technology used to transmit and receive data collected by sensors may include both wired and wireless technologies. From the analysis of the included papers in this review, it was observed the use of wired technologies (ethernet) and wireless technologies for short-range (Wi-Fi, bluetooth, zigbee) and medium-range (LoRaWAN) combined to cellular technologies (2G (GSM/GPRS), 4G). A brief comparison is shown in Table 4; more extensive comparisons including technologies like Z-wave, Sigfox, 5G, wirelessHART, 6LoWPAN, and ISA100.11a can be found elsewhere [197,198,199,200,201,202].
As shown in Table 5, of the 148 papers, 89 used only Wi-Fi, 7 used Bluetooth, 4 used LoRaWAN, 1 used Zigbee, 19 used hybrid cellular technologies, 5 used hybrid Wi-Fi technologies, and 2 used Ethernet, accounting for 59.5%, 4.6%, 3%, 0.8%, 7.6%, 3.8%, and 1.5% of the publications, respectively. Furthermore, 21 publications did not report the communication technology used. These results demonstrate the strong prevalence of Wi-Fi for IoT-based ammonia sensing.
3.4. IoT Platforms
An IoT platform serves as an interface between IoT devices and end-users, providing device management, connectivity, services, and data handling. Platforms can be classified by characteristics such as connectivity/device management, data storage/management, data analysis/visualization, development tools, edge/fog computing, integration, service management, and auditing and payment [203]. As sensing applications involve substantial data processing, IoT platforms typically leverage cloud computing, self-hosted systems, or dedicated clusters [204].
The tools used in the selected papers are classified in Table 6. Some tools are hybrid, depending on the application. According to the findings, 51 publications (34.5%) used the Blynk and ThingSpeak cloud platforms, 35 publications (23.6%) referenced 16 other computational tools, and 62 publications (41.9%) did not report any specific IoT platform. These results indicate a preference for the Blynk and ThingSpeak cloud platforms in gas sensing applications.
3.5. Applications
Ammonia gas sensors are utilized across various sectors. Based on the selected papers, applications were categorized as: agriculture, environmental monitoring, industrial safety, aquaculture, smart cities, healthcare, the food industry, and research/laboratory use. As shown in Table 7, the primary categories were agriculture (27.5%), environmental monitoring (33.6%), aquaculture (13.0%), and industrial safety (9.9%). The remaining 21 publications (16.0%) pertained to other categories. These findings highlight the key application areas of ammonia sensing in the agricultural and environmental sectors.
4. Conclusions
This systematic review analyzed ammonia monitoring systems based on the Internet of Things (IoT). The methodology, adapted from the PRISMA guidelines, was applied to evaluate selected papers with a focus on sensors, microcontrollers, communication technologies, IoT platforms, and application domains. The percentage of papers that addressed each research question was 87.8% for Q1 (sensors), 97.3% for Q2 (microcontrollers), 85.8% for Q3 (communication technologies), 58.1% for Q4 (IoT platforms), and 100% for Q5 (applications). The influence of missing or unreported data on conclusions regarding predominant technologies depends on the number of papers providing consistent answers. In this study, when more than 74 papers (50% of the selected set) reported the same technology, it was considered the preferred option. Specifically, for sensor type, the MQ-135 and MQ-137 were cited 70 and 32 times, respectively—corresponding to 68.9% of the selected papers—indicating that MQ-family sensors are the most widely used. Following the same analysis, the results show that the most frequently employed components were MQ-135 and MQ-137 gas sensors; Xtensa-based microcontrollers with native wireless capabilities such as the ESP32 and ESP8266; and Wi-Fi as the main communication technology. Regarding IoT platforms, cloud-based solutions were preferred and cited in 74 papers, with Blynk and ThingSpeak being the most frequently used. However, since 41.9% of the selected papers did not specify the platform used, the conclusion about the predominant platform in ammonia monitoring systems remains limited. Future research should provide detailed information on the platform technologies to allow a more accurate identification of emerging trends. The predominant application domains identified were agriculture and environmental monitoring.
