Charge disproportionation and nano phase separation in RSrNiO4

Abstract

We have successfully grown centimeter-sized layered $\mathit{R}{\mathrm{SrNiO}}_4$ single crystals under high oxygen pressures of 120–150 bar by the floating zone technique. This enabled us to perform neutron scattering experiments where we observe close to quarter-integer magnetic peaks below $\sim 77\mathrm{K}$ that are accompanied by steep upwards dispersing spin excitations. Within the high-frequency Ni–O bond stretching phonon dispersion, a softening at the propagation vector for a checkerboard modulation can be observed. We were able to simulate the magnetic excitation spectra using a model that includes two essential ingredients, namely checkerboard charge disproportionation and nano phase separation. The results thus suggest that charge disproportionation is preferred instead of a Jahn–Teller distortion even for this layered ${\mathrm{Ni}}^{3+}$ system.