Full Text

Turn on search term navigation

1. Introduction

Wood is a sustainable and abundant biomaterial that consists of cellulose, hemicellulose, and lignin [1,2]. It possesses a lot of advantages, such as light weight [3], high strength [4], easy machinability [5], renewability [6], thermal insulation [7], aesthetic characteristics [8], low price [9] and environmental friendliness [10]. For thousands of years, wood has been extensively utilized in various applications, including fuels [11], indoor and outdoor construction and decorations [12,13,14,15], tools [16], papers [4] and furniture [17]. Due to rich hydroxyl groups, the hydrophilic wood is susceptible to water [3], fire [5], pollutants [18], insects [7], living microorganisms (i.e., bacteria and fungi) [19,20,21] and weathering factors (i.e., acidic rain and UV lights) (Figure 1) [14,15,22], resulting in its dimensional instability (i.e., swelling and shrinking), cracking, decay and degradation [3,9,11,23]. Thus, wood surfaces are urgently needed to be protected such that they can be stably and safely used in different environmental conditions.

Due to excellent liquid repellency, superhydrophobic surfaces (SHSs) (contact angle ˃ 150° and contact angle hysteresis ˂ 10°) have drawn much interest because of their versatile applications in oil/water separation [24,25], self-cleaning [26], anti-corrosion [27,28], anti-fouling [29] and anti-icing [30,31]. By introducing hierarchical roughness and low surface energy, various substrates can be endowed as SHSs, including wood, metals, ceramics, polymers, glass, fabrics and papers [32,33,34,35]. Among them, wood surfaces with hydroxyl groups can be easily decorated with nanomaterials, followed by the chemical modification of low-surface-energy materials. Once superhydrophobic wood surfaces (SHWSs) are achieved, the disadvantages of wood can be mitigated when utilized in real outdoor practical applications.

To the best of our knowledge, there are many reviews on various superhydrophobic surfaces [36,37,38,39,40,41,42], and the state-of-the-art review paper on superhydrophobic wood substrates is lacking and urgently needed. Although Li et al. [43], Ramesh et al. [44], and Wei et al. [45] have recently introduced wood-based composites and wood-based superhydrophobic surfaces, a comprehensive review paper particularly focusing on wood substrates by introducing surface superhydrophobicity is still needed. In this review paper, the recent advances in various preparation methods of SHWSs are summarized and discussed, including immersion, spray-coating, hydrothermal synthesis, dip-coating, deposition, sol-gel process and other methods, respectively. Then, the versatile practical applications of SHWSs are introduced in terms of anti-fungi/anti-bacteria, oil/water separation, fire resistance, anti-ultraviolet (UV) irradiation, electromagnetic interference (EMI) shielding, photocatalytic performance and anti-icing, respectively. In the end, the perspectives and outlooks for the developments and practical applications of SHWSs are revealed and proposed. It is believed that the rational design of SHWSs provides new insights into the utilizations of wood materials, and thus extends the real applications of wood materials in our daily life and industry.

2. Preparation Methods of SHWSs

Generally, the preparation of SHSs needs to satisfy two necessary requirements: the creation of hierarchical structures and the chemical modification of low-surface-energy materials [46]. To realize surface superhydrophobicity of wood materials, there are two approaches towards preparing SHWSs: (1) the chemical modification of low-surface-energy materials and the simultaneous formation of hierarchical surface roughness (i.e., microstructures and nanostructures); (2) the introduction of hierarchical surface roughness, followed by the chemical modification of low-surface-energy materials [32]. Recently, various preparation methods have been successfully designed and applied on wood materials with rich hydroxyl groups to achieve SHWSs, including immersion, spray-coating, hydrothermal synthesis, dip-coating, deposition, sol-gel process and other methods. In this section, these methods of preparing SHWSs have been summarized in Table 1, and then they will be separately introduced and summarized in details as well as their own advantages.

2.1. Immersion

Immersion is a facile and cheap method, which does not need complex operations or special devices. Because of surface hydrophilicity, wood is easy to react with chemicals in solutions [133,134]. Usually, there are two approaches towards preparing SHWSs with the immersion methods: (a) One-step immersion method [135,136]. That is, wood substrates are directly immersed either in the solutions of low-surface-energy materials or in mixture solutions of nanoparticles and low-surface-energy materials. (b) A two-step method [137]. Wood substrates are firstly immersed in the suspension of nanoparticles. After being immersed in above suspension solutions, SHWSs can be easily obtained with further chemical modification of low-surface-energy materials [19,47,48,49,104].

As for one-step immersion, wood can be immersed in solutions of low-surface-energy materials or mixture solutions of nanoparticles and low-surface-energy materials [50,138]. As we all know, both hierarchical structures and low surface energy on wood substrates are necessary for the preparation of SHWSs. The reason why SHWSs can be obtained by immersing wood substrates in the solutions of low-surface-energy materials is that micro/nanostructures can be simultaneously formed during an immersion process [32]. For example, Ou et al. achieved SHWSs by immersing wood substrates (i.e., balsawood, pine wood and basswood) in a composite silane solution consisting of hexadecyltrimethoxysilane (HDTMS) and methyltrimethoxysilane (MTMS) [11]. Liu et al. fabricated SHWSs by using potassium methyl siliconate via a convenient solution-immersion method [51]. Lin et al. realized the production of SHWSs by immersing wood in a modifier solution of n-hexane, PMHS and Kastredt catalyst [10]. Furthermore, when aqueous mixture solutions of nanoparticles and low-surface-energy materials are utilized, SHWSs can also be achieved by one-step immersion. Jia et al. placed wood substrates in a homogeneous reactant solution (i.e., perfluorooctyltriethoxysilane (PFOTS) and BiOCl) for 1.5 h and achieved SHWSs (Figure 2a) [139]. Yue et al. obtained RTVSR/SiO₂ coated superhydrophobic wood by immersing wood into the modifier solutions of poly(methylhydrogens)siloxane (PMHS), vinyl-terminated polydimethylsiloxane (Vi-PDMS) and SiO₂ nanoparticles for 10 min and drying wood at 100 °C for 60 min [52]. Thus, the one-step immersion method as a facile approach is suitable for preparing SHWSs.

As for the two-step method, the hierarchical roughness is usually achieved first, followed by the chemical modification of low-surface-energy materials [53]. For instance, Kang et al. obtained SHWSs by separately immersing wood substrate in the epoxy resin solution and the SiO₂-NH₂ particle suspension followed by treatment with 2 wt.% octadecyltrichlorosilane solution (Figure 2b) [54]. Xia et al. prepared SHWSs by using Cu₂O nanostructures and phenol formaldehyde resin via an immersion process, followed by the chemical modification of 4.8 wt.% stearic acid solution (Figure 2c) [55]. Yang et al. used nano-Al₂O₃, KH580 and polydopamine (PDA) to obtain hierarchical roughness on wood substrates, and then modified the resulting wood substrates with 2 wt.% octadecyltrichlorosilane (OTS) solution to realize low surface energy (Figure 2d) [56]. Gao et al. coated silica particles on wood by using an immersion method and then fabricated poly(ε-caprolactone) film on the resulting wood surface by using a simple pipetting process [57]. Compared with the one-step immersion method, the surface roughness can be enhanced by using the two-step immersion method, thereby improving the surface superhydrophobicity of wood substrates.

To accomplish the immersion process, wood substrates should be immersed in solutions. Compared with other substrates (i.e., metal, glass and ceramics), however, most wood materials are lighter than water, which need to be pressed in the immersion solution [58,59]. In addition, the immersion method can be scaled up for the preparation of SHWSs. Therefore, the immersion method as a low-cost approach is suitable for the fabrication of SHSs (i.e., SHWSs).

2.2. Spray-Coating

Spray-coating is a simple, low-cost, substrate-independent, scalable and efficient method to prepare very thin coatings [4,140,141,142,143,144,145]. When the spray-coating method is used for the preparation of SHWSs, it is supposed to simultaneously form hierarchical roughness and low-energy surfaces. After a curing and/or drying process (i.e., the evaporation of solvents), the dispersion of the desired solutions can be applied on the wood substrate to form superhydrophobic coatings [14,60,61,62,63,146,147,148]. In addition, the thickness of superhydrophobic coatings can be easily adjusted by many factors, including the concentration of dispersion [64], the pressure of spray gun [149], the spraying time [65], the repeated times [66], the distance between wood substrate and spray gun [67] and the drying temperature [68].

For example, Zhan et al. sprayed a solution of Cu₂O nanoparticles/phenol formaldehyde (PF) by using a spray gun on the Masson’s pine and pecan wood samples with a distance of 60 cm, followed by the treatment with 5% solution of stearic acid in ethanol at ambient temperature for 2 h [69]. Tu et al. spray-coated a dispersion of TiO₂/perfluoroalkyl methacrylic copolymer (PMC)/water (i.e., the mass ratio is 1:1:25) on wood substrate for 10 s, and air-dried for 10 min, which was repeated for 3 times to realize a superhydrophobic coating with a desired thickness [70]. Huang et al. prepared a paint mixture solution consisting of lignin-coated cellulose nanocrystals (L-CNC) particles and polyvinyl alcohol (PVA) particles, and then successfully realized superhydrophobic coatings on wood substrate by spraying a L-CNC/PVA composite paint mixture followed by modifying via chemical vapor deposition (Figure 3a) [150]. Che et al. prepared a dispersion of hydrophobic 1H,1H,2H,2H-perfluorooctyltrichlorosilane/SiO₂ nanoparticles (POTS-SiO₂), and then evenly spray-coated this dispersion on a flexible Janus wood membrane to achieve SHWSs (Figure 3b) [71].

Although the spray-coating method is a substrate-independent approach towards preparing SHWSs, the adhesion between superhydrophobic coatings and wood substrates should be considered such that the durability of SHWSs can be enhanced. To increase the adhesion between coatings and wood substrates, an adhesive layer is usually introduced on wood substrates before a spray-coating process [72,73]. For instance, Huang et al. treated wood substrate with an adhesive layer of commercial quick-drying transparent topcoat, and then achieved SHWSs by spraying a hydrophobic CNC-ethanol suspension after drying for 15 min at room temperature (Figure 3c) [64]. Tuong et al. treated wood substrates with a 50 wt.% Epoxy#3021 solution of two components (Part A and Part B), and then spray-coated a suspension of hydrophobic ZnO nanoparticles on the epoxy-pretreated Styrax tonkinensis wood by using a spray gun (i.e., 0.2 MPa compressed air) at a distance of ~10 cm (Figure 3d) [74]. Yang et al. firstly spray-coated an epoxy resin/acetone solution onto 1-Tetradecanol (TD)-decorated delignified wood (DW) substrate, and then further deposited SiO₂ to obtain the superhydrophobic TD/DW composite (Figure 3e) [147]. Xue et al. spray-coated a SiO₂@HDTMS superhydrophobic spray solution of SiO₂, an inorganic aluminum phosphate (AP) adhesive layer and Hexadecyltrimethoxysilane (HDTMS) on various substrates (i.e., wood) by using a spray gun with an orifice diameter of 0.8 mm under an exhaust pressure of 42 psi (Figure 3f) [65].

Of course, the spray-coating method can be utilized by combining with other preparation methods to fabricate SHWSs, such as UV polymerization [75], chemical vapor deposition (CVD) [76,77,151], plasma [152] and immersion [153]. Spray-coating, as a widely used approach, is not limited by surface structures or the shapes of substrates, which is suitable for various substrates (i.e., wood, glass, metals, ceramics and papers). Thus, the spray-coating method can be efficiently used for the preparation of SHWSs.

2.3. Hydrothermal Synthesis

Hydrothermal synthesis is a method that nanoparticles or surface crystal morphologies can be realized in aqueous solutions at high vapor pressure [140]. During a hydrothermal process, the reaction temperatures (i.e., 85 °C [154,155], 90 °C [1,5,78,156], 100 °C [20] and 120 °C [1,79]) and the reaction time (i.e., 2 h [154], 5 h [78], 6 h [1,5,20,156], 8 h [79] and 12 h [155]) have been chosen for the reaction, which greatly influence the formation of crystalline phases around the melting point of reactants. This approach can be employed to create hierarchical micro/nanostructured crystals on the desired wood substrates when preparing SHWSs, including MnFe₂O₄ [79], CoFe₂O₄ [156], ZnO [5,80,81,155,157], TiO₂ [7,20,78,82,83,84], WO₃ [1,85,86], Cu₂(OH)₃Cl [87], α-FeOOH [88], Cu₂O [89] and Ti/Si composite [90].

