Abstract

A palladium(II)-catalyzed ortho-benzoxylation of 2-arylpyridines with aryl acylperoxides was developed. With pyridyl as directing group, the benzoxylation reaction exhibits remarkable regioselectivity and excellent functional group tolerance, providing the products in up to 87% yield.

Details

Title
Palladium(II)-Catalyzed othro-C-H-Benzoxylation of 2-Arylpyridines by Oxidative Coupling with Aryl Acylperoxides
Author
Sit, Wing-Nga; Chan, Chun-Wo; Yu, Wing-Yiu
Pages
4403-4418
Publication year
2013
Publication date
2013
Publisher
MDPI AG
e-ISSN
14203049
Source type
Scholarly Journal
Language of publication
English
ProQuest document ID
1532129290
Copyright
Copyright MDPI AG 2013