Abstract

This paper presents the synthesis and characterization of calcium sulfate hemihydrate (CSH)-supported titania (TiO2) catalysts and their application in the environmentally friendly oxidation of styrene to benzaldehyde using hydrogen peroxide (H2O2) as the oxidant. The study explores the catalyst's structure-activity relationship, emphasizing the importance of mesoporous materials for enhanced catalytic performance. The CSH-Titania catalysts were synthesized using fish bone-derived CSH as a support, which aligns with green chemistry principles. Characterization techniques such as Fourier Transform Infra Red (FTIR), X-ray Diffraction (XRD), Scanning Electron Microscope (SEM), and Brunauer-Emmett-Teller (BET) surface area analysis confirmed the successful impregnation of titania and its catalytic efficiency. The catalysts exhibited high selectivity for benzaldehyde, achieving up to 49.45% conversion of styrene, with benzaldehyde as being the main product. The research highlights that the catalyst’s performance decreased after calcination due to a reduced surface area and pore volume, yet it maintained recyclability across three cycles with minimal lose in selectivity loss. Overall, this study introduces a cost-effective and sustainable approach to styrene oxidation, demonstrating the potential for industrial application in producing high-value chemicals with minimal environmental impact.

Details

Title
Oxidation of Styrene to Benzaldehyde Using Environmentally Friendly Calcium Sulfate Hemihydrate-Supported Titania Catalysts
Author
Koesnarpadi, Soerja; Wirawan, Teguh; Nurhadi, Mukhamad; Wirhanuddin, Wirhanuddin; Prananto, Yuniar Ponco  VIAFID ORCID Logo  ; Nazarudin, Nazarudin; Degirmenci, Volkan  VIAFID ORCID Logo  ; Sin Yuan Lai  VIAFID ORCID Logo  ; Hadi Nur  VIAFID ORCID Logo 
Pages
622-634
Section
Original Research Articles
Publication year
2024
Publication date
2024
Publisher
Department of Chemical Engineering, Diponegoro University
e-ISSN
19782993
Source type
Scholarly Journal
Language of publication
English
ProQuest document ID
3149843595
Copyright
© 2024. This work is licensed under https://creativecommons.org/licenses/by-sa/4.0/ (the “License”). Notwithstanding the ProQuest Terms and Conditions, you may use this content in accordance with the terms of the License.