Strain control of hybridization between dark and localized excitons in a 2D semiconductor

Abstract

Mechanical strain is a powerful tuning knob for excitons, Coulomb-bound electron–hole complexes dominating optical properties of two-dimensional semiconductors. While the strain response of bright free excitons is broadly understood, the behaviour of dark free excitons (long-lived excitations that generally do not couple to light due to spin and momentum conservation) or localized excitons related to defects remains mostly unexplored. Here, we study the strain behaviour of these fragile many-body states on pristine suspended WSe₂ kept at cryogenic temperatures. We find that under the application of strain, dark and localized excitons in monolayer WSe₂—a prototypical 2D semiconductor—are brought into energetic resonance, forming a new hybrid state that inherits the properties of the constituent species. The characteristics of the hybridized state, including an order-of-magnitude enhanced light/matter coupling, avoided-crossing energy shifts, and strain tunability of many-body interactions, are all supported by first-principles calculations. The hybridized excitons reported here may play a critical role in the operation of single quantum emitters based on WSe₂. Furthermore, the techniques we developed may be used to fingerprint unidentified excitonic states.

Mechanical strain is a powerful tuning knob for excitons in two-dimensional semiconductors. Here, the authors find that under the application of strain, dark and localized excitons in monolayer WSe₂ are brought into energetic resonance, forming a new hybrid state that inherits the properties of the constituent species.