Wang et al. successfully planted lamellar MnFe₂O₄ on wood substrate through the association of hydrogen bonds via one-pot hydrothermal method (Figure 4(a1)), and obtained SHWSs by the chemical modification of fluoroalkylsilane (Figure 4(a2,a3)) [79]. Gan et al. prepared a hydrophilic layer of CoFe₂O₄ nanoparticle on the wood substrate via a hydrothermal method, and realized a superhydrophobic coating on wood substrate by the chemical modification of octadecyltrichlorosilane (OTS) (Figure 4b) [156]. Gao et al. fabricated a durable Cu₂O microsphere superamphiphobic film on wood substrate via a hydrothermal method, followed by the chemical modification of (heptadecafluoro-1,1,2,2-tetradecyl)trimethoxysilane (FAS-17) [89]. Sun et al. achieved the in situ synthesis of WO₃ nanoparticles on a wood substrate via a two-step hydrothermal process, and successfully obtained a photochromic and superhydrophobic wood substrate [1].

Among the above nanomaterials, the preparation of ZnO and TiO₂ are widely utilized by the hydrothermal method. For example, Fu et al. investigated the formation of a superhydrophobic ZnO nanorod array on wood substrate via a cosolvent hydrothermal method at 85 °C for about 2 h (Figure 4c) [154]. Wang et al. fabricated a sword-like superhydrophobic ZnO film on wood substrate via an alkaline hydrothermal method [155]. Gao et al. used a low-temperature hydrothermal method to decorate TiO₂ nanoparticles on a wood substrate, and then achieved SHWSs by the chemical modification of low-surface-energy materials (i.e., OTS and FAS-17) [83,84]. Gao et al. obtained a robust superhydrophobic Ag-TiO₂ composite film on wood substrate via a two-step method by combining a hydrothermal method with silver mirror reaction [78].

The hydrothermal method, however, is not suitable for the formation of non-crystalline micro/nanostructured materials on wood substrates. In addition, this method requires special devices (i.e., Teflon-lined stainless-steel autoclave) with high vapor pressure to realize hierarchical roughness on wood substrates. Generally, this method has been extensively used in laboratory, while it still meets challenges of the scale-up preparation and safety in industry.

2.4. Dip-Coating

Dip-coating is a widely used method to construct superhydrophobic coatings because of its easy operation and high efficiency [34]. That is, the desired substrates are immersed into a solution of nanoparticles and/or low-surface-energy materials at a constant speed, and then experience a drying or curing process [146]. Due to rich surface hydrophilic functional groups, wood substrates are easily to react with chemical solutions of nanoparticles and/or low-surface-energy materials via the dip-coating method for the preparation of SHWSs. To achieve ideal SHWSs, the dip-coating process can be repeated for several times such that the thickness of superhydrophobic coatings can be controlled on wood substrates [3,158,159]. Similarly, the surface hierarchical roughness can also be changed by adjusting the concentrations of mixture solutions during a dip-coating process [160].

Kaewsaneha et al. obtained SHWSs by decorating wood substrates with alkyl ketene dimer (AKD) nanoparticles due to the reactions between AKD and the hydroxyls of cellulose via a dipping process (Figure 5a) [9]. Ding et al. achieved SHWSs by simply dipping the wood in the modifier solutions of hydrofluorosilicone oil (HFSO), tetramethyl tetravinyl cyclotetrasiloxane (V4) and hydrophobic SiO₂ (Figure 5b) and heating the resulting wood samples at 105 °C for 2 h [158]. Tu et al. applied silica/epoxy resin/FAS nanocomposites to wood substrate pre-coated with epoxy resin to realize SHWSs by a dipping process (Figure 5c) [159]. Janesch et al. prepared SHWSs by dip-coating spruce wood in a mixture of tung oil and natural beeswax, followed by the deposition of micronized sodium chloride particles (Figure 5d) [160]. Chang et al. successfully obtained SHWSs by simply dip-coating wood substrate with a suspension of hydrophobic silica nanoparticles and polydimethylsiloxane (Figure 5e) [91].

To improve the durability of superhydrophobic coatings, either adding adhesive binders (i.e., epoxy resin) [22,159] or increasing repetition of dipping times [3,12,145,161] are carried out for preparing SHWSs during a dipping process. Furthermore, the drying or curing process is very important to preparing SHWSs by the dip-coating method, which can be controlled by the drying/curing temperature (i.e., 50 °C [92], 80 °C [93,162] and 103 °C [94]) and/or using vacuum-pressurized equipment [95,163]. In short, the dip-coating method can be scaled-up in real applications, which is suitable for the preparation of SHWSs.

2.5. Deposition

Deposition has been used for the preparation of SHWSs, including chemical bath deposition [164], solvothermal deposition [165], electroless deposition [166], chemical vapor deposition (CVD) [96], vapor deposition [97,98], plasma deposition [99], combustion deposition [61,100], thermal-driven deposition [167], reduction deposition [168,169] and plasma-enhanced chemical vapor deposition (PECVD) [170]. The above deposition methods are suitable for the preparation of SHWSs based on the properties (i.e., physicochemical and insulation properties) of wood substrates.

Zhang et al. successfully obtained a superhydrophobic SiO₂/PMHS coating on wood substrate by depositing SiO₂ nanoparticles and then hydrophobically treating with 1% PMHS modifier solution (Figure 6(a1,a2)) [101]. Wang et al. prepared SHWSs by immersing PDA-coated wood substrates in an electroless copper bath for 12 h, soaking the resulting wood substrates in octadecylamine ethanol solution at 30 °C for 24 h, and finally drying at 60 °C, respectively [166]. Wu et al. obtained SHWSs by depositing a polytetrafluoroethylene/microcapsule/zinc oxide (PTFE/MC/ZnO) dispersion on wood substrate, followed by the chemical modification of a mixture of stearic acid (4 wt.%) acidified with acetic acid in an ethanol solution [171]. Yao et al. achieved SHWSs with one-step solvothermal deposition of ZnO nanorod arrays on wood substrates by combining an immersion process, self-assembly and a hydrothermal method (Figure 6b) [165]. Liu et al. firstly treated wood substrate with epoxy resin acetone solution, deposited amino-functionalized silica particles on the epoxidized wood sample, and finally realized SHWSs with the self-assembly of an OTS monolayer (Figure 6c) [172]. Tan et al. realized superhydrophobic/superoleophilic wood flour via the deposition of ZnO nanoparticles and the subsequent chemical modification of octadecanoic acid (Figure 6d) [102]. Furthermore, the candle soot is also be used to decorate wood substrates by combustion. Li et al. fabricated SHWSs by spray-coating a mixture solution of pre-PDMS, n-hexane and cross-linking agent (the mass ratio is 10:10:1) on balsa wood, and depositing candle soot at a height of 2 cm over the flame [61].

To achieve SHWSs, deposition as an individual method is not enough to realize surface superhydrophobicity, and it is necessary to combine it with other techniques (i.e., spray-coating [61], immersion [166], self-assembly [8], reduction [173], dip-coating [95], magnetron sputtering [103] and chemical modification of low-surface-energy materials [171]). However, some of the deposition methods need special or expensive equipment (i.e., CVD and PECVD), which is not beneficial to the extensive and scaled-up preparations of SHWSs. Thus, the chosen and utilization of deposition methods for preparing SHWSs need to be investigated based on the actual demand and experimental conditions.

2.6. Sol-Gel Process

The sol-gel process is a simple, controllable and inexpensive method for preparing SHSs on various substrates [174]. The main purpose of the sol-gel method is to create surface roughness on the desired substrates (i.e., wood and fabrics). Generally, chemical solutions or colloidal solutions (sol) are used as precursors, and gels with three-dimensional networks can be obtained after a series of hydrolysis and polycondensation reactions [140,146,175]. Because of rich hydrophilic functional groups, superhydrophobic coatings are suitable to be formed on wood surfaces by using the sol-gel method and low-surface-energy modification [176].

Tsvetkova et al. obtained SHWSs by coating wood substrates that were pre-coated by a primer (i.e., silica sol with boric acid or commercial reagent ethyl silicate-40) with a sol-gel@paint composition consisting of siloxane modifiers, tetraethoxysilane (TEOS) and aerosil R-972 (Figure 7a) [108]. Wang et al. successfully achieved SHWSs by depositing a film of silica nanoparticles on a wood substrate by using silica sol via a sol-gel process, followed by chemical modification with hydrophobic hexadecyltrimethoxysilane (HDTMS) and a drying process (Figure 7b) [109]. Xia et al. constructed a superhydrophobic coating of 1H,1H,2H,2H-perfluoroalkyltrichlorosilane (PFDS)-SiO₂ on wood substrate by using a sol-gel process and CVD (Figure 7c) [110]. Chang et al. fabricated superhydrophobic organic–inorganic coatings on wood substrates by using an inorganic precursor (i.e., tetraethoxysilane (TEOS)) and an organic modifier (i.e., hexadecyltrimethoxysilane (HDTMS)) via a sol-gel process (Figure 7d) [105].

To prepare SHWSs, the sol-gel method is usually combined with other techniques, such as the hydrothermal synthesis [17], the chemical modification of low-surface-energy materials [106], dipping [177] and electron beam curing [107]. As for the sol-gel methods, reactions need to experience a sol-gel process, which limit the resources of precursors or sols (i.e., SiO₂ sol and TiO₂ sol) for the preparation of SHWSs. Compared with other methods for preparing SHWSs, the sol-gel method can be scaled-up and applied on large-area surfaces, which facilitates extending its applications in our daily life and industry.

2.7. Other Methods

Except for the above methods, there are also various other methods for preparing SHWSs, including coordination-driven multistep assembly [112], dehydrogenation-driven assembly [178], layer-by-layer assembly [15,179], self-assembling and retentions [111], brushing [12,180], drop-coating [181], impregnation [21,182], atom transfer radical polymerization (ATRP) [119], grafting [120,183], casting [121,122], solvothermal method [128], alkali-driven method [129], wet chemical process [184], multi-solvent continuous modification method [185], etching [186], carbonization [187], top-down strategy [188], soft lithography [130], in situ growth [107], hot-compression treatment [189], hot pulling technique [190], nanoimprint lithography [131], photochemical approach [191], spin-coating [192], silver mirror method [193], silanization [194,195], replication [132], etc.

Different assembly methods have been used for preparing SHWSs. Wang et al. prepared tannic-acid-FeIII-based superhydrophobic coatings on wood longitudinal surfaces with natural micro-grooved structures via a coordination-driven multistep assembly and chemical modification of octadecanethiol (Figure 8a) [112]. Lu et al. deposited TiO₂ (or SiO₂ [113]) nanoparticles on wood substrates by using a layer-by-layer assembly method and chemical modification of 1H,1H,2H,2H-perfluoroalkyltriethoxysilane (POTS) [114]. The assembly method is usually not enough to achieve surface superhydrophobicity, which needs to be further modified with low-surface-energy materials.

Compared with spray-coating, the brushing method is a very easy-operation approach to coat superhydrophobic coatings on wood substrates, which does not require expensive equipment or complex procedures [115]. Yao et al. fabricated SHWSs with two coating steps, which consists of preparation of the 1st layer by dip-coating in a cellulose stearoyl ester (CSE) solution and preparation of the 2nd layer by brushing a glycerol stearoyl ester (GSE) solution on the resulting wood samples (Figure 8b) [16]. However, superhydrophobic coatings on wood substrates are not determined by the methods (i.e., spraying, brushing and dipping), which sometimes only depends on the emulsion or suspension for preparing SHWSs [116].

The drop-coating method is a facile approach for preparing SHWSs, wherein wood substrates are coated by gradually dropping mixture solutions [23,118]. Wang et al. obtained SHWSs by dropping several drops of a mixture dispersion solution that consisted of polystyrene (PS), tetrahydrofuran (THF) and silica particles on wood substrate and consequently drying the sample at room temperature (Figure 8c) [181]. Liu et al. coated a poplar wooden substrate with a suspension of SiO₂ and polyvinyl alcohol (PVA), and then realized surface superhydrophobicity after treating with an octadecyltrichlorosilane (OTS) solution to obtain a self-assembled layer of the OTS monolayer [117]. As for the thickness of superhydrophobic coatings, it can be controlled by repeating the drop-coating procedure; the solvent should be completely evaporated before the next drop-coating procedure.

