Simultaneous capturing phonon and electron dynamics in MXenes

Abstract

Plasmonic MXenes are of particular interest, because of their unique electron and phonon structures and multiple surface plasmon effects, which are different from traditional plasmonic materials. However, to date, how electronic energy damp to lattice vibrations (phonons) in MXenes has not been unraveled. Here, we employed ultrafast broadband impulsive vibrational spectroscopy to identify the energy damping channels in MXenes (Ti₃C₂T_x and Mo₂CT_x). Distinctive from the well-known damping pathways, our results demonstrate a different energy damping channel, in which the Ti₃C₂T_x plasmonic electron energy transfers to coherent phonons by nonthermal electron mediation after Landau damping, without involving electron-electron scattering. Moreover, electrons are observed to strongly couple with A_1g mode (~60 fs, 85–100%) and weakly couple with E_g mode (1–2 ps, 0–15%). Our results provide new insight into the electron-phonon interaction in MXenes, which allows the design of materials enabling efficient manipulation of electron transport and energy conversion.

How electron energy damp to lattice vibrations (phonons) in MXenes has not yet been unraveled. Here, the authors demonstrate an energy damping channel in which the Ti₃C₂T_x plasmonic electron energy transfers to coherent phonons by nonthermal electron mediation after Landau damping, without involving electron-electron scattering.