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Abstract
In the presence of both space and time reversal symmetries, ans-waveA1gsuperconducting state is usually topologically trivial. Here, we demonstrate that an exception can take place in a type of nonsymmorphic lattice structure. We specify the demonstration in a time reversal invariant system with a centrosymmetric space groupP4/nmm, the symmetry that governs iron-based superconductors, by showing the existence of a second-order topological state protected by a mirror symmetry. The topological superconductivity is featured by2Zdegenerate Dirac cones on the (10) edge andZpairs of Majorana modes at the intersection between the (11) and(11¯)edges. The topological invariance and Fermi surface criterion for the topological state are provided. Moreover, we point out that the previously proposeds-wave state in iron-based superconductors, which features a sign-changed superconducting order parameter between two electron pockets, is such a topological state. Thus, these results not only open a new route to pursue topological superconductivity, but also establish a measurable quantity to settle one long-lasting debate on the pairing nature of iron-based superconductors.