ATRP is an efficient method for grafting polymers on substrates, which can be accurately controlled. Wang et al. used wood-Br with active terminal bromine as the macro-initiator, and fabricated SHWSs by grafting poly(2-(perfluorooctyl)ethyl methacrylate) (PFOEMA) onto a wood substrate via ATRP (Figure 8d) [119]. Grafting as a facile approach is also used to decorate wood substrates with long-chain alkyls to realize surface superhydrophobicity. Wang et al. successfully prepared highly hydrophobic wood substrates by grafting long-chain alkyl groups onto wood cell walls via urethane linkage (or ester linkage [120]) [183].

Casting is a simple and low-cost approach for constructing SHSs on wood substrates. Shen et al. drop-casted polymer latexes onto sanded wood surfaces, and obtained SHWSs by drying the above polymer latexes at 30 °C (Figure 8e) [121]. Similarly, Wang et al. casted a fluoroalkylsilane/silica composite suspension onto sanded wood substrate, and achieved SHWSs by drying at 120 °C for 2 h [122]. Compared with the drop-coating method, the casting method has a reconstructing process for the polymer coatings by drying.

Impregnation is a process of permeating or infusing chemicals on the chosen substrates, which is suitable for preparing durable superhydrophobic coatings on wood substrates with natural roughness (or porous structures) [21,123]. For example, Yang et al. prepared durable SHWSs by using a two-step impregnation consisting of chemical modification with natural maleic rosin and subsequent coating with TiO₂ nanoparticles to increase surface roughness [124]. Of course, the impregnation approach can be improved by the assistance of vacuum with pressure (i.e., 0.01 MPa [125], 0.5 MPa [125] and −0.1 MPa [13]). Liu et al. realized SHWSs by the impregnation of a silica/silicone oil complex emulsion into wood substrates with the help of vacuum (i.e., 0.01 MPa for 1 h and 0.5 MPa for 1 h) and drying with different temperatures (i.e., 60 °C for 12 h, elevated to 80 °C for 12 h, and elevated to 103 °C for drying) [125]. Furthermore, the impregnation method can combine with other methods (i.e., hydrothermal method [80], drying [126] and low-surface-energy modification [127]) for preparing SHWSs.

Some solvent-based methods have been introduced for preparing SHWSs, such as the solvothermal method [128], alkali-driven method [129], wet chemical process [184] and multi-solvent continuous modification method [185]. For example, Cai et al. prepared superhydrophobic (polydivinylbenzene) PDVB-wood membrane by implementing PDVB onto wood substrate via a solvothermal method (Figure 8f) [128]. Jia et al. utilized an alkali-driven method by using SiO₂ nanoparticles and vinyltriethoxysilane (VTES) [129]. Wang et al. fabricated a lamellar superhydrophobic ZnO coating on wood substrate by using a wet chemical process followed by modification of stearic acid [184]. Yang et al. fabricated a polyethylene glycol (PEG)-functionalized SiO₂/poly(vinylalcohol) (PVA)/poly(acrylic acid) (PAA)/fluoropolymer hybrid by using a multi-solvent continuous modification method, including chemical reaction, solution self-assembly and impregnation [185]. To some extent, the solvent-based methods may be similar to the immersion method, while the driving force for preparing SHWSs is different.

Silanization is a very facile approach to modifying wood substrates. Yin et al. modified birch wood substrate by the silanization of silicone nanofilaments and 1H,1H,2H,2H-Perfluorodecyltrichlorosilane (PFDTS) in a sealed desiccator [195]. Zhang et al. fabricated superhydrophobic coatings on various substrates (i.e., plywood, filter paper, aluminum, cotton fabric and plastic) by a single-step, stoichiometrically controlled reaction of long-chain organosilanes with water [194]. Zhu et al. fabricated wood aerogels by using a top-down strategy to remove lignin and hemicellulose, followed by freeze-drying (Figure 8g) [188]. They successfully obtained SHWSs after the treatment of methyltrimethoxysilane (MTMS) in an in-house reaction chamber via the CVD method [188]. To achieve surface superhydrophobicity, the silanization method as a single approach is not enough for many smooth substrates (i.e., glass, metals and polymers), while it is suitable for preparing SHSs on wood substrates with natural hierarchical surface roughness.

Bio-inspired from nature, template methods are also used for preparing SHWSs, including soft lithography, nanoimprint lithography and replication. Chen et al. obtained superhydrophobic taro-leaf-like film-decorated wood surfaces by using the PDMS stamp (as being peeled from the taro leaf) and PDMS/nano-Fe₃O₄ composite suspensions via soft lithography (Figure 8h) [130]. Yang et al. realized a superhydrophobic PVB/SiO₂-coating-decorated wood substrate by using a one-step solvothermal method and a nanoimprint lithography method (Figure 8i) [131]. Yang et al. prepared canna-leaf-like micro/nanostructures on a wood substrate by using PDMS as a template and replicating polyvinyl butyral (PVB)/SiO₂ coatings on wood substrate [132]. Although the template method is a well-controlled approach to preparing SHWSs, it is still not suitable for large-scale production of SHWSs due to the special and complex procedures required.

In addition to this, there are some interesting methods preparing SHWSs. For example, Li et al. reported that a robust superhydrophobic coating can be successfully achieved on wood substrate through in situ mineralization and polymerization (Figure 8j) [107]. Wu et al. used a silver mirror method to realize in situ growth of silver nanoparticles on wood substrate followed by the chemical modification of a mixture solution of stearic acid (4 wt.%) and ethanol [193]. In summary, the above methods of preparing SHWSs have own unique characteristics, and they can be chosen based on cost and experimental conditions. In addition, the practical applications of wood materials should be considered; this is because SHWSs need to have different physiochemistry and mechanical properties in different environments and different practical applications. Furthermore, to enhance surface superhydrophobicity, multiple of the above methods can be combined such that SHWSs can be successfully obtained with excellent properties in different experimental conditions.

3. Applications of SHWSs

Due to excellent surface superhydrophobicity, SHWSs has been extensively utilized in various fields, including anti-fungi [16], anti-bacteria [119], oil/water separation [102], fire resistance [133], anti-UV irradiation [156], photo-response [137], electromagnetic interference (EMI) shielding [79], anti-icing [177] and wood-based devices [147]. In this section, we summarize recent applications of SHWSs, and discuss challenges for the versatile application of SHWSs.

3.1. Anti-Fungi and Anti-Bacteria

When exposed to favorable environments (i.e., moisture, sufficient air and fat), hydrophilic wood surfaces can be easily degraded and damaged due to the attacks of fungi and bacteria [16]. Traditionally, inorganic waterborne preservatives (i.e., chromated copper arsenate) [21] and organic mold inhibitors (i.e., 4,5-dichloro-2-octyl-isothiazolone) [196] have been used to protect wood surfaces. However, they suffer from harms to human beings and environments, degradation and decomposition [21,197]. Recently, an alternative strategy is to introduce SHSs, which can serve as water barriers and thus prevent SHWSs from being permeated by moisture [16]. Up to now, many SHWSs have been used in the fields of anti-fungi [16,21] and anti-bacteria [19,78,119,193].

For example, Yao et al. prepared SHWSs by dip-coating and brush-coating, and found that SHWSs can thoroughly prevent fungal attachment to wood surfaces compared to hydrophobic or hydrophilic wood surfaces [16]. This is because SHWSs work as water barriers and can isolate moisture with wood structures, thus limiting water resources for the growth of fungi and bacteria. Another reason is that SHWSs have very low adhesion, which makes the attachment of fungi and bacteria on SHWSs difficult. Lu et al. carried out mold-proof experiments with rubberwood and superhydrophobic rubberwood by using four kinds of molds (i.e., Botryodiplodia theobromae, Trichoderma viride, Penicillium citrinum and Aspergillus niger), and found that superhydrophobic rubberwood shows much better anti-mold performance than that of rubberwood (Figure 9(a1–a8)) [21]. Compared with rubberwood, the attachment of molds onto superhydrophobic rubberwood is difficult (Figure 9(a5–a8)). Wang et al. obtained SHWSs by grafting poly(2-(perfluorooctyl)ethyl methacrylate) onto wood by atom transfer radical polymerization [119]. It can be found in Figure 9(b1–b6) that the color of the pristine wood changes after the cultivation of Aspergillus niger, and the hyphae gradually penetrates into wood [119]. As for SHWSs, no mold colony can be observed even after 15 days of cultivation (Figure 9(c1,c2)) [119]. Duan et al. prepared SHWSs by self-polymerization of dopamine, chemical deposition of Cu nanoparticles and hydrophobic modification of fluorosilane, and the SHWSs possessed excellent antibacterial performance for killing E. coli and S. aureus (Figure 9(d1–d6)) [19]. Gao et al. fabricated superhydrophobic Ag/TiO₂-coated wood by hydrothermal synthesis, silver mirror reaction and chemical modification [78]. They found that TiO₂-treated wood does not show any antibacterial activity, while Ag/TiO₂-coated wood can kill all the bacteria under and around them [78].

The reason why SHWSs can effectively prevent fungi and bacteria is that SHWSs possess very low adhesion for both fungi and bacteria, and also show excellent water repellency to stop water moisture. These two advantages inhibit the living environments of fungi and bacteria, and thus can prevent the growing of fungi and bacteria for a long time. In other words, the anti-fungi and anti-bacteria properties of SHWSs can be maintained as long as the surface superhydrophobicity of SHWSs exists. As time elapses, however, the surface superhydrophobicity of SHWSs cannot be guaranteed under extremely humid environments towards various fungi and bacteria. A realistic roadmap towards protecting wood materials is to introduce SHWSs as well as the regular maintenance of SHWSs. In a word, self-cleaning and anti-fouling properties of wood surfaces can prevent wood materials from being molded, which will extend their real outdoor practical applications.

3.2. Oil/Water Separation

Oceanic oil spills and the discharge of oily wastewaters have caused significant threats to the ecological environment and human health [32,198,199]. To mitigate this issue, traditional methods have been utilized to remove toxic chemicals in oily wastewaters, including in situ burning, air flotation, centrifugation, chemical dispersion, and bioremediation [24,32]. These methods, however, suffer from complex operations, high cost, low separation efficiency, and secondary pollution [198,199]. Thus, adsorption and separation materials draw much attention for dealing with oily wastewaters. Recently, many materials have be used in the field of oil/water separation, such as papers [24], polymers (i.e., polyester fabrics) [200], metal meshes [201], cottons [202] and wood [203]. Among them, the sustainable superhydrophobic wood material with porous structures is an excellent candidate for oil/water separation or oil recovery (See Table 2) [203].

Latthe et al. utilized low-cost sawdust and polystyrene to prepare superhydrophobic pellets that possess micro-voids less than 100 μm [25]. These superhydrophobic pellets show excellent oil/water separation efficiency higher than 90% as well as separation cycles around 30 for oils and organic solvents (Figure 10(a1–a4)) [25]. Chen et al. obtained a superhydrophobic delignified wood material by coating TiO₂ and PDMS, and this superhydrophobic wood can easily absorb underwater oils (Figure 10b) [162]. This superhydrophobic wood shows a high permeation flux of up to 6111 L m⁻² h⁻¹ and a separation efficiency of up to 93.4% [162]. Wang et al. prepared superhydrophobic wood aerogel/PDMS composite by partially removing hemicellulose and lignin and treating with PDMS [135]. This prepared wood aerogel/PDMS membrane material can efficiently separate oil/water mixtures with high separation efficiency (99.5%) and flux (around 2.25 × 104 L m⁻² h⁻¹) by only using the driving force of gravity (Figure 10(c1,c2)) [135]. Ma et al. achieved a bio-based fireproof and superhydrophobic wood template for oil/water separation via a layer-by-layer assembly technique, and this superhydrophobic wood showed excellent oil/water properties (>97%), self-cleaning capability, and mechanical durability (Figure 10(f1–f4,g1–g6)) [179]. Although the oil/water separation performance of SHWSs is not as good as that of sponges [199], SHWSs are still good candidates because of their high efficiency and recyclability (Table 2).

As for SHWSs, natural porous structures are not enough for high oil adsorption capacity, while superhydrophobic wood aerogels with delignified structures may be promising for oil/water separation. Actually, the challenges for oil/water separation are mainly the separation of viscous oils and oil/water emulsions. One approach for designing SHWSs with excellent oil/water separation properties is to decorate delignified wood surfaces with various desired nanoparticles and thus achieve suitable hierarchical surface roughness. Another approach is to introduce the photo-thermal effect to enhance the oil/water separation by decorating with light-absorbing nanoparticles, which facilitates to decrease the viscosity of oil/water mixtures (or emulsions) and thereby improve the separation efficiency.

