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Copyright © 2016 Lele Wang et al. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

Abstract

Here we report a facile, efficient, and catalyst-free method to realize C-C cross-coupling of aryl chlorides and inert arenes under UV light irradiation. The aryl radical upon homolytic cleavage of C-Cl bond initiated the nucleophilic substitution reaction with inert arenes to give biaryl products. This mild reaction mode can also be applied to other synthetic reactions, such as the construction of C-N bonds and trifluoromethylated compounds.

Details

Title
Photoinduced C-C Cross-Coupling of Aryl Chlorides and Inert Arenes
Author
Wang, Lele; Qiu, Wenzhao; Shao, Hongge; Yuan, Rusheng
Publication year
2016
Publication date
2016
Publisher
John Wiley & Sons, Inc.
ISSN
1110662X
e-ISSN
1687529X
Source type
Scholarly Journal
Language of publication
English
ProQuest document ID
1797845294
Copyright
Copyright © 2016 Lele Wang et al. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.