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Abstract
This work reported a new perspective on improving the incorporation of nanoparticles(NPs) into membranes for several applications. Composite membranes were produced via the phase inversion method using cellulose acetate (CA) as the polymer, mixed with four differentNPs: ZnO and Fe3O4 NPs were prepared by the co-precipitation method, while SiO2 and TiO2 NPs were commercial NPs. The impact of NPs on the membrane morphology was investigated by SEM and AFM. The composite CA membranes have been characterized by their contact angle, porosity, and water content. Membrane performance has been investigated in terms of water permeability and salt retention such as NaCl and Na2SO4. The produced CA composite membrane could be successfully applied for salt removal, particularly the CA-Fe3O4composite membrane, which shows good water permeability (15.4 l m2hbar−1) and higher salt rejection (93%).Consequently, the use of low-density hydrophilic NPs in the polymeric dope solution produces membranes with higher hydrophilicity and the ability to reduce the membrane fouling.
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1 Laboratory, water, membrane and environmental biotechnology, Centre of Research and Water Technologies, Technologies of Borj-Cedria, BP 273,8020 Solimman, Tunisia; Faculty of Sciences of Tunis, University of Tunis - El Manar , 20 Tolede street, 2092, Tunisia
2 Institute on Membrane Technology (ITM-CNR), Via P. Bucci 17 C, 87036 Rende (CS), Italy
3 Department of Chemistry, Laboratory of Characterizations, Applications and Modeling of Materials LR18ES08, University of Tunis El Manar , Tunisia
4 Laboratory, water, membrane and environmental biotechnology, Centre of Research and Water Technologies, Technologies of Borj-Cedria, BP 273,8020 Solimman, Tunisia
5 Higher Institute of Science and Technology of Environment of Borj-Cedria, BP 2050 Borj-Cedria, Tunisia