3.3. Fire Resistance

Although wood materials have many advantages (i.e., high strength, easy machinability, aesthetic characteristics) for indoor and outdoor construction and decorations, the combustion of wood materials is an unavoidable problem for the safe utilization of wood materials [5,17,133,179]. With wood materials have combustion characteristics, a possible solution is to endow wood materials with fire resistance. One traditional method is to treat wood materials with fire retardants; however, these fire retardants are harmful to the environments. With the assistance of adhesives, durable flame retardant coatings have been utilized for improving the fire resistance of wood materials [206]. Among various retardant coatings, superhydrophobic coatings consisting of metal or inorganic oxides (i.e., ZnO [5], Mg-Al-layered double-hydroxide [17] and SiO₂ [133,179]) have been successfully introduced onto wood surfaces, showing excellent fire-resistance properties. The fire-resistance property of SHWSs is possibly due to the combination of the fire resistance of metal oxides (or inorganic oxides) and the superhydrophobic coatings of wood materials acting as a protective layer.

Kong et al. deposited highly dense and uniform ZnO arrays on the wood surface and achieved a superhydrophobic wood surface with a water contact angle of ~154° [5]. They carried out flame retardancy tests for pristine wood (Figure 11(a1)) and ZnO-nanorod-coated wood (Figure 11(a2,a3)), and the experimental results showed that ZnO nanorod arrays can be used as a thermal protective layer for fire resistance [5]. Jia et al. prepared superhydrophobic wood surfaces by immersing wood surfaces into a sealed vessel with a mixture of massive epoxy and SiO₂ nanoparticles [133]. This superhydrophobic wood took 50 s for the surface to be entirely covered by flame, and 2.5 times longer than the untreated wood surface (Figure 11(b1,b2)) [133]. Ma et al. verified flame retardancy by using UL-94 tests, and found that superhydrophobic wood surfaces can easily pass the UL-94 test (Figure 11c) [179]. Guo et al. studied the combustion properties of superhydrophobic Mg-Al LDH-coated wood by using LOI and CONE calorimetry testing, and found that the LOI value can increase from 18.9% ± 1.3% to 39.1% ± 2.7% compared with the untreated wood [17]. Based on the above examples, SHWSs can be considered as good candidates for the application of fire resistance.

To achieve the property of fire resistance, the design of wood materials may focus on properties of inorganic coatings when preparing SHWSs, considering the thickness of coatings, thermal stability, flammability and smoke production. To be realistic, SHWSs can prevent combustion for a certain time, while they cannot constantly stop the flame for a long time as time elapses and flame temperature increases. All in all, superhydrophobic coatings on wood materials can be used as retardant coatings, and the fire resistance property of SHWSs is enough for wood materials as applied in some indoor or outdoor practical applications.

3.4. Anti-UV Irradiation

When wood materials are exposed to external environments, anti-UV irradiation should be considered such that the longevity of wood surfaces can be estimated. Generally, anti-UV irradiation properties are investigated by monitoring the color changes of pristine wood and SHWSs over a period of time [152]. For example, Jnido et al. found that the color change in uncoated wood is clearly recognizable, while the color change in the polyester/TiO₂-coated wood is not immediately visible [152]. Li et al. showed that the color of the pristine wood became noticeably darker and yellow after 18 days of UV irradiation, while no visible color change on superhydrophobic wood surfaces was found [152]. By introducing nanomaterials (i.e., TiO₂ [107,152,176], ZnO [165] and CoFe₂O₄ [156]) with anti-UV properties, wood materials can be endowed with anti-UV properties and, thus, the utilization of wood materials can be enhanced in outdoor fields.

The color changes before and after UV irradiation are measured in accelerated aging tests to evaluate the anti-UV property of the pristine wood and SHWSs [156]. Usually, the change tendency of the chromaticity parameters (Δa* (a tendency to turn reddish), Δb* (a tendency to turn yellowish)), the lightness (ΔL*) and the overall color change (ΔE*) of the pristine wood and SHWSs is characterized. For example, Gan et al. found that the value of Δa* for the pristine wood and SHWSs is similar, while the value of Δa* for SHWSs is only 1/10 that of the untreated wood as shown in Figure 12(a1–a4) [156]. Wang et al. found that the nano-TiO₂ treatment significantly improves the photostability of wood surfaces [176]. Yao et al. also found that the superhydrophobic ZNA-treated wood shows superior UV resistance compared to that of the pristine wood Figure 12(b1–b4) [165]. In addition to this, the color fastness and color stability of wood materials can be also investigated by the characterization of their anti-UV properties. For example, Wang et al. studied color fastness enhancement of dyed wood with a Si-sol@PDMS-based superhydrophobic coating [95]. Tuong et al. prepared superhydrophobic epoxy@ZnO coated wood, and found that the color stability can be improved by around 50% compared with that of the uncoated wood [74]. Thus, the superhydrophobic coatings are suitable to be utilized for the protection of wood materials for UV resistance.

In short, as for outdoor applications of wood materials, the anti-UV property is one of most important factors that determine the application of wood materials. Solar irradiation (i.e., UV irradiation) can be easily absorbed by the component lignin in wood materials, thereby gradually degrading wood materials as time elapses. To enhance anti-UV properties, delignified wood materials may be a good choice when used as wood substrates when preparing SHWSs. Overall, the introduction of superhydrophobic coatings with anti-UV properties is also a realistic approach towards protecting wood materials in outdoor environments.

3.5. EMI Shielding

As the use of portable electronic devices increases, massive electromagnetic wave pollutions significantly influence living environments, which has a detrimental impact on human health [207]. To mitigate this issue, EMI shielding and electromagnetic (EM) wave absorption materials have been developed such that public health can be protected. When preparing SHWSs, superhydrophobic coatings are suitable for use as a protective layer against EMI interference.

Metal (or oxides) (i.e., copper [48], MnFe₂O₄ [79] and CoFe₂O₄ [22])-based superhydrophobic coatings have been decorated onto wood materials. Xing et al. tested electromagnetic radiation intensity of three types of wood by using a cell phone (Figure 13(a1)) [48]. They found that the electromagnetic intensity of ordinary wood, coppered wood and superhydrophobic coppered wood is 1.686 μT, 0.446 μT and 0.358 μT (Figure 13(a2)), respectively [48]. Wang et al. showed that the absorption bandwidth of the FMW can be significantly improved compared with the wood (Figure 13(b1,b2)) [79]. Gan et al. found that the reflection loss of the coated wood composites is much lower than that of the pristine wood [22]. Thus, the EMI interference and/or EM wave absorption can be realized on wood materials.

Now that the widespread use of portable electronic vehicles and devices are unavoidable in modern life, the mitigation of EM wave pollutions has become a huge and realistic challenge. As for indoor and outdoor construction and decorations, the introduction of SHWSs can be considered such that wood materials can simultaneously possess many excellent performances (i.e., self-cleaning and water repellency) as well as the abilities of EMI shielding and EM wave absorption.

3.6. Photocatalytic Performance

Self-cleaning is an excellent property of SHSs, which facilitates automatically removing contaminants (i.e., dust, powder, wastewater and organic contaminants). Inorganic contaminants can be easily removed by SHSs, while organic contaminants may stay on SHSs and thus gradually destroy the superhydrophobicity of SHSs as time elapses. If SHSs possess the self-cleaning property as well as photocatalytic performance, the self-cleaning property of SHSs can be definitely enhanced in various different environments.

Recently, SHWSs have been developed to have a good photocatalytic functionality in the degradation of organic contaminants. For example, Wang et al. prepared thermally induced responsive superhydrophobic wood, and studied the performance of the TRS-wood on the degradation of oleic acid (Figure 14(a1–a4)) [208]. They found that the TRS-wood shows a degradation efficiency of above 90% (Figure 14(a3)) [208]. Gao et al. obtained superhydrophobic Ag/TiO₂-coated wood, and investigated the photodegradation of phenol [78]. Jia et al. tested the degradation efficiencies of three catalytic samples (i.e., the untreated wood, Bi-wood, and Bi&F-wood), and the photocatalytic degradation efficiency was almost 100% for the Bi&F-wood after 80 min UV irradiation (Figure 14(b1–b6)) [139]. Xia et al. prepared superhydrophobic STA@PF@Cu₂O-coated balsa, and found that the concentrations of methylene blue declined substantially to 99.8% when exposed to visible light after 320 min [55]. Chen et al. prepared superhydrophobic PDMS@TiO₂ wood for photocatalytic degradation [162]. They found that the TiO₂ loading and the surface area of the samples are both important factors affecting the photocatalytic degradation efficiency [162]. When testing the photocatalytic degradation efficiency, they used crushed PDMS@TiO₂ wood to increase surface contact area and thus improve the photocatalytic degradation efficiency between the TiO₂ coating and UV light [162]. Based on above discussions, SHWSs can be endowed the photocatalytic performance, and thus the applications of SHWSs can be extended.

Of course, compared with many nanomaterials (i.e., Pd and Pt), the photocatalytic property of SHWSs is not good enough. This is because the photocatalytic property of SHWSs is not the main property of wood materials, which is an additional functionality that enhances the self-cleaning property. For example, wood-material-based house roofs can be functionalized with the photocatalytic property such that birds’ droppings can be gradually degraded under solar irradiation.

3.7. Anti-Icing

Anti-icing surfaces can be defined as follows: (1) repelling cooled water droplets, (2) suppressing ice nucleation, and (3) lowering ice adhesion strength [209,210,211], which are suitable for SHSs as well as SHWSs. Wood materials have some differences with other materials (i.e., ceramics, metals and polymers) when discussing the anti-icing property due to their water adsorption capability. As for SHWSs, the anti-icing property can be maintained as long as the surface superhydrophobicity exists.

In cold outdoor environments, the anti-icing property of wood surfaces is very important for the utilization of wood construction [212]. This is because the mechanical property of wood materials may decrease when water-adsorbing wood materials experience freeze–thaw cycles. Thus, SHWSs are necessary to be used in wood construction to prevent wood materials from being absorbed by moisture (or water vapor). For example, Cao et al. found that the SiO₂/PMHOS-modified wood samples have good anti-icing properties (Figure 15a) [177]. Zhao et al. found that the hydrophobic DH-wood sample only showed a 13% ± 2% thickness expansion (Figure 15(b1,b2)) [134]. Traditionally, water-proof paints are used for wood construction, which are good enough for regular construction. In highly humid environments, SHWSs are recommended to be introduce onto wood constructions such that the life span of wood materials can be extended, and thus the safety of wood constructions be improved in cold and humid environments.

3.8. Other Applications

Except for the above applications, SHWSs can also be utilized in many other fields, such as thermal energy storage [67,147], light-driven devices [151], photoluminescence [1,137], piezoresistive pressure sensors [49], moisture harvesting [61] and wood preservation [115], because of their excellent physiochemical properties.

When SHWSs are functionalized with light-responsive (or light-absorbing) layers, they can be utilized in photo-responsive fields. Kong et al. fabricated a polydivinylbenzene (PDVB)-nanotubes-based superhydrophobic thermal-energy-storage coating on wood substrate, and found that this coating shows a great loading capacity for IPW (78.29 wt.%) (Figure 16(a1–a3)) [67]. Yang et al. prepared a superhydrophobic TD/DW composite, and found that the calculated energy storage efficiency of the superhydrophobic TD/DW composite can reach 449.84% (Figure 16(b1–b3)) [147]. Chen et al. prepared superhydrophobic CNT/Fe₃O₄/MTMS wood and investigated light-driven linear motion by using NIR light (808 nm) and sunlight (Figure 16(c1,c2)) [151]. In addition to this, SHWSs can be endowed with the property of photoluminescence. For example, EI-Naggar et al. prepared a superhydrophobic nanocomposite coating on wood substrates by introducing lanthanide-doped aluminum strontium oxide nanoparticle-immobilized polystyrene [137]. Sun et al. prepared superhydrophobic wood by using WO₃ nanostructures via a two-step hydrothermal process [1]. Therefore, superhydrophobic coatings on wood substrates can enable wood materials as good candidates for the utilization of low-cost photo-responsive materials.

