Charge self-regulation in 1T'''-MoS2 structure with rich S vacancies for enhanced hydrogen evolution activity

Abstract

Active electronic states in transition metal dichalcogenides are able to prompt hydrogen evolution by improving hydrogen absorption. However, the development of thermodynamically stable hexagonal 2H-MoS₂ as hydrogen evolution catalyst is likely to be shadowed by its limited active electronic state. Herein, the charge self-regulation effect mediated by tuning Mo−Mo bonds and S vacancies is revealed in metastable trigonal MoS₂ (1T'''-MoS₂) structure, which is favarable for the generation of active electronic states to boost the hydrogen evolution reaction activity. The optimal 1T'''-MoS₂ sample exhibits a low overpotential of 158 mV at 10 mA cm⁻² and a Tafel slope of 74.5 mV dec⁻¹ in acidic conditions, which are far exceeding the 2H-MoS₂ counterpart (369 mV and 137 mV dec⁻¹). Theoretical modeling indicates that the boosted performance is attributed to the formation of massive active electronic states induced by the charge self-regulation effect of Mo−Mo bonds in defective 1T'''-MoS₂ with rich S vacancies.

Metal chalcogenides have shown promising performances for renewable hydrogen evolution and such activities are sensitive to the material electronic structures. Here, authors modulate the electronic properties of molybdenum sulfide in 1T'''-MoS₂ for hydrogen evolution electrocatalysis.