High-Transmittance 2π Electrically Tunable Terahertz Phase Shifter with CMOS-Compatible Driving Voltage Enabled by Liquid Crystals

Abstract

We have investigated tunable terahertz (THz) phase shifters that are based on a sandwiched liquid crystal (LC) cell with indium–tin–oxide (ITO) nanowhiskers (NWhs) as transparent electrodes. More than 360° of phase shift at 1.0 THz was achieved at a driving voltage as low as ~2.6 V (rms). This is approximately 40 times smaller than that reported in previous works using an electrically tuned LC device. Significance of the NWhs in reducing the required voltage is demonstrated. Overall transmittance of the device is as high as 30%, which is accountable by absorption losses of ITO NWhs, quartz substrate and LC. Experimental results are in good agreement with a theoretical formulism while taking into account super-thick LC cells (~1 mm) and pretilt angles. We also propose and demonstrate a novel THz technique for measuring pretilt angles of liquid crystals.

1. Introduction

To meet the demands of applications in emerging technologies, such as sub–terahertz (THz) radio–over–fiber communication link [1], numerous quasi–optic components, such as phase shifters [2,3,4,5,6,7,8,9,10], polarization converter [11,12,13], filters [14], phase gratings [15], and polarizers [16], have been reported. In particular, a number of tunable THz devices using liquid crystals (LCs) have received attention [2,3,4,5,6,7,8,9,10,11,12,13,14,15,16,17]. For example, an LC spatial THz modulator that can tune THz wavefronts is pivotal in the demonstration of a THz vortex system that can execute orbital angular momentum conversions [17].

Among LC THz devices, magnetically tunable 2π phase shifters have been shown to work effectively [2]. They are, however, somewhat bulky and are not so easy to use in some applications. Electrically tunable phase shifters are, therefore, attractive. However, early designs require a high driving voltage (larger than 100 V), because they use widely separated lateral electrodes for the lack of electrodes that are transparent in the THz band [3].

Graphene exhibit outstanding electrical conductivity and high transparency in the THz frequency range [4,8,10]. Several groups have demonstrated THz phase controllers with graphene electrodes [4,8,10]. Y. Wu and et al. achieved the phase shift, which is 10.8 degree with a 50 μm LC cell [8]. By applying the randomly aligned LCs cell with graphene electrodes T. Sasaki and et al. demonstrated a phase shift of 0.11 rad at 1.5 THz [10]. A phase shift of more than 90 degrees, which is approximately ten times better than that reported in previous designs using LCs and graphene electrodes, was accomplished by our group [4].

Besides, graphene, poly(3,4-ethylenedioxythiophene)/poly(styrenesulfonate) (PEDOT/PSS) films [11], and subwavelength metallic gratings [12] have been employed by Sasaki et al. in electrically tunable THz polarization converters based on twisted nematic (TN) LC cells as transparent electrodes. The three main advantages are low operating voltages, high transmittance, and simple structures.

Previously, we have shown that indium–tin–oxide (ITO) nanomaterials exhibit outstanding transmittance in the THz frequencies [18,19,20]. Their conductivity and DC mobility are also comparable to the sputtered ITO films [18,19,20]. Later, we also demonstrated the quarter-wave operation or a phase shift of around π/2 at 1.0 THz with ITO nanomaterials as transparent electrodes [5]. Interestingly, ITO nanowhiskers have the additional functionality of aligning liquid crystal molecules [5].

Due to the long wavelength of THz waves, thick LC cells are unavoidable. Lest the devices become too unwieldy, a sandwiched LC cell structure for THz application was proposed and demonstrated by us in magnetically tuned phase shifters [2] and patented [21]. With a sandwiched LC cell structure, it is possible to achieve a phase shift of 2π at 1.0 THz with a relatively low voltage. Preliminary results were reported by us in a conference paper [22].

In this work, we present in more detail the experimental and theoretical aspects of the device [22]. The frequency–and voltage–dependent characteristics of the THz phase shifters are described. In particular, a theoretical formulism that can handle thick (approximately 1 mm) LC cells is presented. Pretilt angles, which were measured by novel THz techniques, were taken into account. Experimental data are in good agreement with this theoretical formulism.

2. Experimental Methods

For use as electrodes, ITO NWhs were deposited on fused silica substrates by using a glancing–angle-incidence e–beam deposition apparatus, as described previously [18]. A photoconductive antenna-based THz time–domain spectrometer (THz-TDS) was employed for characterizing the devices at frequencies of between 0.2 and 1.4 THz [19]. The structural, electrical, and THz optical properties of ITO nanowhiskers were summarized previously [20]. Briefly, ITO NWhs exhibit superb transparency (~82%) in the THz frequency band. Meanwhile, their DC mobility (~92 cm²V⁻¹s⁻¹) and conductivities (~245 Ω⁻¹cm⁻¹) are comparable to sputtered ITO thin film.