Furthermore, SHWSs have also been developed for functional devices and protective applications. For example, Li et al. studied sandwich-structured photothermal wood for durable moisture harvesting and pumping (Figure 16(d1–d3)) [61]. Huang et al. investigated superhydrophobic and high-performance wood-based piezoresistive pressure sensors for detecting human motions [49]. David et al. studied superhydrophobic coatings based on cellulose acetate for pinewood preservation [115]. Although wood materials have been applied for the above utilizations, their performances are not as good as other specially designed substrates (i.e., ceramics, metals and polymers). In a word, low-cost wood materials become promising in various fields as long as they are functionalized with surface superhydrophobicity.

4. Conclusions

In this paper, we summarize recent progress in the preparation methods and the versatile practical applications of SHWSs. The preparation of SHWSs can be achieved by using various methods, including immersion, spray-coating, hydrothermal synthesis, dip-coating, deposition, sol-gel process and other methods. Each method has its own characteristics and reaction conditions. Similarly to the preparation of SHSs, the preparation of SHWSs also pursues facile, low-cost, controllable, scalable, efficient and environmentally friendly approaches. Based on the properties of wood substrates, the following issues may be considered during the preparation and practical applications of SHWSs.

(1). Multiple above preparation strategies are recommended to be combined to prepare SHWSs. The selection of preparation methods is mainly based on the experimental conditions and real practical applications. Actually, each preparation strategy usually has its own advantages and disadvantages, and sometimes an individual method is not enough to achieve SHSs on wood substrates.
(2). The decoration of nanomaterials on wood substrates for preparing SHWSs needs to consider real practical applications. The SHWSs can be endowed with many properties, such as anti-aging, thermal stability, anti-fungi/anti-bacteria, fire resistance and electromagnetic interference (EMI) shielding. However, when used in different environmental conditions, one particular property as well as surface superhydrophobicity is mainly concerned. Thus, the selection of suitable functional nanomaterials for the preparation of SHWSs is crucial to meet the needs of special indoor and outdoor applications.
(3). The longevity of SHWSs usually determines real practical applications in the long term. The surface chemistry sustainability and the mechanical durability of SHWSs are two critical factors, which are also the challenges of SHSs. For example, an adhesive layer can be introduced to enhance the mechanical durability of SHWSs.

5. Challenges and Perspectives

As the global climate changes, people worry more about environmental problems and sustainable developments. For example, the term ‘carbon neutralization’ has drawn much attention from many fields all over the world, including research, industry and even daily life. Thus, the investigation of wood material becomes a hot issue, as wood material is a sustainable and abundant biomaterial in nature. The challenges of SHWSs are usually the challenges of SHSs, including the durability, the sustainability of low-surface-energy layers, anti-corrosion, anti-icing, anti-UV, transparency, etc. Furthermore, SHWSs also have other challenges because of the physiochemical properties of wood materials. For instance, wood materials are susceptible to fire, and thus SHWSs cannot suffer from being combusted under a high temperature for a long time. In addition, wood materials are the food of some insects and living microorganisms, which determines that wood materials may be destroyed as long as the surface superhydrophobicity of SHWSs is lost.

In the future, sustainable and abundant wood materials are promising resources for the versatile practical applications though some challenges of the utilization of wood materials still exist. When used in the fields of anti-fungi and anti-bacteria, suitable methods for preparing SHWSs should be chosen such that the surfaces (i.e., edge defects) of wood materials are all functionalized by introducing a superhydrophobic coating with proper thickness. As for oil/water separation, the pre-treatment (i.e., delignified, the preparation of wood aerogel) is necessary, which mainly increases the porous structures. After that, the resulting superhydrophobic wood substrates can possess better oil/water separation performance. Of course, the photothermal effect can also be introduced by depositing light-absorbing nanoparticles during the preparation of SHWSs. This is because the viscosity of oil/water mixtures (or emulsions) can be reduced and thus improve the separation efficiency. As for fire resistance, SHWSs cannot completely avoid fire combustion, but they can extend the time for wood materials under fire. One possible solution to enhance the fire resistance of wood materials is that flame resistant nanomaterials (metal or inorganic oxides) can be impregnated both in the inner structures as well as on the surfaces of wood materials. When used in the anti-UV field, the design of SHWSs need to consider the role of lignin that can absorb solar light. Probably, the delignified wood substrates have the promising anti-UV property after functionalizing with surface superhydrophobicity. Similarly, when wood materials are used in many other fields (i.e., EMI shielding, photocatalytic performance, anti-icing, thermal energy storage, moisture harvesting and photo-responsive devices), the SHWSs can be rationally designed based on the characteristics of practical applications, and the preparation process needs to be selected to simultaneously avoid possible drawbacks of wood materials. In summary, SHWSs functionalized from wood materials have great potential in versatile practical applications, and how to make full use of wood materials will become a hot topic in our daily life and industry.

Author Contributions

Conceptualization, Z.H.; investigation, X.G., M.W. and Z.H.; writing—original draft preparation, X.G., M.W. and Z.H.; writing—review and editing, Z.H.; supervision, Z.H.; project administration, Z.H.; funding acquisition, Z.H. All authors have read and agreed to the published version of the manuscript.

Acknowledgments

The Fundamental Research Funds for the Provincial Universities of Zhejiang (GK220701218030), the National Natural Science Foundation of China (Grant No. 51803043) and the Science Foundation of Hangzhou Dianzi University (KYS205620119) are acknowledged for the financial support.

Conflicts of Interest

The authors declare no conflict of interest.

Footnotes

Disclaimer/Publisher’s Note: The statements, opinions and data contained in all publications are solely those of the individual author(s) and contributor(s) and not of MDPI and/or the editor(s). MDPI and/or the editor(s) disclaim responsibility for any injury to people or property resulting from any ideas, methods, instructions or products referred to in the content.

Figures and Tables

Table 1

Summary of preparation methods for SHWSs.

Methods	Types of Wood	Decorated Materials	Modifying Materials	Experimental Conditions	WCA (°)	Ref.
Immersion	Basswood	-	HDTMS, MTMS	Immersed for 6 h, dried at 120 °C for 30 min	162.9 ± 2	[11]
	Poplar wood	Cu	FAS-17	Pretreated by DA, Immersed at 30 °C for 2 h	155.7	[19]
	Basswood	Aluminate	-	Immersed at 70 °C, dried for one week at room temperature	163.6	[47]
	Pine lumber	Cu	FAS	Immersed in NaOH at 70 °C for 10 min	160	[48]
	Balsa wood	rGO	PDMS	Immersed in GO solution, then reduced to rGO@wood	152	[49]
	Ash wood	-	APTES	Immersed at 60 °C for 5 h	161	[50]
	Poplar wood	-	PMS	Immersed at room temperature (RT) for 18 h	153	[51]
	Wood blocks	SiO₂	PDMS, PMHS	Immersed for 10 min, dried at 100 °C	164.4	[52]
	Dalbergia sissoo wood	TiO₂	PFOTS	Immersed in a mixture solution for 15 s	165 ± 8	[53]
	Pinus sylvestris wood	SiO₂	OTS	Pretreated with EP, immersed for 10 min	155.4	[54]
	Balsa wood	Cu₂O	STA	Immsersed at RT for 1 h	153	[55]
	Pinus sylvestris var. mongolica	Al₂O₃	OTS	Pretreated with DA, immersed for 20 h	152.9	[56]
	Poplar wood	SiO₂	PCL_10,000	Immersed for 24 h	156 ± 1	[57]
	Wood substrate	SiO₂	F13-TMS	Immersed for 1.5 h	156	[58]
	Wood substrate	SiO₂, TiO₂	VTES	Immersed at 100 °C for 1.5 h	153.2 ± 2.3	[59]
Spray-coating	Pine wood	SiO₂	Zonyl 8740	Oven-dried at 105 °C for 12 h	168.3	[14]
	Birch wood	SiO₂	PDMS	0.3 MPa at a distance of 10 cm	170	[60]
	Balsa wood	Soot	PDMS	Sprayed for 3 s	160	[61]
	European beech wood	AKD wax		Oven-dried at 45 °C for 10 min	160	[62]
	Beech wood	CNC@SiO₂@PL rod	PDMS	Dried at 150 °C for 2 h	157.4	[63]
	Wood substrate	CNC	FOTS	Dried at RT for 15 min	163	[64]
	Wood substrate	SiO₂	HDTMS	Sprayed for 2 s under pressure of 42 psi	151.8	[65]
	Wood substrate	SiO₂	N-Boroxine-PDMS	0.24 MPa at a distance of 12 cm	160.9	[66]
	Wood substrate	PDVB NTs, SiO₂	PFS	0.3–0.4 MPa at a distance of 10–15 cm	157.7	[67]
	European beech wood	AKD wax		Using a 0.15 mm nozzle	166	[68]
	Masson’s pine, pecan wood	Cu₂O	STA	Sprayed at a 30° angle and a distance of 60 cm	155	[69]
	Wood blocks	TiO₂	PMC	Sprayed for 10 s, cured at 103 °C for 8 h	152.2 ± 2.6	[70]
	Balsa wood	SiO₂	POTS	Sprayed for 6 s	151.2	[71]
	Wood substrate	CNC/SiO₂	PFTS	Pretreated with adhesive, dried at RT	>159	[72]
	Chinese fir wood	PS/SiO₂	PDMS	Sprayed for 10 s, baked at 100 °C for 2 h	150	[73]
	Styrax tonkinensis wood	ZnO	STA	0.2 MPa at a distance of 10 cm	154.1	[74]
	Wood substrate	SiO₂	DTMS	Sprayed at a distance of 20–25 cm	162.3 ± 1.1	[75]
	Wood substrate	NCF	PFOCTS	0.2–0.4 MPa at a distance of 45–60 cm	161	[76]
	Pine wood	CNC	FOTS	0.2–0.4 MPa at a distance of 30–60 cm	162	[77]
Hydrothermal synthesis	Polar wood	WO₃	SDS	120 °C for 6 h	152	[1]
	Wood blocks	ZnO	STA	90 °C for 6 h	154	[5]
	Spruce wood	TiO₂	SDS	75 or 90 °C for 1 h	>150	[7]
	Eucalyptus wood	TiO₂	VTES	100 °C for 6 h	153	[20]
	Poplar wood	Ag-TiO₂	FAS-17	90 °C for 5 h	153.2	[78]
	Wood slices	MnFe₂O₄	FAS-17	120 °C for 8 h	156 ± 1	[79]
	Sapwood	ZnO	Palmitoyl chloride	90 °C for 3 h	155	[80]
	Wood substrate	ZnO	DTMS	90 °C for 3 h	156	[81]
	Polar wood	TiO₂	SDS	Reheated at 70 °C for 4 h	154	[82]
	Poplar wood	TiO₂	OTS	90 °C for 5 h	152	[83]
	Poplar wood	TiO₂	Fluoroalkyl silane	90 °C for 5 h	152.9	[84]
	Birch veneer	WO₃	OTS	90 °C for 12 h	152	[85]
	Birch veneer	WO₃	OTS	110 °C for 24 h	150.1	[86]
	Pinus wood	Cu₂(OH)₃Cl NPs	STA	70 °C for 10 min	151 ± 3	[87]
	Poplar lumbers	α-FeOOH	OTS	80 °C for 0.5, 1, 2, 4 h	158	[88]
	Poplar sapwood	Cu₂O	FAS-17	180 °C for 2 h	153.8	[89]
	Poplar wood	Ti/Si	VTES	100 °C for 6 h	152.7	[90]
Dip-coating	Spruce veneers	SiO₂	POTS	Dip-coated in sol, stirred for another 5 h	151.8	[3]
	Juvenile teakwood	AKD	-	Heating to form β-ketoester bond	150 ± 2	[9]
	Chinese Cunninghamia lanceolata	SiO₂	PMHS	Dipped for 5 min, air-dried for 1 min	154.1 ± 2.1	[12]
	Cathay poplar wood	CoFe₂O₄	FAS	Dipped for 3 min, air-dried for 20 min	158	[22]
	Chinese fir wood	SiO₂	PDMS	Dipped for 10 min, dried at 103 °C for 1 h	152	[91]
	Wood substrate	Al₂O₃	PDMS	Dipped for 30 s, dried at 50 °C for 20 min	154	[92]
	Poplar wood	CeO₂	OTS	Dipped for 20 min, dried at 80 °C for 1 h	152	[93]
	Chinese white pine	SiO₂	PDMS, FAS	Dipped for 5 min, dried at 103 °C for 15 min	>150	[94]
	Poplar sapwood	Si-sol	PDMS	Evacuated to −0.09 MPa, dried at 103 °C for 3 h	151.6	[95]
Deposition	Poplar wood	-	PDMS	CVD, hydrolysis reaction	157.3	[96]
	Balsa wood	-	MTMS	Vapor deposition	151.8	[97]
	Birch veneers	Silicone nanofilaments	TCOS	CVD for 3 h	156	[98]
	Golden chinkapin wood	-	PFE	Plasma deposition at a working pressure of 1.0 Torr	161.2 ± 1.5	[99]
	Wood substrate	Candle soot	Paraffin wax	Evaporation and deposition	162	[100]
	Chinese Cunninghamia lanceolata	SiO₂	PMHS	Deposition of 75 nm SiO₂ NPs	158.2	[101]
	Larch species wood	ZnO	Octadecanoic acid	Maintained at 70 °C for 5 h	156	[102]
	Radiata pine	Cu	Perfluorocarboxylic acid	Magnetron sputtering	154	[103]
Sol-gel	Walnut wood	-	PDMS	Immersed for 12 h	162.4	[104]
	Chinese fir wood	Silica	HDTMS	Dipped for 30 min to deposit silica	152	[105]
	Poplar lumbers	SiO₂	POTS	Maintained at RT for 6 h	164	[106]
	Poplar sapwood	TiO₂	PDMS	In-situ deposition, EB radiation curing	165.7	[107]
	Pine blocks	Silica	Aerosil R-972	Placed for 10 min, dried in air for 24 h	152	[108]
	Chinese fir wood	Silica	HDTMS	Immersed for 30 min, dried at 80 °C for 10 h	150	[109]
	Eucalyptus wood	SiO₂	PFDS	Stirred at 50 °C for 4 h, dried at 70 °C for 10 h	159	[110]
Assembly	Norway spruce	ZnO	Carnauba wax	Layer-by-layer	155	[15]
	Southern pine sapwood	ZnO	STA	Self-assembly	>150	[111]
	Poplar wood	TA–Fe^III	Octadecanethiol	Multistep assembly	156	[112]
	Populus ussuriensis Kom.	SiO₂	POTS	Layer-by-layer	161	[113]
	Poplar wood	TiO₂	POTS	Layer-by-layer	161	[114]
Brushing	European beech	-	GSE	Dried for 5 min, repeated 5 times	159 ± 2	[16]
	Pinewood	ZnO, TiO₂	Acetic acid	Brushed for 3 layers, dried at 100 °C for 24 h	>150	[115]
	Chinese fir wood	SiO₂, TiO₂	PTES	Curd at RT	152	[116]
Drop-coating	Poplar lumbers	PS/silica	OTS	1 mL cm², dried at RT	153 ± 1	[117]
	Wooden sheet	TiO₂	H-PDMS	Kept at RT for 30 min, cured at 120 °C for 10 h	155.5 ± 1	[118]
	Poplar lumbers	SiO₂	OTS	Oven-dried at RT for 12 h	159	[117]
Grafting	Chinese fir wood	-	PFOEMA	ATRP	156	[119]
Grafting	Radiata pine	-	Stearoyl chloride	The ester linkage	152	[120]
Casting	Chinese fir wood	Polymer latex	-	Drop-casting, dried at 30 °C	152	[121]
Casting	Chinese fir wood	Nano fumed silica	Acetic acid	Heating at 120 °C for 2 h	160	[122]
Impregnation	Pine wood	Cu(OH)₂	Dodecanethiol	Dried in an oven	154	[123]
	Poplar specimens	TiO₂	Maleic rosin	Dried in an oven at 180 °C for 4 h	157	[124]
	Poplar sapwood	Silica	Silicone oil	At a vacuum of 0.01 MPa for 1 h, a subsequent pressure of 0.5 MPa for 1 h	154.8	[125]
	Pinewood	Copolymers	-	Impregnated for 2 h, heated at 140 °C for 2 h	>150	[126]
	Masson’s pine wood	Cu₂(OH)₃Cl	PF and STA	Impregnated at RT for 4 h, immersed at RT for 2 h	163	[127]
Solvent-based methods	Balsa wood	PVDB	-	A solvothermal method, heated at 100 °C for 24 h	160	[128]
Solvent-based methods	Chinese fir wood	SiO₂	VTES	Alkali-driven method	156.6	[129]
Template methods	Populus ussuriensis Kom.	Fe₃O₄	PDMS	Soft lithography	152 ± 2	[130]
	Populus ussuriensis Kom.	PVB/SiO₂	OTS	Nanoimprint lithography	160	[131]
	Ash wood	PVB/SiO₂	OTS	Replication	155	[132]

