Two-dimensional metal–organic framework for post-synthetic immobilization of graphene quantum dots for photoluminescent sensing

Abstract

Immobilization of graphene quantum dots (GQDs) on a solid support is crucial to prevent GQDs from aggregation in the form of solid powder and facilitate the separation and recycling of GQDs after use. Herein, spatially dispersed GQDs are post-synthetically coordinated within a two-dimensional (2D) and water-stable zirconium-based metal–organic framework (MOF). Unlike pristine GQDs, the obtained GQDs immobilized on 2D MOF sheets show photoluminescence in both suspension and dry powder. Chemical and photoluminescent stabilities of MOF-immobilized GQDs in water are investigated, and the use of immobilized GQDs in the photoluminescent detection of copper ions is demonstrated. Findings here shed the light on the use of 2D MOFs as a platform to further immobilize GQDs with various sizes and distinct chemical functionalities for a range of applications.

Graphene quantum dots have versatile properties, but their luminescence can be quenched when the dots aggregate. Here, the authors immobilize graphene quantum dots on 2D MOF sheets and demonstrate their photoluminescence in suspension and as a dry powder, and show their application in copper ion sensing.