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© 2023 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/). Notwithstanding the ProQuest Terms and Conditions, you may use this content in accordance with the terms of the License.

Abstract

The automotive upholstery industry, which processes bovine leathers, has struggled with vast amounts of solid waste, of which the majority are fractions, such as shavings and splits and offcuts, both containing chromium (Cr) and free of Cr. In this work, a novel leather waste-to-fertiliser approach has been tested: four lightly processed (incubation with effective microorganisms) and three aggressively processed (using pyrolysis or hydrolysis processes) tanned leather waste fractions were used. They were applied as organic nitrogen-based fertilisers in two separate glasshouse experiments, consisting of four subsequent harvests, under spring–autumn conditions in northern Poland. The Cr stressing effect caused by bovine shavings containing Cr and splits and offcuts containing Cr stimulated an increase in ryegrass growth after 30 days, providing twice the dry matter yield than bovine shavings free of Cr and splits and offcuts free of Cr, then (after 90 and 120 days) it inhibited growth. The Monod kinetics model was developed using the best fitting procedure (R2 > 0.94) for the efficiency of internal N use in ryegrass for the lightly processed fractions of tanned leather-waste fractions and each harvest. In the case of the processed leather waste-fractions, the relation was quasi linear, evidencing less growth inhibition and no over-fertilisation effects. The acid hydrolysate of bovine shavings containing Cr showed the best performance, reaching a relative agronomic effectiveness (RAE, N utilization-based) equal to 89%, 95%, 19%, and 38% for 30, 60, 90, and 120 days, respectively, and 71% in total. For the lightly processed fractions, it was lower than 12%. The future perspective should focus on steps including scaling up the tests to field conditions; transportation, storage, and application methods; effectiveness for other crops; usage in crop rotation systems; environmental impact assessment; production carbon footprint; commercial potential; and optimizing the production processes.

Details

Title
Application of Leather Waste Fractions and Their Biochars as Organic Fertilisers for Ryegrass Growth: Agri-Environmental Aspects and Plants Response Modelling
Author
Kuligowski, Ksawery 1   VIAFID ORCID Logo  ; Cenian, Adam 1   VIAFID ORCID Logo  ; Konkol, Izabela 1 ; Świerczek, Lesław 1 ; Chojnacka, Katarzyna 2 ; Izydorczyk, Grzegorz 2   VIAFID ORCID Logo  ; Skrzypczak, Dawid 2 ; Bandrów, Paulina 3 

 Department of Physical Aspects of Ecoenergy, The Institute of Fluid-Flow Machinery Polish Academy of Sciences, Fiszera 14 St., 80-231 Gdańsk, Poland 
 Department of Advanced Material Technology, Faculty of Chemistry, Wroclaw University of Science and Technology, M. Smoluchowskiego 25 St., 50-372 Wroclaw, Poland 
 BADER Polska Sp. z o.o., Mostowa 1 St., 59-700 Bolesławiec, Poland 
First page
3883
Publication year
2023
Publication date
2023
Publisher
MDPI AG
e-ISSN
19961073
Source type
Scholarly Journal
Language of publication
English
ProQuest document ID
2812438746
Copyright
© 2023 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/). Notwithstanding the ProQuest Terms and Conditions, you may use this content in accordance with the terms of the License.