We studied three different designs of THz phase shifters: types A, B, and C (See Figure 1a). Type A comprised of two identical cells (four substrates) with four ITO NWhs layers; type B consisted of a single cell (three substrates) with three ITO NWhs layers; and, type C was made of a single cell (three substrates) with two ITO NWhs layers. These shifters were constructed by sandwiching the LC (MDA–00-3461 by Merck) layer between fused silica substrates that were deposited with ITO NWhs and then spin-coated by a polyimide (PI) layer, which was rubbed for LC alignment. The substrate thickness was approximately 1.033 mm, whereas that of the LC layer was ~1.12 mm. In other words, the total thickness of the LC material for each design was approximately 2.24 mm. The cells were always biased with sinusoidal signals at 1 kHz.

The cross-sectional images by scanning electron microcopy of the substrate deposited with ITO NWhs only, ITO NWhs coated with PI, and further treated with the rubbing process are shown in Figure 1b–d, respectively. In Figure 1c, it can be seen that ITO NWhs that were clustered with adjacent whiskers after coating by PI. Besides, the average height of ITO NWhs decreased from 918 nm to 729 nm after the rubbing process. The trunks of the ITO NWhs were inclined toward the rubbing direction. Therefore, LC molecules in the proximity of the ITO NWhs and the alignment layer will exhibit pretilt angles. Pretilting is thus enhanced by the glancing–angle structure of the ITO NWhs.

3. Theoretical Formulism

Expected performances of the phase shifters can be analyzed using the approach that we reported earlier [3]. In the absence of the external field, the LC molecules were initially in equilibrium and were oriented more or less parallel to the substrates (Figure 1a). Because of the Fréedericksz transition, when the applied bias was greater than the threshold voltage, the LC molecules will reorient themselves toward the direction of the external field. The threshold voltage for reorienting the LC molecules is given by V_th = π·(k₁/(ε₀·∆ε))^1/2L/d [23], where ε₀ = 8.854 × 10⁻¹² F·m⁻¹, ∆ε = ε_// −_ε⊥ = 11.2, k₁ = 12.6 × 10⁻¹² N, and L and d are the free-space permittivity, dielectric anisotropy, splay elastic constants, distance between two electrodes, and thickness of the LC layers, respectively. The maximum tilt angle of the LC director, θ_max, is assumed to be found at the mid-point position of the LC cell, i.e., z = d/2. Here, the THz wave is assumed to be propagating along the z-direction, normal to the LC cell. The relationship between θ_max and V can be determined by solving [23]:

_∫0π2(1+ζ^sin2 _θmax ^sin2δ)(1+ρ^sin2 _θmax ^sin2δ)(1−^sin2 _θmax ^sin2δ)(1+ρ^sin2 _θmax ^sin2δ)dδ=π2V_Vth,

where θ is the tilt angle of the LC molecule, sinδ = sinθ/sinθ_max. We define η = sinθ_max, then sinθ (z) = sinθ_max · sinδ′(z), δ′(z) being the derivative of the integrating variable. In Equation (1), ζ = (k₃−k₁)/k₁ ≈ 0.22, k₃ = 15.4 × 10⁻¹² N, ρ = (ε_// −_ε⊥)/_ε⊥≈ 2.55,_ε⊥= 4.4 for the LC that we used. V is the applied voltage. Equation (1) can be rewritten and used to find θ at every z position in the LC cell, as follows:

∫0^δ′(1+ζ^{η2 sin2}δ)(1+ρ^{η2 sin2}δ)(1−^{η2 sin2}δ)(1+ρ^{η2 sin2}δ)dδ=π2E⋅z_Vth,

where E is the electric field applied to the device. When considering the effective birefringence of the LC, the total phase shift experienced by the THz wave propagating through the device, ∆ϕ, is given by

Δϕ(V)=_∫0d2πf_c0[^{(cos2θ_no2+sin2θ_ne2)−1/2}−_no]dz,

where f and c₀ are the frequency and speed, respectively, of the THz wave in vacuum. The extraordinary and ordinary refractive indices of MDA–00–3461 in a frequency range of 0.3–1.4 THz at 25 °C are essentially frequency-independent: n_e = 1.74 and n_o = 1.54, respectively [24]. The aforementioned model is suitable for a thin LC cell (thickness of approximately 20 μm or less). However, in this study, the thickness of the LC layer for the 2π THz phase shifter was approximately 1.12 mm, which was approximately 100 times thicker than typical LC devices that were designed in the visible frequency range. In such thick cells, LC molecules more than a few tens of microns away from the cell walls will not be exactly parallel to the rubbed direction in the absence of the applied electric field. Besides, almost all the LC molecules can be easily reoriented in the direction, which is parallel to the external field when the LC cell is biased.

