Abstract

The Mn(TpCPP)-Xln10A artificial metalloenzyme, obtained by non-covalent insertion of Mn(III)-meso-tetrakis(p-carboxyphenyl)porphyrin [Mn(TpCPP), 1-Mn] into xylanase 10A from Streptomyces lividans (Xln10A) as a host protein, was found able to catalyze the selective photo-induced oxidation of organic substrates in the presence of [RuII(bpy)3]2+ as a photosensitizer and [CoIII(NH3)5Cl]2+ as a sacrificial electron acceptor, using water as oxygen atom source.

Details

Title
Photoassisted Oxidation of Sulfides Catalyzed by Artificial Metalloenzymes Using Water as an Oxygen Source[dagger]
Author
Herrero, Christian; Nguyen-Thi, Nhung; Hammerer, Fabien; Banse, Frederic; Gagne, Donald; Doucet, Nicolas; Mahy, Jean-Pierre; Ricoux, Remy
First page
202
Publication year
2016
Publication date
2016
Publisher
MDPI AG
e-ISSN
20734344
Source type
Scholarly Journal
Language of publication
English
ProQuest document ID
1858325969
Copyright
Copyright MDPI AG 2016