Abstract

The synthesis of a set of 1-aryl-2-aryl(3-pyridyl)ethanones 1-5 and thecorresponding ketoximes 6-9 is reported. Structural studies of oximes 6, 7 and 9 wereperformed in solution using 1H-NMR and in the solid state by X-ray crystallography,providing evidence of H-bonding networks. The crystal packing was controlled byhomomeric intermolecular oxime***oxime H-bond interactions for 6 and cooperativeoxime***N(pyridyl) and CH/π interactions for 7 and 9.

Details

Title
1,2-Diaryl(3-pyridyl)ethanone Oximes. Intermolecular Hydrogen Bonding Networks Revealed by X-ray Diffraction
Author
Alcalde, Ermitas; Mesquida, Neus; Alvarez-Rúa, Carmen; Cuberes, Rosa; Frigola, Jordi; García-Granda, Santiago
Pages
301-318
Publication year
2008
Publication date
2008
Publisher
MDPI AG
e-ISSN
14203049
Source type
Scholarly Journal
Language of publication
English
ProQuest document ID
1531128542
Copyright
Copyright MDPI AG 2008