Table 2

Oil/water separation of SHWSs.

Modifying Materials	Adsorbed Materials	Adsorption Capacity (g∙g⁻¹)	Separation Efficiency (%)	Permeation Flux (L∙m⁻²∙h⁻¹)	Cycles (Times)	Ref.
Acetic acid/NaClO₂	Toluene	14.25	94	32.8	100	[2]
Polystyrene	Hexane	-	>98	-	36	[25]
PDMS	Trichloromethane	20	99.5	2.25 × 10⁴	10	[135]
TEOS/PDMS	Dichloromethane	-	98.5	1.3 × 10³	3	[104]
NaClO₂	Dichloromethane	37	88.6	-	10	[138]
STA/PF/Cu₂O	Dichloromethane	3.2	94	-	30	[55]
POTS/SiO₂	Emulsions	-	>99	710	10	[71]
PDMS/TiO₂	Silicone oil	2.7	93.4	6111	20	[162]
ZnO/octadecanoic acid	Engine oil	20.81	>98	-	10	[102]
APTES/SiO₂	Chloroform	-	97.5	-	-	[179]
PDVB	Toluene emulsions	-	99.98	8829.4	20	[128]
MTMS	Olive oil	23.1	-	-	10	[188]
Cu(OH)₂	Emulsions	-	>98	11	6	[123]
PSP	Emulsions	-	>99	4392	12	[204]
Na₃(Cu₂(CO₃)₃OH)∙4H₂O	Dichloromethane	5	90	-	11	[205]

References

1. Sun, M.; Song, K. Low temperature hydrothermal fabrication of tungsten trioxide on the surface of wood with photochromic and superhydrophobic properties. BioResources; 2018; 13, pp. 1075-1087. [DOI: https://dx.doi.org/10.15376/biores.13.1.1075-1087]

2. Gao, R.; Huang, Y.; Gan, W.; Xiao, S.; Gao, Y.; Fang, B.; Zhang, X.; Lyu, B.; Huang, R.; Li, J. et al. Superhydrophobic elastomer with leaf-spring microstructure made from natural wood without any modification chemicals. Chem. Eng. J.; 2022; 442, 136338. [DOI: https://dx.doi.org/10.1016/j.cej.2022.136338]

3. Wang, Y.; Yan, W.; Frey, M.; Vidiella del Blanco, M.; Schubert, M.; Adobes-Vidal, M.; Cabane, E. Liquid-like SiO₂-g-PDMS coatings on wood surfaces with underwater durability, antifouling, antismudge, and self-healing properties. Adv. Sustain. Syst.; 2019; 3, 1800070. [DOI: https://dx.doi.org/10.1002/adsu.201800070]

4. Tuominen, M.; Teisala, H.; Haapanen, J.; Mäkelä, J.M.; Honkanen, M.; Vippola, M.; Bardage, S.; Wålinder, M.E.P.; Swerin, A. Superamphiphobic overhang structured coating on a biobased material. Appl. Surf. Sci.; 2016; 389, pp. 135-143. [DOI: https://dx.doi.org/10.1016/j.apsusc.2016.05.095]

5. Kong, L.; Tu, K.; Guan, H.; Wang, X. Growth of high-density ZnO nanorods on wood with enhanced photostability, flame retardancy and water repellency. Appl. Surf. Sci.; 2017; 407, pp. 479-484. [DOI: https://dx.doi.org/10.1016/j.apsusc.2017.02.252]

6. Jia, S.; Liu, M.; Wu, Y.; Luo, S.; Qing, Y.; Chen, H. Facile and scalable preparation of highly wear-resistance superhydrophobic surface on wood substrates using silica nanoparticles modified by VTES. Appl. Surf. Sci.; 2016; 386, pp. 115-124. [DOI: https://dx.doi.org/10.1016/j.apsusc.2016.06.004]

7. Pori, P.; Vilčnik, A.; Petrič, M.; Sever Škapin, A.; Mihelčič, M.; Šurca Vuk, A.; Novak, U.; Orel, B. Structural studies of TiO₂/wood coatings prepared by hydrothermal deposition of rutile particles from TiCl₄ aqueous solutions on spruce (Picea abies) wood. Appl. Surf. Sci.; 2016; 372, pp. 125-138. [DOI: https://dx.doi.org/10.1016/j.apsusc.2016.03.065]

8. Šprdlík, V.; Kotradyová, V.; Tiňo, R. Superhydrophobic coating of european oak (Quercus robur), european Larch (Larix decidua), and scots pine (Pinus sylvestris) wood surfaces. BioResources; 2017; 12, pp. 3289-3302. [DOI: https://dx.doi.org/10.15376/biores.12.2.3289-3302]

9. Kaewsaneha, C.; Roeurn, B.; Apiboon, C.; Opaprakasit, M.; Sreearunothai, P.; Opaprakasit, P. Preparation of water-based alkyl ketene dimer (AKD) nanoparticles and their use in superhydrophobic treatments of value-added teakwood products. ACS Omega; 2022; 7, pp. 27400-27409. [DOI: https://dx.doi.org/10.1021/acsomega.2c02420]

10. Lin, W.; Huang, Y.; Li, J.; Liu, Z.; Yang, W.; Li, R.; Chen, H.; Zhang, X. Preparation of highly hydrophobic and anti-fouling wood using poly(methylhydrogen)siloxane. Cellulose; 2018; 25, pp. 7341-7353. [DOI: https://dx.doi.org/10.1007/s10570-018-2074-y]

11. Ou, J.; Zhao, G.; Wang, F.; Li, W.; Lei, S.; Fang, X.; Siddiqui, A.R.; Xia, Y.; Amirfazli, A. Durable superhydrophobic wood via one-step immersion in composite silane solution. ACS Omega; 2021; 6, pp. 7266-7274. [DOI: https://dx.doi.org/10.1021/acsomega.0c04099] [PubMed: https://www.ncbi.nlm.nih.gov/pubmed/33778241]

12. Lin, W.; Cao, M.; Olonisakin, K.; Li, R.; Zhang, X.; Yang, W. Superhydrophobic materials with good oil/water separation and self-cleaning property. Cellulose; 2021; 28, pp. 10425-10439. [DOI: https://dx.doi.org/10.1007/s10570-021-04175-0]

13. Cao, H.; Guo, X.; Zhou, Y.; Yan, Y.; Sun, W. Fabrication of durable hydrophobic/superhydrophobic wood using an alkyl ketene dimer by a simple and feasible method. ACS Omega; 2022; 7, pp. 17921-17928. [DOI: https://dx.doi.org/10.1021/acsomega.2c01215] [PubMed: https://www.ncbi.nlm.nih.gov/pubmed/35664597]

14. Hsieh, C.-T.; Chang, B.-S.; Lin, J.-Y. Improvement of water and oil repellency on wood substrates by using fluorinated silica nanocoating. Appl. Surf. Sci.; 2011; 257, pp. 7997-8002. [DOI: https://dx.doi.org/10.1016/j.apsusc.2011.04.071]

15. Lozhechnikova, A.; Bellanger, H.; Michen, B.; Burgert, I.; Österberg, M. Surfactant-free carnauba wax dispersion and its use for layer-by-layer assembled protective surface coatings on wood. Appl. Surf. Sci.; 2017; 396, pp. 1273-1281. [DOI: https://dx.doi.org/10.1016/j.apsusc.2016.11.132]

16. Yao, Y.; Gellerich, A.; Zauner, M.; Wang, X.; Zhang, K. Differential anti-fungal effects from hydrophobic and superhydrophobic wood based on cellulose and glycerol stearoyl esters. Cellulose; 2018; 25, pp. 1329-1338. [DOI: https://dx.doi.org/10.1007/s10570-017-1626-x]

17. Guo, B.; Liu, Y.; Zhang, Q.; Wang, F.; Wang, Q.; Liu, Y.; Li, J.; Yu, H. Efficient flame-retardant and smoke-suppression properties of Mg–Al-layered double-hydroxide nanostructures on wood substrate. ACS Appl. Mater. Interfaces; 2017; 9, pp. 23039-23047. [DOI: https://dx.doi.org/10.1021/acsami.7b06803]

