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Abstract
Styrene-terminated polyphenylene oxide (SPPO) and low polar thermosetting polybutadiene (PB) resin were employed to obtain a curing system with excellent electrical properties and enhanced thermal properties. By terminal styrenisation, SPPO is cured with PB, forming a continuous phase in the blend. The SPPO/PB blends have excellent solvent resistance and thermal stability, while the good dielectric performance is retained. Especially, when the mass ratio of PB is 0.5, the curing system has a high T g of 226.5°C and excellent dielectric properties with Dk = 2.46 and Df = 0.0022 at 10 GHz, which is suitable for high frequency electrical applications.
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Details
1 State Key Laboratory of Advanced Technology for Materials Synthesis and Processing, School of Materials Science and Engineering, Wuhan University of Technology, Wuhan 430070, P. R. China
2 State Key Laboratory of Silicate Materials for Architectures, Wuhan University of Technology, Wuhan 430070, P. R. China