Abstract

New zinc(II)-complexes with S-alkyl derivatives of thiosalicylic acid (alkyl = benzyl-(L1), methyl-(L2), ethyl-(L3), propyl-(L4), butyl-(L5)) have been synthesized and characterized by elemental microanalysis, IR spectroscopy, and 1H and 13C NMR spectroscopy. The S-alkyl derivatives of thiosalicylic acid were prepared by alkylation of thiosalicylic acid by adding alkyl halides to an alkaline water-ethanol solution, while the corresponding zinc(II)-complexes were obtained via the direct reaction of ZnCl2 with S-alkyl derivatives of thiosalicylic acid in water. Based on the microanalysis results and the IR and NMR spectra of the S-alkyl derivatives of thiosalicylic acid and the corresponding zinc(II)-complexes, we concluded that the ligands are bidentately coordinated to the zinc(II)-ion.

Details

Title
Synthesis and Characterization of Zinc(II)-Complexes with S-Alkyl Derivatives of Thiosalicylic Acid
Author
Nikolic, Milos V 1 ; Mijajlovic, Marina Z 1 ; Tomovic, Dusan Lj 1 ; Bukonjic, Andriana M 1 ; Jevtic, Verica V 2 ; Ratkovic, Zoran R 2 ; Trifunovic, Srecko R 2 ; Radic, Gordana P 1 

1  University of Kragujevac, Serbia, Faculty of Medical Sciences, Department of Pharmacy 
2  University of Kragujevac, Serbia, Faculty of Science, Department of Chemistry 
Pages
113-117
Publication year
2018
Publication date
2018
Publisher
De Gruyter Brill Sp. z o.o., Paradigm Publishing Services
ISSN
18208665
e-ISSN
29562090
Source type
Scholarly Journal
Language of publication
English
DOI
https://doi.org/10.1515/sjecr-2017-0005
ProQuest document ID
3158070386
Copyright
© 2018. This work is published under http://creativecommons.org/licenses/by-nc-nd/3.0 (the “License”). Notwithstanding the ProQuest Terms and Conditions, you may use this content in accordance with the terms of the License.