Interface engineering breaks both stability and activity limits of RuO2 for sustainable water oxidation

Abstract

Designing catalytic materials with enhanced stability and activity is crucial for sustainable electrochemical energy technologies. RuO₂ is the most active material for oxygen evolution reaction (OER) in electrolysers aiming at producing ‘green’ hydrogen, however it encounters critical electrochemical oxidation and dissolution issues during reaction. It remains a grand challenge to achieve stable and active RuO₂ electrocatalyst as the current strategies usually enhance one of the two properties at the expense of the other. Here, we report breaking the stability and activity limits of RuO₂ in neutral and alkaline environments by constructing a RuO₂/CoO_x interface. We demonstrate that RuO₂ can be greatly stabilized on the CoO_x substrate to exceed the Pourbaix stability limit of bulk RuO₂. This is realized by the preferential oxidation of CoO_x during OER and the electron gain of RuO₂ through the interface. Besides, a highly active Ru/Co dual-atom site can be generated around the RuO₂/CoO_x interface to synergistically adsorb the oxygen intermediates, leading to a favourable reaction path. The as-designed RuO₂/CoO_x catalyst provides an avenue to achieve stable and active materials for sustainable electrochemical energy technologies.

RuO₂ encounters critical electrochemical dissolution issues during oxygen evolution reaction and it remains a grand challenge to achieve stable and active RuO₂ electrocatalyst. Here, the authors report breaking stability and activity limits of RuO₂ by constructing a RuO₂/CoO_x interface.