18. Yue, D.; Feng, Q.; Huang, X.; Zhang, X.; Chen, H. In situ fabrication of a superhydrophobic ORMOSIL coating on wood by an ammonia–HMDS vapor treatment. Coatings; 2019; 9, 556. [DOI: https://dx.doi.org/10.3390/coatings9090556]

19. Duan, X.; Liu, S.; Huang, E.; Shen, X.; Wang, Z.; Li, S.; Jin, C. Superhydrophobic and antibacterial wood enabled by polydopamine-assisted decoration of copper nanoparticles. Colloids Surf. A; 2020; 602, 125145. [DOI: https://dx.doi.org/10.1016/j.colsurfa.2020.125145]

20. Liu, M.; Qing, Y.; Wu, Y.; Liang, J.; Luo, S. Facile fabrication of superhydrophobic surfaces on wood substrates via a one-step hydrothermal process. Appl. Surf. Sci.; 2015; 330, pp. 332-338. [DOI: https://dx.doi.org/10.1016/j.apsusc.2015.01.024]

21. Lu, P.; Yun, H.; Zhang, W.; Tu, D.; Hu, C.; Cherdchim, B. A facile method of superhydrophobic coating on rubberwood to improve its anti-mildew performance. BioResources; 2019; 14, pp. 7111-7121. [DOI: https://dx.doi.org/10.15376/biores.14.3.7111-7121]

22. Gan, W.; Gao, L.; Zhang, W.; Li, J.; Zhan, X. Fabrication of microwave absorbing CoFe₂O₄ coatings with robust superhydrophobicity on natural wood surfaces. Ceram. Int.; 2016; 42, pp. 13199-13206. [DOI: https://dx.doi.org/10.1016/j.ceramint.2016.05.112]

23. Yang, H.; Wang, J.; Zhao, P.; Mu, H.; Qi, D. UV-assisted multiscale superhydrophobic wood resisting surface contamination and failure. ACS Omega; 2021; 6, pp. 26732-26740. [DOI: https://dx.doi.org/10.1021/acsomega.1c04207] [PubMed: https://www.ncbi.nlm.nih.gov/pubmed/34661027]

24. He, Z.; Wu, H.; Shi, Z.; Gao, X.; Sun, Y.; Liu, X. Mussel-inspired durable TiO₂/PDA-based superhydrophobic paper with excellent self-cleaning, high chemical stability, and efficient oil/water separation properties. Langmuir; 2022; 38, pp. 6086-6098. [DOI: https://dx.doi.org/10.1021/acs.langmuir.2c00429] [PubMed: https://www.ncbi.nlm.nih.gov/pubmed/35504860]

25. Latthe, S.S.; Kodag, V.S.; Sutar, R.S.; Bhosale, A.K.; Nagappan, S.; Ha, C.-S.; Sadasivuni, K.K.; Kulal, S.R.; Liu, S.; Xing, R. Sawdust-based superhydrophobic pellets for efficient oil-water separation. Mater. Chem. Phys.; 2020; 243, 122634. [DOI: https://dx.doi.org/10.1016/j.matchemphys.2020.122634]

26. He, Z.; Zhang, Z.; He, J. CuO/Cu based superhydrophobic and self-cleaning surfaces. Scripta Mater.; 2016; 118, pp. 60-64. [DOI: https://dx.doi.org/10.1016/j.scriptamat.2016.03.015]

27. Liu, X.; He, H.; Zhang, T.C.; Ouyang, L.; Zhang, Y.-X.; Yuan, S. Superhydrophobic and self-healing dual-function coatings based on mercaptabenzimidazole inhibitor-loaded magnesium silicate nanotubes for corrosion protection of AZ31B magnesium alloys. Chem. Eng. J.; 2021; 404, 127106. [DOI: https://dx.doi.org/10.1016/j.cej.2020.127106]

28. Tang, W.; Jian, Y.; Shao, M.; Cheng, Y.; Liu, J.; Liu, Y.; Hess, D.W.; Wan, H.; Xie, L. A novel two-step strategy to construct multifunctional superhydrophobic wood by liquid-vapor phase deposition of methyltrimethoxysilane for improving moisture resistance, anti-corrosion and mechanical strength. Colloids Surf. A; 2023; 666, 131314. [DOI: https://dx.doi.org/10.1016/j.colsurfa.2023.131314]

29. Gao, S.; Huang, J.; Li, S.; Liu, H.; Li, F.; Li, Y.; Chen, G.; Lai, Y. Facile construction of robust fluorine-free superhydrophobic TiO₂@fabrics with excellent anti-fouling, water-oil separation and UV-protective properties. Mater. Des.; 2017; 128, pp. 1-8. [DOI: https://dx.doi.org/10.1016/j.matdes.2017.04.091]

30. He, Z.; Xie, H.; Jamil, M.I.; Li, T.; Zhang, Q. Electro-/photo-thermal promoted anti-icing materials: A new strategy combined with passive anti-icing and active de-icing. Adv. Mater. Interfaces; 2022; 9, 2200275. [DOI: https://dx.doi.org/10.1002/admi.202200275]

31. He, Z.; Jamil, M.I.; Li, T.; Zhang, Q. Enhanced surface icephobicity on an elastic substrate. Langmuir; 2022; 38, pp. 18-35. [DOI: https://dx.doi.org/10.1021/acs.langmuir.1c02168] [PubMed: https://www.ncbi.nlm.nih.gov/pubmed/34919404]

32. He, Q.; Guo, Z.; Ma, S.; He, Z. Recent advances in superhydrophobic papers for oil/water separation: A mini-review. ACS Omega; 2022; 7, pp. 43330-43336. [DOI: https://dx.doi.org/10.1021/acsomega.2c05886] [PubMed: https://www.ncbi.nlm.nih.gov/pubmed/36506134]

33. He, Z.; He, J.; Zhang, Z. Selective growth of metallic nanostructures on microstructured copper substrate in solution. CrystEngComm; 2015; 17, pp. 7262-7269. [DOI: https://dx.doi.org/10.1039/C5CE01093D]

34. Zeng, Q.; Zhou, H.; Huang, J.; Guo, Z. Review on the recent development of durable superhydrophobic materials for practical applications. Nanoscale; 2021; 13, pp. 11734-11764. [DOI: https://dx.doi.org/10.1039/D1NR01936H]

35. Jing, X.; Guo, Z. Biomimetic super durable and stable surfaces with superhydrophobicity. J. Mater. Chem. A; 2018; 6, pp. 16731-16768. [DOI: https://dx.doi.org/10.1039/C8TA04994G]

36. Kocaefe, D.; Huang, X.; Kocaefe, Y. Dimensional stabilization of wood. Curr. For. Rep.; 2015; 1, pp. 151-161. [DOI: https://dx.doi.org/10.1007/s40725-015-0017-5]

37. Nikolic, M.; Lawther, J.M.; Sanadi, A.R. Use of nanofillers in wood coatings: A scientific review. J. Coat. Technol. Res.; 2015; 12, pp. 445-461. [DOI: https://dx.doi.org/10.1007/s11998-015-9659-2]

38. Liu, F.; Wang, C. Research progress and preparation methods of biomimetic functional superhydrophobic wood surfaces. Sci. Technol. Rev.; 2016; 34, pp. 120-126.

39. Blanchet, P.; Pepin, S. Trends in chemical wood surface improvements and modifications: A review of the last five years. Coatings; 2021; 11, 1514. [DOI: https://dx.doi.org/10.3390/coatings11121514]

40. Wang, Q.; Sun, G.; Tong, Q.; Yang, W.; Hao, W. Fluorine-free superhydrophobic coatings from polydimethylsiloxane for sustainable chemical engineering: Preparation methods and applications. Chem. Eng. J.; 2021; 426, 130829. [DOI: https://dx.doi.org/10.1016/j.cej.2021.130829]

41. Saji, V.S. Wax-based artificial superhydrophobic surfaces and coatings. Colloids Surf. A; 2020; 602, 125132. [DOI: https://dx.doi.org/10.1016/j.colsurfa.2020.125132]

42. Liu, M.; Wu, Y.; Qing, Y.; Tian, C.; Jia, S.; Luo, S.; Li, X. Progress in the research of functional modification on bionic fabrication of superhydrophobic wood. J. Funct. Mater.; 2015; 46, pp. 14012-14018.

43. Li, X.; Gao, L.; Wang, M.; Lv, D.; He, P.; Xie, Y.; Zhan, X.; Li, J.; Lin, Z. Recent development and emerging applications of robust biomimetic superhydrophobic wood. J. Mater. Chem. A; 2023; 11, pp. 6772-6795. [DOI: https://dx.doi.org/10.1039/D2TA09828H]

44. Ramesh, M.; Rajeshkumar, L.; Sasikala, G.; Balaji, D.; Saravanakumar, A.; Bhuvaneswari, V.; Bhoopathi, R. A critical review on wood-based polymer composites: Processing, properties, and prospects. Polymers; 2022; 14, 589. [DOI: https://dx.doi.org/10.3390/polym14030589] [PubMed: https://www.ncbi.nlm.nih.gov/pubmed/35160578]

45. Wei, X.; Niu, X. Recent advances in superhydrophobic surfaces and applications on wood. Polymers; 2023; 15, 1682. [DOI: https://dx.doi.org/10.3390/polym15071682]

46. He, Z.; Zhuo, Y.; Zhang, Z.; He, J. Design of icephobic surfaces by lowering ice adhesion strength: A mini review. Coatings; 2021; 11, 1343. [DOI: https://dx.doi.org/10.3390/coatings11111343]

47. El-Naggar, M.E.; Ullah, S.; Wageh, S.; Abu-Saied, M.A.; Khattab, T.A.; Alhashmialameer, D.; Abou Taleb, M.; Matter, E.A. Preparation of epoxy resin/rare earth doped aluminate nanocomposite toward photoluminescent and superhydrophobic transparent woods. J. Rare Earths; 2023; 41, pp. 397-405. [DOI: https://dx.doi.org/10.1016/j.jre.2022.04.018]

48. Xing, Y.; Xue, Y.; Song, J.; Sun, Y.; Huang, L.; Liu, X.; Sun, J. Superhydrophobic coatings on wood substrate for self-cleaning and EMI shielding. Appl. Surf. Sci.; 2018; 436, pp. 865-872. [DOI: https://dx.doi.org/10.1016/j.apsusc.2017.12.083]

49. Huang, W.; Li, H.; Zheng, L.; Lai, X.; Guan, H.; Wei, Y.; Feng, H.; Zeng, X. Superhydrophobic and high-performance wood-based piezoresistive pressure sensors for detecting human motions. Chem. Eng. J.; 2021; 426, 130837. [DOI: https://dx.doi.org/10.1016/j.cej.2021.130837]

50. Cai, P.; Bai, N.; Xu, L.; Tan, C.; Li, Q. Fabrication of superhydrophobic wood surface with enhanced environmental adaptability through a solution-immersion process. Surf. Coat. Technol.; 2015; 277, pp. 262-269. [DOI: https://dx.doi.org/10.1016/j.surfcoat.2015.07.060]

51. Liu, C.; Wang, S.; Shi, J.; Wang, C. Fabrication of superhydrophobic wood surfaces via a solution-immersion process. Appl. Surf. Sci.; 2011; 258, pp. 761-765. [DOI: https://dx.doi.org/10.1016/j.apsusc.2011.08.077]

52. Yue, D.; Lin, S.; Cao, M.; Lin, W.; Zhang, X. Fabrication of transparent and durable superhydrophobic polysiloxane/SiO₂ coating on the wood surface. Cellulose; 2021; 28, pp. 3745-3758. [DOI: https://dx.doi.org/10.1007/s10570-021-03758-1]

53. Pandit, S.K.; Tudu, B.K.; Mishra, I.M.; Kumar, A. Development of stain resistant, superhydrophobic and self-cleaning coating on wood surface. Prog. Org. Coat.; 2020; 139, 105453. [DOI: https://dx.doi.org/10.1016/j.porgcoat.2019.105453]

54. Kang, F.; Yi, Z.; Zhao, B.; Qin, Z. Surface physical structure and durability of superhydrophobic wood surface with epoxy resin. BioResources; 2021; 16, pp. 3235-3254. [DOI: https://dx.doi.org/10.15376/biores.16.2.3235-3254]

