Zn-Alloyed All-Inorganic Halide Perovskite-Based White Light-Emitting Diodes with Superior Color Quality

Abstract

Recently, lead halide perovskite nanocrystals (NCs) have gained tremendous attention in optoelectronic devices due to their excellent optical properties. However, the toxicity of lead limits their practical applications. Here, the synthesis of Zn²⁺-alloyed CsZn_xPb_1-xX₃ (up to 15%) NCs is reported to achieve lead-reduced white light-emitting diodes (WLEDs). The incorporation of Zn²⁺ into CsPbX₃ host NCs results in a lattice contraction, without altering the structure and morphology, which has a direct effect on the optical properties. The blue-shifts in the photoluminescence emission and increase in bandgap is observed while retaining high photoluminescence quantum yield. Then by engineering the different compositions of halides for 15% Zn²⁺-alloyed CsZn_xPb_1-xX₃ NCs, tunable emission (411–636 nm) is obtained. Notably, the WLEDs are experimentally demonstrated employing the lead-reduced NCs (blue, green, yellow, and red). By varying the ratios of the amount of NCs, white lights with a tunable correlated-color temperature (2218–8335 K), an exemplary color-rendering index (up to 93) and high luminous efficacy of radiation (268–318 lm·W⁻¹) are obtained. Best of our knowledge, these are superior to other reported WLEDs based on CsPbX₃ NCs doped with transition metal ions. This work places the halide perovskite NCs one-step closer in designing the environmentally benign and energy-efficient WLEDs.