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Abstract
Tropical Pacific stalagmites are commonly affected by dating uncertainties because of their low U concentration and/or elevated initial 230Th content. This poses problems in establishing reliable trends and periodicities for droughts and pluvial episodes in a region vulnerable to climate change. Here we constrain the chronology of a Cook Islands stalagmite using synchrotron µXRF two-dimensional mapping of Sr concentrations coupled with growth laminae optical imaging constrained by in situ monitoring. Unidimensional LA-ICP-MS-generated Mg, Sr, Ba and Na variability series were anchored to the 2D Sr and optical maps. The annual hydrological significance of Mg, Sr, Ba and Na was tested by principal component analysis, which revealed that Mg and Na are related to dry-season, wind-transported marine aerosols, similar to the host-rock derived Sr and Ba signatures. Trace element annual banding was then used to generate a calendar-year master chronology with a dating uncertainty maximum of ± 15 years over 336 years. Our approach demonstrates that accurate chronologies and coupled hydroclimate proxies can be obtained from speleothems formed in tropical settings where low seasonality and problematic U–Th dating would discourage the use of high-resolution climate proxies datasets.
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Details
1 The University of Newcastle, School of Environmental and Life Sciences, Newcastle, Australia (GRID:grid.266842.c) (ISNI:0000 0000 8831 109X)
2 The University of Melbourne, School of Earth Sciences, Melbourne, Australia (GRID:grid.1008.9) (ISNI:0000 0001 2179 088X)
3 National Institute of Water and Atmospheric Research Ltd., Auckland, New Zealand (GRID:grid.419676.b) (ISNI:0000 0000 9252 5808)
4 University of Waikato, Environmental Research Institute, School of Science, Faculty of Science and Engineering, Hamilton, New Zealand (GRID:grid.49481.30) (ISNI:0000 0004 0408 3579)
5 Royal Holloway University of London, Department of Earth Sciences, Egham, UK (GRID:grid.4970.a) (ISNI:0000 0001 2188 881X)