It appears you don't have support to open PDFs in this web browser. To view this file, Open with your PDF reader
Abstract
High-pressure Raman scattering experiments were performed for type-I Sn based clathrates, Ba8Ga16Sn30, at room temperature up to 6.9 GPa. We observed irreversible amorphization at 6 GPa. The rattling vibrations of the guest atoms in the cages were investigated up to 5.8 GPa. Pressure induced evolution of spectral shape of the rattling suggested that the reduction in the cage size causes the displacement of the guest atoms from the off center to the center in the cage.
You have requested "on-the-fly" machine translation of selected content from our databases. This functionality is provided solely for your convenience and is in no way intended to replace human translation. Show full disclaimer
Neither ProQuest nor its licensors make any representations or warranties with respect to the translations. The translations are automatically generated "AS IS" and "AS AVAILABLE" and are not retained in our systems. PROQUEST AND ITS LICENSORS SPECIFICALLY DISCLAIM ANY AND ALL EXPRESS OR IMPLIED WARRANTIES, INCLUDING WITHOUT LIMITATION, ANY WARRANTIES FOR AVAILABILITY, ACCURACY, TIMELINESS, COMPLETENESS, NON-INFRINGMENT, MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE. Your use of the translations is subject to all use restrictions contained in your Electronic Products License Agreement and by using the translation functionality you agree to forgo any and all claims against ProQuest or its licensors for your use of the translation functionality and any output derived there from. Hide full disclaimer
Details
1 Department of Materials Science and Technology, Gifu University, 1-1 Yanagido, Gifu 501-1193, Japan
2 Department of Materials Science and Technology, Gifu University, 1-1 Yanagido, Gifu 501-1193, Japan; To whom any correspondence should be addressed
3 Department of Quantum Matter, ADSM, Hiroshima University, Higashi-Hiroshima 739-8530, Japan