Abstract

The studied of the influence of fuller enoles on adrenaline auto-oxidation reaction by optical and theoretical methods was carried out in this work. It was shown that fullerenols at concentrations from 0.0005 mg/ml to 0.5 mg/ml exhibits prooxidant activity and accelerates autoxidation reaction of adrenaline. The suggested scheme of auto-oxidation reaction, which explained by energy advantage under transferring electron from the molecule of adrenaline to fullerenol by density functional method B3LYP/6-31(p,d).

Details

Title
The Properties of the Water-Soluble Hydroxy-Polyhydroxy fullerenes in Auto-Oxidation Reactions Epinephrine
Author
Yaykova, Olga A; Tomilin, Felix N; Dubinina, Irina A; Kuzubov, Alexander A; Dudnik, Alexander I; Vnukova, Natalia G; Ovchinnikov, Sergey G; Churilov, Grigory N
Pages
533-540
Publication year
2015
Publication date
2015
Publisher
Siberian Federal University
ISSN
19982836
e-ISSN
23136049
Source type
Scholarly Journal
Language of publication
Russian
ProQuest document ID
1786259492
Copyright
Copyright Siberian Federal University 2015