Despite significant advancements, IoT-based ammonia sensing faces technical and operational challenges. Future research should address critical aspects such as sensor accuracy and reliability, which depend on calibration, environmental conditions, and interference from other gases. While most publications demonstrated proof-of-concept systems, information on long-term performance was limited. Temporal analysis is essential for evaluating not only sensor reliability but also factors like mechanical integrity and energy consumption—particularly in battery-operated sensors deployed in locations without a stable power supply.
As IoT technologies evolve, new sensors, microcontrollers, communication methods, and platforms must be evaluated for both existing and emerging applications. Future research should focus on the integration of heterogeneous IoT systems, which often use different protocols and standards, hindering interoperability and consolidated data analysis [205,206]. Integration with other emerging technologies, such as Artificial Intelligence (AI) and machine learning, could further expand potential applications by enabling leak prediction, process optimization, and proactive decision-making [207].
For example, temporal data analysis using AI can improve system reliability prediction by considering environmental variables—such as temperature and humidity—as well as operational parameters, including the presence of interfering gases or dust. Moreover, the use of data from multiple types of sensors or sensing modalities in a multimodal sensor fusion architecture allows for more accurate, reliable, and comprehensive characterization of system performance [208]. In this configuration, including sensors for different gases, machine learning algorithms such as support vector machine (SVM), K-Nearest Neighbor (KNN), Random Forest (RF) and Neural Networks (NN) are used to classify and identify gases, predict concentration, and also model nonlinear patterns [28,209,210,211]. Such approaches are highly valuable not only to detect, identity and quantify the concentration of the gas, but for planning the maintenance of gas monitoring systems and developing automated calibration routines, reducing manual intervention and significantly improving detection accuracy, selectivity, and long-term stability under variable environmental conditions [212]. However, these advancements also introduce new challenges. The integration of AI capabilities directly into edge devices—such as sensors, microcontrollers, or gateways—known as edge intelligence, allows data to be analyzed and processed locally without relying on constant communication with centralized cloud servers [213,214]. This paradigm enables low-latency responses, reduced bandwidth usage, enhanced privacy, and improved energy efficiency, which are essential for scalable and autonomous industrial IoT deployments.
Furthermore, cybersecurity is a critical concern, as IoT systems are vulnerable to attacks that compromise data integrity and system functionality. Consequently, future research should focus on developing: (1) inexpensive encryption algorithms for microcontrollers (e.g., ESP32); (2) blockchain technologies to ensure the integrity of sensor data for compliance, forensic analysis, and dispute resolution; and (3) Zero-Trust Architecture (ZTA), where every device and user request is rigorously authenticated, authorized, and encrypted before being granted access to the network or data, regardless of its origin.
According to the obtained results, Wi-Fi is the main communication technology employed in academic, pilot, or semi-industrial settings; however, these systems often lack full industrial robustness, where factors such as safety, interference, and power consumption are essential for successful long-term operation. Special attention should be given to developing robust infrastructures to enhance safety and ensure system reliability. This includes using commercial sensors, industrial-grade hardware, and Industrial IoT (IIoT) solutions for real-time data transmission, which requires robust communication infrastructure, especially in remote areas or regions with limited network coverage. In this context, the industrial applicability of electrochemical sensors should be investigated more deeply. Additionally, the development of Low-Power Wide-Area Network (LPWAN) technologies, such as LoRaWAN and Narrowband IoT (NB-IoT), is crucial for optimizing data protocols and transmission intervals to maximize battery life in areas without grid power. The recent use of commercial sensors and long-distance communication technologies reported in [171,172] is a promising step in this direction.
Finally, as data from in-situ IoT ammonia sensor studies become more accessible, it is necessary to establish standardized methodologies for testing and validating the performance, reliability, and longevity of these integrated systems under real-world operational stress. This will provide clear guidelines for industry adoption and ensure the deployment of effective and trustworthy monitoring solutions.
