Abstract

Derivatives of salarin A, salarin C and tulearin A, three new cytotoxic sponge derived nitrogenous macrolides, were prepared and bio-evaluated as inhibitors of K562 leukemia cells. Interesting preliminary SAR (structure activity relationship) information was obtained from the products. The most sensitive functionalities were the 16,17-vinyl epoxide in both salarins, the triacylamino group in salarin A and the oxazole in salarin C (less sensitive). Regioselectivity of reactions was also found for tulearin A.

Details

Title
Derivatives of Salarin A, Salarin C and Tulearin A-Fascaplysinopsis sp. Metabolites
Author
Zur, Lee Goren; Bishara, Ashgan; Aknin, Maurice; Neumann, Drorit; Ben-Califa, Nathalie; Kashman, Yoel
Pages
4487-4509
Publication year
2013
Publication date
2013
Publisher
MDPI AG
e-ISSN
16603397
Source type
Scholarly Journal
Language of publication
English
ProQuest document ID
1535665956
Copyright
Copyright MDPI AG 2013