Abstract

Oxygen isotopes (δ18O) are the most commonly utilized speleothem proxy and have provided many foundational records of paleoclimate. Thus, understanding processes affecting speleothem δ18O is crucial. Yet, prior calcite precipitation (PCP), a process driven by local hydrology, is a widely ignored control of speleothem δ18O. Here we investigate the effects of PCP on a stalagmite δ18O record from central Vietnam, spanning 45 – 4 ka. We employ a geochemical model that utilizes speleothem Mg/Ca and cave monitoring data to correct the δ18O record for PCP effects. The resulting record exhibits improved agreement with regional speleothem δ18O records and climate model simulations, suggesting that the corrected record more accurately reflects precipitation δ18O (δ18Op). Without considering PCP, our interpretations of the δ18O record would have been misleading. To avoid misinterpretations of speleothem δ18O, our results emphasize the necessity of considering PCP as a significant driver of speleothem δ18O.

This study finds that in-cave processes affect speleothem oxygen isotope records. Correcting for these processes improves agreement with other regional records and climate models, providing a more accurate reflection of past hydroclimate change.

Details

Title
Local hydroclimate alters interpretation of speleothem δ18O records
Author
Patterson, E. W. 1   VIAFID ORCID Logo  ; Skiba, V. 2   VIAFID ORCID Logo  ; Wolf, A. 3   VIAFID ORCID Logo  ; Griffiths, M. L. 4   VIAFID ORCID Logo  ; McGee, D. 5   VIAFID ORCID Logo  ; Bùi, T. N. 6 ; Trần, M. X. 6 ; Đinh, T. H. 6 ; Đỗ-Trọng, Q. 7 ; Goldsmith, G. R. 8 ; Ersek, V. 9   VIAFID ORCID Logo  ; Johnson, K. R. 10   VIAFID ORCID Logo 

 University of California, Department of Earth System Science, Irvine, USA (GRID:grid.266093.8) (ISNI:0000 0001 0668 7243); William Paterson University, Department of Environmental Science, Wayne, USA (GRID:grid.268271.8) (ISNI:0000 0000 9702 2812) 
 Member of the Leibniz Association, Potsdam Institute for Climate Impact Research, Potsdam, Germany (GRID:grid.4556.2) (ISNI:0000 0004 0493 9031); Helmholtz Centre for Polar and Marine Research, Alfred Wegener Institute, Potsdam, Germany (GRID:grid.10894.34) (ISNI:0000 0001 1033 7684) 
 University of California, Department of Earth System Science, Irvine, USA (GRID:grid.266093.8) (ISNI:0000 0001 0668 7243); University of Michigan, Department of Earth and Environmental Sciences, Ann Arbor, USA (GRID:grid.214458.e) (ISNI:0000 0004 1936 7347) 
 William Paterson University, Department of Environmental Science, Wayne, USA (GRID:grid.268271.8) (ISNI:0000 0000 9702 2812) 
 Massachusetts Institute of Technology, Department of Earth, Atmospheric and Planetary Sciences, Cambridge, USA (GRID:grid.116068.8) (ISNI:0000 0001 2341 2786) 
 Phong Nha- Ke Bang National Park, Phong Nha, Vietnam (GRID:grid.116068.8) 
 Vietnam National University, University of Science, Hanoi, Vietnam (GRID:grid.267852.c) (ISNI:0000 0004 0637 2083) 
 Orange, Schmid College of Science and Technology, Chapman University, California, USA (GRID:grid.254024.5) (ISNI:0000 0000 9006 1798) 
 Northumbria University, Department of Geography and Environmental Sciences, Newcastle, United Kingdom (GRID:grid.42629.3b) (ISNI:0000 0001 2196 5555) 
10  University of California, Department of Earth System Science, Irvine, USA (GRID:grid.266093.8) (ISNI:0000 0001 0668 7243) 
Pages
9064
Publication year
2024
Publication date
2024
Publisher
Nature Publishing Group
e-ISSN
20411723
Source type
Scholarly Journal
Language of publication
English
ProQuest document ID
3118954522
Copyright
© The Author(s) 2024. This work is published under http://creativecommons.org/licenses/by-nc-nd/4.0/ (the “License”). Notwithstanding the ProQuest Terms and Conditions, you may use this content in accordance with the terms of the License.