In Figure 2a, we drew a thick LC cell in the e-ray mode without bias. The LC molecules that are sufficiently away from the substrates, highlighted in yellow, are not oriented toward the rubbed direction. After applying a sufficiently high voltage, e.g., V_max = 70 V, we can achieve the o-ray mode for the cell shown in Figure 2b. From the measured phase difference for THz wave propagation through LC cells in these two modes, we find the maximum possible difference in relative phase retardation, ∆ϕ(V_max) can be significantly different from the total relative phase shift in the ideal case, 2πf (n_e − n_o)d/c₀. We propose, therefore, to apply a correction factor for the phase shift,

α = [2πf (n_e − n_o)d /c₀]/∆ϕ(V_max)

If the LC molecules in the middle of the cell are not perfectly aligned with the rubbing direction because of the weak anchoring ability of the thick LC device, α > 1.

As mentioned above, the effect of pretilt angle on phase shift in our devices cannot be neglected due to the glancing–angle structure of ITO NWhs. Figure 2b–d are used to describe the experimental method for measuring the pretilt angle of our devices.

We first measured the effective refractive index, n_p, which is the sum of the refractive indices in the o-ray mode, n_o, _Exp, and the birefringence that is caused by the pretilt angle, ∆n_E, in the absence of the external field (see Figure 2c). The same procedure was repeated with the cell biased at 70 V (rms), as shown in Figure 2b. The parameters, ∆ϕ_E, and n_p are then related by

_np(_θ0)=Δ_nE+_{no, Exp}=_c02πfdΔ_ϕE+_{no, Exp},

where θ₀ is the pretilt angle. On the other hand, n_p can also be determined by using the index ellipsoid shown in Figure 2d,

_np(_θ0)=^{[sin2(_θ0)_ne2+cos2(_θ0)_no2]−1/2}.

The pretilt angle can then be determined by the above procedure and applying Equations (5) and (6). Taking into account of the thick cell and effect of the pretilt angle mentioned above, we obtain an expression for the effective phase shift,

Δϕ_eff = (α)(β)(∆ϕ),

where the compensation factor for pretilt, β, is given by,

β = c₀d∆ϕ_E(V_max)/(2πf)/(n_e − n_o).

For the case of β < 1, the LC cell exhibits a pretilt angle in the absence of the bias electric field. 4. Results and Discussions

Figure 3 shows plots of the experimentally measured transmittances of the three types of phase shifters. The cumulative transmittances for the THz phase shifters of type A, B, and C, reduced due to absorption losses of fused silica, LCs, and ITO NWhs were 20%, 25%, and 31%, respectively. The difference is mainly due to the numbers of substrates and ITO NWhs layers that were employed in the three configurations.

The transmittance of π/2 phase shifters using ITO NWhs as electrodes (≥75%) is much more superior than that using sputtered ITO film (≤1%) [5]. Therefore, in this case of 2π waveplate with multi-cell structure using ITO NWhs as electrodes, transmittance of 20~30% is reasonable and much superior to the previous state-of-art result. Using complex permittivities or refractive indices of ITO NWhs, fused Silica, and LCs, reported in our previous works [18,19,20,24] in a Jones matrix formulation with Fresnel equations, we can estimate the loss caused from different interfaces of the device. The analysis shows that the most serious sources of loss for our device come from the interfaces of fused Silica/ITO NWhs, and LCs/ITO NWhs. On the other hand, losses incurred at air/ fused Silica and LCs/ fused Silica interfaces are slight.

In Figure 4, we have plotted phase shift as a function of frequency from 0.2 to 1.0 THz by varying the voltages for the three types of devices. As expected, the measured phase shift changed linearly with frequency for a given bias voltage. For the type-A phase shifter, the slope of linear fits varied from 0.40π/THz to 2.67π/THz as the applied voltage was ramped from 2.12 to 10.61 V (rms). For the type-B and type-C structures, they varied from 0.51π/THz to 2.49π/THz, and 0.60π/THz to 2.59π/THz, as the applied voltages was ramped from 2.40 to 10.61 V (rms) and 5.66 to 21.21 V (rms), respectively.

In Figure 5, we have plotted experimentally measured phase shifts as a function of the driving voltage. The theoretical curve according to the model proposed in this study and those use earlier ones that are based on simpler models with approximations. References [3,8] are also shown.