Conceptualization, L.A.G.-M.; methodology, A.H.M.C.d.S. and L.A.G.-M.; formal analysis, A.H.M.C.d.S. and L.A.G.-M.; data curation, A.H.M.C.d.S. and L.A.G.-M.; writing-review and editing, A.H.M.C.d.S., M.K.d.S., A.S. and L.A.G.-M.; supervision, L.A.G.-M., funding acquisition, L.A.G.-M. All authors have read and agreed to the published version of the manuscript.
Not applicable.
Data is contained within the article.
During the preparation of this manuscript, the authors used ChatGPT (GPT-5, OpenAI) for the purposes of checking grammar, spelling, and clarity of English language usage. The authors have reviewed and edited the output and take full responsibility for the content of this publication.
Adriel Henrique Monte Claro da Silva and Luis Arturo Gómez-Malagón declare no conflicts of interest. Mikaelle K. da Silva and Augusto Santos are employee of an organization or company (Máximos SMS).
Footnotes
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Figure 1 PRISMA flow diagram.
Figure 2 Distribution of publications by (a) type and (b) publication year.
Inclusion and exclusion criteria used in the screening process.
| Inclusion Criteria | Exclusion Criteria |
|---|---|
| Publications from 2015–2025 | Duplicates |
| Research manuscripts published in journals or conference proceedings | Books, book chapters, reviews, magazines, abstracts |
| Written in English | Written in other languages |
| Within the scope of the research queries | Out of the scope of the research questions |
Microcontrollers used in ammonia detectors.
| Group | Microcontrollers | Native Wireless | References |
|---|---|---|---|
| Xtensa (Espressif) | ESP32: ESP-32 CAM, WROOM-32, Mappi 32, TTGO, Heltec Lora. | Yes (99) | [ |
| ARM Cortex-M | STM32: STM32F103C8T6, STM32F103RCT6, STM32L431RCT6, F401RE, B-L072Z-LRWAN1. | No (11) | [ |
| AVR (8-bit) | ATmega328P: Arduino UNO/Nano. | No (61) | [ |
| ARM Cortex-A | Raspberry Pi 5/4/4B/3B+/2/Zero/pico W | Yes (15) (Raspberry Pi 3B+/4/5) | [ |
| MSP430 (16-bit) | MSP430G2553 | No (1) | [ |
| Hybrid/Special | Waspmote Gases PRO v3 | Yes (2) | [ |
| N/A | [ |
Comparison of wireless technologies [
| Parameter | Wi-Fi * | Bluetooth | ZigBee | LoRaWAN ** [ | 2G (GSM/GPRS) *** [ | 4G (LTE ****) |
|---|---|---|---|---|---|---|
| Range | 100 m | 10 m | 10–100 m | 5 km (Urban) | 500 m–25 km | 15 km |
| Data Rate | 31.4 Mbps | 732 kbps | 20, 40, 250 Kbps | 250 bps-50 kbps | 64 kbps | 100 Mbps-1 Gbps |
| Operating Frequency | 2.4 GHz, 5 GHz | 2.4 GHz | 2.4 GHz, 868 MHz, 915 MHz | 868 MHz, 915 MHz, 430 MHz | 1.8 GHz | 2–8 GHz |
* Wi-Fi: wireless fidelity; ** LoRaWAM: Long Range Wide Area Network; *** GSM/GPRS: GSM: Global System for Mobile communication/General Packet Radio Service; **** LTE: Long Term Evolution.
