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Abstract
The secondary reaction of toluene is difficult to be suppressed in benzene alkylation with methanol over conventional acidic zeolite catalysts. Moreover, the formation of coke yet remains a challenging problem. In this study, Na-Y zeolites were modified with ammonium carbonate (AC), citric acid (CA) and caesium nitrate(CN) to evaluate the alkylation of benzene with methanol, which was also characterized by XRD, SEM, FT-IR, N2 adsorption and Py-IR. For the Na-Y treated with AC-CA-CN, not only the catalytic selectivity for the alkylation of benzene with methanol was improved (the total selectivity of toluene and xylene was 97.9% and toluene selectivity was 86.4%), but also the quantity of coke was greatly decreased.
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Details
1 College of Petrochemical Technology, Lanzhou University of Technology, Lanzhou, People’s Republic of China; Lanzhou Petrochemical College of Vocational Technology, Lanzhou, People’s Republic of China
2 College of Chemistry and Chemical Engineering, Lanzhou University, Lanzhou, People’s Republic of China
3 Lanzhou Petrochemical College of Vocational Technology, Lanzhou, People’s Republic of China
4 College of Petrochemical Technology, Lanzhou University of Technology, Lanzhou, People’s Republic of China