In all cases, more than 360° degrees of phase shifts was achieved for all three types of devices. Further, Bias voltages for achieving 2π phase shift at 1.0 THz were V (rms) ≈ 2.6, 5.3, 10.3 for types A, B, and C devices, respectively. Thus, the effect of ITO NWhs for assisting the alignment and reorientation of LC molecules is significant. Further, this characteristic for type A device is compatible with CMOS technology. We measured the response time properties of the present ITO NWhs phase shifter. The 20 to 80% rise time and fall time are around 52 s and 240 s, respectively.

Overall, the agreement of experimental data with the present model is significantly better than previous ones. To check quantitatively the accuracy of the theoretical models, we define an error function, ∆ = Σ|Л_j,theo−Л_j,exp|, where j equals 1, 2, 3, …. The parameters, Л_j,exp and Л_j,theo, represent the experimental and theoretical phase shift when a bias voltage, V_j, was applied. For the case of data shown in Figure 5a for type A and employing the theoretical model that is described in Refs. [3,8], and this work, ∆ were found to be 8.19, 8.38, and 6.51, respectively. For the case of data shown in Figure 5b,c for type B and C, similar sets of values for ∆ were found to be (7.06, 16.11, 4.25), and (17.23, 41.89, 10.96), respectively. These analyses further confirmed that the theoretical method that is presented in this work is in closer agreement with the experimental data.

Finally, we summarize the experimental data and calculated parameters for the three types of devices in Table 1.

5. Conclusions In this work, we theoretically and experimentally studied tunable terahertz (THz) phase shifters that are based on a sandwiched liquid crystal (LC) cell with ITO nanowhiskers (NWhs) as transparent electrodes. Three designs were presented. All achieved more than 360° of phase shift at 1.0 THz. The bias required was as low as ~2.6 V (rms), while the highest throughput was more than 30% for Type A devices. The bias voltage reported is a new record, which is approximately 40 times smaller than that reported previously using electrically tunable LC device. Such operating characteristics are compatible with CMOS technology. Significance of the NWhs in reducing the required voltage is demonstrated. The experimental results are in good agreement with a theoretical formulism that took into account super-thick LC cells (~1 mm) and effect of the pretilt. We also demonstrated a new method for measuring pretilt angles of LC cells by a novel THz technique.

Figure 1.(a) Schematic diagrams of three different configurations of indium-tin-oxide-nanowhiskers (ITO-NWhs)-based phase shifters, type A, B, and C, respectively. The cross-sectional images of (b) the substrate of ITO NWhs, (c) ITO NWhs coated with polyimide, and (d) ITO NWhs treated with the rubbing process.

Figure 2. Configurations for determining the correction factors of the thickness (α), and pretilt angle (β) of liquid crystal (LC) devices. The cell (a) in the e-ray mode without external field, (b) in the o-ray mode with high driving voltage, and (c) in the o-ray mode without external field. (d) Index ellipsoid used to describe the pretilt angle (θ0).

Figure 3. Tunable terahertz (THz) transmittance of the phase shifters, type A, B, and C, respectively.

Figure 4. THz Phase shift as a function of THz frequency for five driving voltages, respectively, for devices of (a) type A, (b) type B, and (c) type C configurations.

Figure 4. THz Phase shift as a function of THz frequency for five driving voltages, respectively, for devices of (a) type A, (b) type B, and (c) type C configurations.

Figure 5. Phase shift as a function of applied voltage for devices of (a) type A, (b) type B, and (c) type C configurations.

Figure 5. Phase shift as a function of applied voltage for devices of (a) type A, (b) type B, and (c) type C configurations.

	Type A	Type B	Type C
∆ϕE at 1 THz	2.750π	2.832π	2.690π
∆nE	0.183	0.191	0.177
θ0	19.07°	15.98°	21.42°
α	1.064	1.081	1.187
β	0.915	0.955	0.885
Bias voltage for 2π phase shift at 1.0 THz V (rms)	2.6	5.3	10.3
Averaged transmittance	20.0%	25.4%	31.3%

Author Contributions

C.-S.Y., C.K., and C.-L.P. conceived the research. C.-S.Y. and C.K. carried out optical measurements, analysed the data, and performed theoretical analysis. C.-S.Y. fabricated the devices and received assistance from C.K., P.-H.C., W.-T.W., R.-P.P., and P.Y., C.-S.Y. and C.-L.P. wrote the manuscript with inputs from all authors.

Funding

This study was partially funded by grant 104-2221-E-007-093-MY3 and others of the Ministry of Science Technology, as well as the Academic Top University Program of the Ministry of Education, Taiwan.

Acknowledgments

C.-L.P. would like to thank the U.S. Air Force Office of Scientific Research for support, AOARD FA2386-13-1-4086.

Conflicts of Interest

The authors declare no conflicts of interest.

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