Communication technologies used in ammonia detectors.
| Communication Technology | References |
|---|---|
| Wi-Fi | [ |
| Bluetooth | [ |
| Lorawan | [ |
| Zigbee | [ |
| Cellular technologies 2G (GSM/GPRS) and 4G. | [ |
| Cellular technologies 2G (GSM/GPRS) and 4G coupled to other technologies (Wi-Fi, zigbee, lorawan, bluetooth, ethernet) | Cellular technologies + Wi-Fi: [ |
| Wi-Fi coupled to others (bluetooth, zigbee, lorawan, ethernet) | Wi-Fi + ethernet: [ |
| Ethernet | [ |
| N/A | [ |
IoT platforms used in ammonia detectors.
| Category | Tool | References |
|---|---|---|
| Cloud platform | Alibaba | [ |
| Aliyun | [ | |
| AWS | [ | |
| Firebase | [ | |
| Losant | [ | |
| Blynk | [ | |
| Blynk/ThingSpeak | [ | |
| Blynk/Thingspeak/AWS | [ | |
| ThingSpeak | [ | |
| VK Cloud | [ | |
| Ubidot | [ | |
| Google Cloud | [ | |
| In.IoT | [ | |
| Kaggle | [ | |
| oneNET | [ | |
| Self-hosted | Grafana | [ |
| Thingsboard | [ | |
| NodeRed | [ | |
| Thinger.io | [ | |
| Other | GoDaddy | [ |
| N/A | [ |
Application of ammonia detectors.
| Category | Applications | References |
|---|---|---|
| Agriculture | Animal farming: chicken farming, poultry farming, rabbitry farming. | [ |
| Environmental | Air and water quality, odor pollution, landfill, sewage and biogas facilities, wastewater management, sewage treatment plant. | [ |
| Industrial Safety | Hazardous area, gas leakage, industrial ambient, mines, industrial sewage outlet. | [ |
| Aquaculture | Aquaculture, aquaponics. | [ |
| Smart Cities | Smart Trash Bin, smart room, manhole, sewers, Subsurface, gas drainage. | [ |
| Healthcare | Medicine, Animal laboratory, Space disinfection, Pet house | [ |
| Food Industry | Freshness food, Food industry. | [ |
| Research & Labs | Laboratory, quality assessment. | [ |
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Abstract
Ammonia is a gas primarily produced for use in agriculture, refrigeration systems, chemical manufacturing, and power generation. Despite its benefits, improper management of ammonia poses significant risks to human health and the environment. Consequently, monitoring ammonia is essential for enhancing industrial safety and preventing leaks that can lead to environmental contamination. Given the abundance and diversity of studies on Internet of Things (IoT) systems for gas detection, the main objective of this paper is to systematically review the literature to identify emerging research trends and opportunities. This review follows the Preferred Reporting Items for Systematic Reviews and Meta-Analyses (PRISMA) methodology, focusing on sensor technologies, microcontrollers, communication technologies, IoT platforms, and applications. The main findings indicate that most studies employed sensors from the MQ family (particularly the MQ-135 and MQ-137), microcontrollers based on the Xtensa architecture (ESP32 and ESP8266) and ARM Cortex-A processors (Raspberry Pi 3B+/4), with Wi-Fi as the predominant communication technology, and Blynk and ThingSpeak as the primary cloud-based IoT platforms. The most frequent applications were agriculture and environmental monitoring. These findings highlight the growing maturity of IoT technologies in ammonia sensing, while also addressing challenges like sensor reliability, energy efficiency, and development of integrated solutions with Artificial Intelligence.
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; da Silva Mikaelle Karoline 2 ; Santos, Augusto 3
; Gómez-Malagón, Luis Arturo 1
1 Polytechnic School of Pernambuco, University of Pernambuco, Recife 50720-001, PE, Brazil; [email protected] (A.H.M.C.d.S.); [email protected] (M.K.d.S.)
2 Polytechnic School of Pernambuco, University of Pernambuco, Recife 50720-001, PE, Brazil; [email protected] (A.H.M.C.d.S.); [email protected] (M.K.d.S.), Máximo SMS, Recife 52051-305, PE, Brazil; [email protected]
3 Máximo SMS, Recife 52051-305, PE, Brazil; [email protected]





