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Abstract
Soil contamination is an environmental issue due to increasing anthropogenic activities. Existing processes for soil remediation suffer from long treatment time and lack generality because of different sources, occurrences, and properties of pollutants. Here, we report a high-temperature electrothermal process for rapid, water-free remediation of multiple pollutants in soil. The temperature of contaminated soil with carbon additives ramps up to 1000 to 3000 °C as needed within seconds via pulsed direct current input, enabling the vaporization of heavy metals like Cd, Hg, Pb, Co, Ni, and Cu, and graphitization of persistent organic pollutants like polycyclic aromatic hydrocarbons. The rapid treatment retains soil mineral constituents while increases infiltration rate and exchangeable nutrient supply, leading to soil fertilization and improved germination rates. We propose strategies for upscaling and field applications. Techno-economic analysis indicates the process holds the potential for being more energy-efficient and cost-effective compared to soil washing or thermal desorption.
Soil contamination is a pressing environmental concern due to increasing anthropogenic activity. Here, the authors developed a rapid and energy-efficient electrothermal process that simultaneously removes heavy metals and organic pollutants in soil.
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1 Rice University, Department of Chemistry, Houston, USA (GRID:grid.21940.3e) (ISNI:0000 0004 1936 8278)
2 Rice University, Department of BioSciences, Houston, USA (GRID:grid.21940.3e) (ISNI:0000 0004 1936 8278)
3 Rice University, Department of Chemistry, Houston, USA (GRID:grid.21940.3e) (ISNI:0000 0004 1936 8278); Applied Physics Program, Rice University, Houston, USA (GRID:grid.21940.3e) (ISNI:0000 0004 1936 8278); Smalley-Curl Institute, Rice University, Houston, USA (GRID:grid.21940.3e) (ISNI:0000 0004 1936 8278)
4 U.S. Army Engineer Research & Development Center, Geotechnical and Structures Laboratory, Vicksburg, USA (GRID:grid.417553.1) (ISNI:0000 0001 0637 9574)
5 Rice University, Department of Chemistry, Houston, USA (GRID:grid.21940.3e) (ISNI:0000 0004 1936 8278); Applied Physics Program, Rice University, Houston, USA (GRID:grid.21940.3e) (ISNI:0000 0004 1936 8278)
6 Rice University, Department of Earth, Environmental, & Planetary Sciences, Houston, USA (GRID:grid.21940.3e) (ISNI:0000 0004 1936 8278); Carbon Hub, Rice University, Houston, USA (GRID:grid.21940.3e) (ISNI:0000 0004 1936 8278)
7 Rice University, Department of Materials Science and NanoEngineering, Houston, USA (GRID:grid.21940.3e) (ISNI:0000 0004 1936 8278)
8 Rice University, Department of Earth, Environmental, & Planetary Sciences, Houston, USA (GRID:grid.21940.3e) (ISNI:0000 0004 1936 8278)
9 Rice University, Department of Chemistry, Houston, USA (GRID:grid.21940.3e) (ISNI:0000 0004 1936 8278); Smalley-Curl Institute, Rice University, Houston, USA (GRID:grid.21940.3e) (ISNI:0000 0004 1936 8278); Rice University, Department of Materials Science and NanoEngineering, Houston, USA (GRID:grid.21940.3e) (ISNI:0000 0004 1936 8278); NanoCarbon Center and the Rice Advanced Materials Institute, Rice University, Houston, USA (GRID:grid.21940.3e) (ISNI:0000 0004 1936 8278)