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© 2023 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/). Notwithstanding the ProQuest Terms and Conditions, you may use this content in accordance with the terms of the License.

Abstract

The new proton-conducting composite electrolyte films (PCCEFs) consisting of polyvinyl alcohol (PVA) with varying ammonium fluoride salt concentrations were created using an expanded liquid casting process. The X-ray diffraction (XRD) study confirms the composite electrolyte films (CEFs) formation. The improvement in AMF02 salt doping compared to the PVA matrix film approach resulted in decreased variation in the crystalline size values, thus explaining how [NH4+] and polymer PVA matrix films interact. The band gaps decrease when the AMF02 salt filler concentration increases due to increased crystallite size. The suggested composites evaluated successful CUT-OFF laser filters and attenuation, as well as limiting laser power systems. For the 11.11 wt% AMF02 doping salt, the highest DC conductivity was 73.205 × 10−9 (siemens/m) at ambient temperature. Our dielectric results demonstrate that the CEFs are usually suitable for optoelectronic systems. There is a huge need to develop low dielectric permittivity composite electrolyte films (CEFs) for microelectronic devices and the high-frequency region.

Details

Title
The Impact of Ammonium Fluoride on Structural, Absorbance Edge, and the Dielectric Properties of Polyvinyl Alcohol Films: Towards a Novel Analysis of the Optical Refractive Index, and CUT-OFF Laser Filters
Author
Zyoud, Samer H 1   VIAFID ORCID Logo  ; Jilani, Wissal 2 ; Bouzidi, Abdelfatteh 3 ; AlAbdulaal, Thekrayat H 4 ; Harraz, Farid A 5   VIAFID ORCID Logo  ; Al-Assiri, Mohammad S 6 ; Yahia, Ibrahim S 7   VIAFID ORCID Logo  ; Zahran, Heba Y 8   VIAFID ORCID Logo  ; Ibrahim, Medhat A 9 ; Mohamed Sh Abdel-wahab 10 

 Department of Mathematics and Sciences, Ajman University, Ajman P.O. Box 346, United Arab Emirates; Nonlinear Dynamics Research Center (NDRC), Ajman University, Ajman P.O. Box 346, United Arab Emirates; Center of Medical and Bio-Allied Health Sciences Research (CMBHSR), Ajman University, Ajman P.O. Box 346, United Arab Emirates 
 Department of Physics, Faculty of Science Sciences and Arts Dhahran Al Janoub, King Khalid University, P.O. Box 960, Abha 61421, Saudi Arabia; Laboratory of Materials for Energy and Environment and Modelling (LMEEM), Faculty of Sciences of Sfax, University of Sfax-Tunisia, B.P. 1171, Sfax 3038, Tunisia 
 Laboratory of Materials for Energy and Environment and Modelling (LMEEM), Faculty of Sciences of Sfax, University of Sfax-Tunisia, B.P. 1171, Sfax 3038, Tunisia 
 Laboratory of Nano-Smart Materials for Science and Technology (LNSMST), Department of Physics, Faculty of Science, King Khalid University, P.O. Box 9004, Abha 61421, Saudi Arabia 
 Promising Centre for Sensors and Electronic Devices (PCSED), Advanced Materials and Nano-Research Centre, Najran University, P.O. Box 1988, Najran 11001, Saudi Arabia; Nanomaterials and Nanotechnology Department, Central Metallurgical Research and Development Institute (CMRDI), Cairo 11421, Egypt 
 Promising Centre for Sensors and Electronic Devices (PCSED), Advanced Materials and Nano-Research Centre, Najran University, P.O. Box 1988, Najran 11001, Saudi Arabia; Department of Physics, Faculty of Science and Arts, Najran University, P.O. Box 1988, Najran 11001, Saudi Arabia 
 Center of Medical and Bio-Allied Health Sciences Research (CMBHSR), Ajman University, Ajman P.O. Box 346, United Arab Emirates; Laboratory of Nano-Smart Materials for Science and Technology (LNSMST), Department of Physics, Faculty of Science, King Khalid University, P.O. Box 9004, Abha 61421, Saudi Arabia; Research Center for Advanced Materials Science (RCAMS), King Khalid University, P.O. Box 9004, Abha 61413, Saudi Arabia; Nanoscience Laboratory for Environmental and Biomedical Applications (NLEBA), Semiconductor Lab., Metallurgical Lab. 1., Department of Physics, Faculty of Education, Ain Shams University, Roxy, Cairo 11757, Egypt 
 Laboratory of Nano-Smart Materials for Science and Technology (LNSMST), Department of Physics, Faculty of Science, King Khalid University, P.O. Box 9004, Abha 61421, Saudi Arabia; Research Center for Advanced Materials Science (RCAMS), King Khalid University, P.O. Box 9004, Abha 61413, Saudi Arabia; Nanoscience Laboratory for Environmental and Biomedical Applications (NLEBA), Semiconductor Lab., Metallurgical Lab. 1., Department of Physics, Faculty of Education, Ain Shams University, Roxy, Cairo 11757, Egypt 
 Molecular Spectroscopy and Modeling Unit, National Research Centre, Spectroscopy Department, 33 El-Bohouth St., Dokki, Giza 12622, Egypt 
10  Materials Science and Nanotechnology Department, Faculty of Postgraduate Studies for Advanced Sciences, Beni-Suef University, Beni-Suef 62511, Egypt 
First page
376
Publication year
2023
Publication date
2023
Publisher
MDPI AG
e-ISSN
20734352
Source type
Scholarly Journal
Language of publication
English
ProQuest document ID
2791606593
Copyright
© 2023 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/). Notwithstanding the ProQuest Terms and Conditions, you may use this content in accordance with the terms of the License.