Characterization and performance evaluation of Cu-based/TiO2 nano composites

Abstract

Copper and copper alloys are used in industrial applications and food contact surfaces due to their desirable properties; copper metal matrix composites have been exciting researchers' attention in recent years since they can offer many valuable characteristics. The present study investigated the effects of the TiO₂ nanoparticles addition with different weight percent on the hardness and corrosion behavior of copper nanocomposites. The powder metallurgy method was used to fabricate the Cu/TiO₂ reinforced with different weight fractions of TiO₂ nano particles up to 12 wt.%. The corrosion behavior of fabricated specimens is evaluated using potentiodynamic polarization curves and electrochemical impedance spectroscopy in different solutions. These solutions were 3.5wt.% NaCl, 0.5 NaOH and 0.5 M H₂SO₄ reflected different pH. The results showed that the addition of TiO₂ nano particles improves pure copper's hardness. The hardness of pure copper increased from 53 to 91 HV by adding 12 wt.% TiO_2. The corrosion current density (I_corr) of copper nanocomposites test specimens was higher than I_corr of pure copper in all test solutions. As TiO₂ nano particles increase, the corrosion resistance of Cu nano composites decreased. All test specimens exhibited little corrosion current density in 3.5 wt.% NaCl solution as compared with other test solutions.