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Abstract
The universe abounds with solid helium in polymorphic forms. Therefore, exploring the allotropes of helium remains vital to our understanding of nature. However, it is challenging to produce, observe and utilize solid helium on the earth because high-pressure techniques are required to solidify helium. Here we report the discovery of room-temperature two-dimensional solid helium through the diamond lattice confinement effect. Controllable ion implantation enables the self-assembly of monolayer helium atoms between {100} diamond lattice planes. Using state-of-the-art integrated differential phase contrast microscopy, we decipher the buckled tetragonal arrangement of solid helium monolayers with an anisotropic nature compressed by the robust diamond lattice. These distinctive helium monolayers, in turn, produce substantial compressive strains to the surrounded diamond lattice, resulting in a large-scale bandgap narrowing up to ~2.2 electron volts. This approach opens up new avenues for steerable manipulation of solid helium for achieving intrinsic strain doping with profound applications.
Helium is the second most abundant element in the universe, and at low temperatures it becomes a quantum crystal with exotic physical properties such as second sound, superfluidity, and giant plasticity. Here authors prepare 2D solid helium at room temperature through diamond lattice confinement.
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1 City University of Hong Kong, Department of Mechanical Engineering, Hong Kong, China (GRID:grid.35030.35) (ISNI:0000 0004 1792 6846)
2 Shanghai University, School of Materials Science and Engineering, Shanghai, China (GRID:grid.39436.3b) (ISNI:0000 0001 2323 5732)
3 University of Groningen, Zernike Institute for Advanced Materials, Groningen, The Netherlands (GRID:grid.4830.f) (ISNI:0000 0004 0407 1981)
4 Southern University of Science and Technology, Department of Physics, Shenzhen, China (GRID:grid.263817.9) (ISNI:0000 0004 1773 1790)
5 Energy Geoscience Division, Lawrence Berkeley National Laboratory, Berkeley, USA (GRID:grid.184769.5) (ISNI:0000 0001 2231 4551)
6 Southeast University, School of Energy and Environment, Nanjing, China (GRID:grid.263826.b) (ISNI:0000 0004 1761 0489)
7 City University of Hong Kong, Department of Materials Science and Engineering, Hong Kong, China (GRID:grid.35030.35) (ISNI:0000 0004 1792 6846)
8 City University of Hong Kong, Department of Mechanical Engineering, Hong Kong, China (GRID:grid.35030.35) (ISNI:0000 0004 1792 6846); Nano-Manufacturing Laboratory (NML), Shenzhen Research Institute of City University of Hong Kong, Shenzhen, China (GRID:grid.35030.35) (ISNI:0000 0004 1792 6846)
9 National Tsing Hua University, Department of Biomedical Engineering and Environmental Science, Hsinchu, Taiwan (GRID:grid.38348.34) (ISNI:0000 0004 0532 0580); Taoyuan General Hospital, Department of Radiology, Taoyuan, Taiwan (GRID:grid.416911.a) (ISNI:0000 0004 0639 1727)
10 City University of Hong Kong, Department of Mechanical Engineering, Hong Kong, China (GRID:grid.35030.35) (ISNI:0000 0004 1792 6846); City University of Hong Kong, Centre for Advanced Nuclear Safety and Sustainable Development, Hong Kong, China (GRID:grid.35030.35) (ISNI:0000 0004 1792 6846)