Review and interlaboratory comparison of the Oddy test methodology

Abstract

Since the introduction of the Oddy test in 1973, many museums and cultural institutions have put the method in use, developing their own versions and protocols. Currently the 3-in-1 version, temperature at 60 ºC and 2 g of tested material are set as common practice; however, other variables of the test are not standardized. The purpose of this study is to examine current versions of the Oddy test, to identify differences in the results derived from variations in the procedures, and ultimately raising awareness within the conservation community to work together towards a standardized protocol. In this article, we review the available information on the methodological differences in Oddy test protocols published in the literature related to glassware cleaning, coupon preparation, reaction vessel setup and rating of materials. Based on the review, and to highlight the many variables that could affect the results of the test, seven European cultural institutions working under the H2020 IPERION HS project performed a comparative 3-in-1 Oddy test by blindly evaluating the same ten materials. Each institution used its own test methodology but some guidelines were advised: (1) Detergents as a cleaning procedure for glassware, (2) P600 sandpaper or micromesh pad close to 1500 to prepare metal coupons and (3) 1:100 as water–air ratio. Despite this, differences between institutions’ results were still observed. Some of them are due to the differences in the coupons preparation, either in the sanding pattern or in the edge area. In order to separate the contribution of the experimental setup and the subjectivity of the evaluation in the discrepancies, coupons from all institutions have been rated by a single team of judges with experience in the Oddy Test. Results show that differences in the evaluation criteria play a relevant role in the discrepancies of the results, especially for institutions with less experience in the test. These results highlight the need to further standardize the methodology and criteria for visual assessment. Nevertheless, the Oddy test has been found to be reliable for the identification of materials that produce emissions hazardous for the conservation of cultural assets.