55. Xia, S.; Cheng, R.; Zhan, K.; Lu, Q.; Jiang, H.; Yi, T.; Morrell, J.J.; Zhang, L.; Du, G.; Gao, W. Superhydrophobic STA@PF@Cu₂O modified wood with photocatalytic degradation properties for efficiency oil/water separation. J. Environ. Chem. Eng.; 2021; 9, 106857. [DOI: https://dx.doi.org/10.1016/j.jece.2021.106857]

56. Yang, J.; Li, H.; Yi, Z.; Liao, M.; Qin, Z. Stable superhydrophobic wood surface constracting by KH580 and nano-Al2O3 on polydopamine coating with two process methods. Colloids Surf. A; 2022; 637, 128219. [DOI: https://dx.doi.org/10.1016/j.colsurfa.2021.128219]

57. Gao, Z.; Zhai, X.; Wang, C. Facile transformation of superhydrophobicity to hydrophilicity by silica/poly(ɛ-caprolactone) composite film. Appl. Surf. Sci.; 2015; 359, pp. 209-214. [DOI: https://dx.doi.org/10.1016/j.apsusc.2015.09.246]

58. Jia, S.; Deng, S.; Luo, S.; Qing, Y.; Yan, N.; Wu, Y. Texturing commercial epoxy with hierarchical and porous structure for robust superhydrophobic coatings. Appl. Surf. Sci.; 2019; 466, pp. 84-91. [DOI: https://dx.doi.org/10.1016/j.apsusc.2018.10.017]

59. Wu, Y.; Jia, S.; Qing, Y.; Luo, S.; Liu, M. A versatile and efficient method to fabricate durable superhydrophobic surfaces on wood, lignocellulosic fiber, glass, and metal substrates. J. Mater. Chem. A; 2016; 4, pp. 14111-14121. [DOI: https://dx.doi.org/10.1039/C6TA05259B]

60. Chu, Z.; Seeger, S. Robust superhydrophobic wood obtained by spraying silicone nanoparticles. RSC Adv.; 2015; 5, pp. 21999-22004. [DOI: https://dx.doi.org/10.1039/C4RA13794A]

61. Li, Y.-T.; Chen, H.; Deng, R.; Wu, M.-B.; Yang, H.-C.; Darling, S.B. Sandwich-structured photothermal wood for durable moisture harvesting and pumping. ACS Appl. Mater. Interfaces; 2021; 13, pp. 33713-33721. [DOI: https://dx.doi.org/10.1021/acsami.1c08901] [PubMed: https://www.ncbi.nlm.nih.gov/pubmed/34232009]

62. Arminger, B.; Gindl-Altmutter, W.; Hansmann, C. Efficient recovery of superhydrophobic wax surfaces on solid wood. Eur. J. Wood Wood Prod.; 2022; 80, pp. 345-353. [DOI: https://dx.doi.org/10.1007/s00107-022-01793-8]

63. Zhang, Z.; Ren, C.; Sun, Y.; Miao, Y.; Deng, L.; Wang, Z.; Cao, Y.; Zhang, W.; Huang, J. Construction of CNC@SiO₂@PL based superhydrophobic wood with excellent abrasion resistance based on nanoindentation analysis and good UV resistance. Polymers; 2023; 15, 933. [DOI: https://dx.doi.org/10.3390/polym15040933] [PubMed: https://www.ncbi.nlm.nih.gov/pubmed/36850214]

64. Huang, J.; Wang, S.; Lyu, S.; Fu, F. Preparation of a robust cellulose nanocrystal superhydrophobic coating for self-cleaning and oil-water separation only by spraying. Ind. Crops Prod.; 2018; 122, pp. 438-447. [DOI: https://dx.doi.org/10.1016/j.indcrop.2018.06.015]

65. Xue, F.; Shi, X.; Bai, W.; Li, J.e.; Li, Y.; Zhu, S.; Liu, Y.; Feng, L. Enhanced durability and versatile superhydrophobic coatings via facile one-step spraying technique. Colloids Surf. A; 2022; 640, 128411. [DOI: https://dx.doi.org/10.1016/j.colsurfa.2022.128411]

66. Li, X.; Li, B.; Li, Y.; Sun, J. Nonfluorinated, transparent, and spontaneous self-healing superhydrophobic coatings enabled by supramolecular polymers. Chem. Eng. J.; 2021; 404, 126504. [DOI: https://dx.doi.org/10.1016/j.cej.2020.126504]

67. Kong, L.; Kong, X.; Ji, Z.; Wang, X.; Zhang, X. Large-scale fabrication of a robust superhydrophobic thermal energy storage sprayable coating based on polymer nanotubes. ACS Appl. Mater. Interfaces; 2020; 12, pp. 49694-49704. [DOI: https://dx.doi.org/10.1021/acsami.0c15531]

68. Arminger, B.; Gindl-Altmutter, W.; Keckes, J.; Hansmann, C. Facile preparation of superhydrophobic wood surfaces via spraying of aqueous alkyl ketene dimer dispersions. RSC Adv.; 2019; 9, pp. 24357-24367. [DOI: https://dx.doi.org/10.1039/C9RA03700D]

69. Zhan, K.; Xia, S.; Lu, Q.; Cheng, R.; Jiang, H.; Yi, T.; Morrell, J.; Yang, L.; Xie, L.; Lei, H. et al. Superhydrophobic wood surface fabricated by Cu₂O nano-particles and stearic acid: Its acid/alkali and wear resistance. Holzforschung; 2021; 75, pp. 917-931. [DOI: https://dx.doi.org/10.1515/hf-2020-0219]

70. Tu, K.; Wang, X.; Kong, L.; Guan, H. Facile preparation of mechanically durable, self-healing and multifunctional superhydrophobic surfaces on solid wood. Mater. Des.; 2018; 140, pp. 30-36. [DOI: https://dx.doi.org/10.1016/j.matdes.2017.11.029]

71. Che, W.; Zhou, L.; Zhou, Q.; Xie, Y.; Wang, Y. Flexible Janus wood membrane with asymmetric wettability for high-efficient switchable oil/water emulsion separation. J. Colloid Interface Sci.; 2023; 629, pp. 719-727. [DOI: https://dx.doi.org/10.1016/j.jcis.2022.09.109] [PubMed: https://www.ncbi.nlm.nih.gov/pubmed/36183650]

72. Huang, J.; Lyu, S.; Chen, Z.; Wang, S.; Fu, F. A facile method for fabricating robust cellulose nanocrystal/SiO₂ superhydrophobic coatings. J. Colloid Interface Sci.; 2019; 536, pp. 349-362. [DOI: https://dx.doi.org/10.1016/j.jcis.2018.10.045] [PubMed: https://www.ncbi.nlm.nih.gov/pubmed/30380434]

73. Yang, R.; Zuo, S.; Song, B.; Mao, H.; Huang, Z.; Wu, Y.; Cai, L.; Ge, S.; Lian, H.; Xia, C. Hollow mesoporous microspheres coating for super-hydrophobicity wood with high thermostability and abrasion performance. Polymers; 2020; 12, 2856. [DOI: https://dx.doi.org/10.3390/polym12122856] [PubMed: https://www.ncbi.nlm.nih.gov/pubmed/33260485]

74. Tuong, V.M.; Huyen, N.V.; Kien, N.T.; Dien, N.V. Durable epoxy@ZnO coating for improvement of hydrophobicity and color stability of wood. Polymers; 2019; 11, 1388. [DOI: https://dx.doi.org/10.3390/polym11091388] [PubMed: https://www.ncbi.nlm.nih.gov/pubmed/31450769]

75. Shang, Q.; Chen, J.; Liu, C.; Hu, Y.; Hu, L.; Yang, X.; Zhou, Y. Facile fabrication of environmentally friendly bio-based superhydrophobic surfaces via UV-polymerization for self-cleaning and high efficient oil/water separation. Prog. Org. Coat.; 2019; 137, 105346. [DOI: https://dx.doi.org/10.1016/j.porgcoat.2019.105346]

76. Huang, J.; Lyu, S.; Fu, F.; Chang, H.; Wang, S. Preparation of superhydrophobic coating with excellent abrasion resistance and durability using nanofibrillated cellulose. RSC Adv.; 2016; 6, pp. 106194-106200. [DOI: https://dx.doi.org/10.1039/C6RA23447J]

77. Li, M.; Huang, W.; Ren, C.; Wu, Q.; Wang, S.; Huang, J. Preparation of lignin nanospheres based superhydrophobic surfaces with good robustness and long UV resistance. RSC Adv.; 2022; 12, pp. 11517-11525. [DOI: https://dx.doi.org/10.1039/D2RA01245F]

78. Gao, L.; Gan, W.; Xiao, S.; Zhan, X.; Li, J. A robust superhydrophobic antibacterial Ag–TiO₂ composite film immobilized on wood substrate for photodegradation of phenol under visible-light illumination. Ceram. Int.; 2016; 42, pp. 2170-2179. [DOI: https://dx.doi.org/10.1016/j.ceramint.2015.10.002]

79. Wang, H.; Yao, Q.; Wang, C.; Fan, B.; Sun, Q.; Jin, C.; Xiong, Y.; Chen, Y. A simple, one-step hydrothermal approach to durable and robust superparamagnetic, superhydrophobic and electromagnetic wave-absorbing wood. Sci. Rep.; 2016; 6, 35549. [DOI: https://dx.doi.org/10.1038/srep35549]

80. Tan, Y.; Wang, K.; Dong, Y.; Zhang, W.; Zhang, S.; Li, J. Bulk superhydrophobility of wood via in-situ deposition of ZnO rods in wood structure. Surf. Coat. Technol.; 2020; 383, 125240. [DOI: https://dx.doi.org/10.1016/j.surfcoat.2019.125240]

81. Sun, Q.F.; Lu, Y.; Li, J.; Cao, J. Self-assembly of a superhydrophobic ZnO nanorod arrays film on wood surface using a hydrothermal method. Key Eng. Mater.; 2014; 609–610, pp. 468-471. [DOI: https://dx.doi.org/10.4028/www.scientific.net/KEM.609-610.468]

82. Sun, Q.; Lu, Y.; Liu, Y. Growth of hydrophobic TiO₂ on wood surface using a hydrothermal method. J. Mater. Sci.; 2011; 46, pp. 7706-7712. [DOI: https://dx.doi.org/10.1007/s10853-011-5750-y]

83. Gao, L.; Lu, Y.; Cao, J.; Li, J.; Sun, Q. Reversible photocontrol of wood-surface wettability between superhydrophilicity and superhydrophobicity based on a TiO₂ film. J. Wood Chem. Technol.; 2015; 35, pp. 365-373. [DOI: https://dx.doi.org/10.1080/02773813.2014.984078]

84. Gao, L.; Lu, Y.; Zhan, X.; Li, J.; Sun, Q. A robust, anti-acid, and high-temperature–humidity-resistant superhydrophobic surface of wood based on a modified TiO₂ film by fluoroalkyl silane. Surf. Coat. Technol.; 2015; 262, pp. 33-39. [DOI: https://dx.doi.org/10.1016/j.surfcoat.2014.12.005]

85. Hui, B.; Li, G.; Li, J.; Via, B.K. Hydrothermal deposition and photoresponsive properties of WO₃ thin films on wood surfaces using ethanol as an assistant agent. J. Taiwan Inst. Chem. E; 2016; 64, pp. 336-342. [DOI: https://dx.doi.org/10.1016/j.jtice.2016.04.031]

86. Hui, B.; Wu, D.; Huang, Q.; Cai, L.; Li, G.; Li, J.; Zhao, G. Photoresponsive and wetting performances of sheet-like nanostructures of tungsten trioxide thin films grown on wood surfaces. RSC Adv.; 2015; 5, pp. 73566-73574. [DOI: https://dx.doi.org/10.1039/C5RA10479C]

87. Lu, Q.; Cheng, R.; Jiang, H.; Xia, S.; Zhan, K.; Yi, T.; Morrell, J.J.; Yang, L.; Wan, H.; Du, G. et al. Superhydrophobic wood fabricated by epoxy/Cu₂(OH)₃Cl NPs/stearic acid with performance of desirable self-cleaning, anti-mold, dimensional stability, mechanical and chemical durability. Colloids Surf. A; 2022; 647, 129162. [DOI: https://dx.doi.org/10.1016/j.colsurfa.2022.129162]

88. Wang, S.; Wang, C.; Liu, C.; Zhang, M.; Ma, H.; Li, J. Fabrication of superhydrophobic spherical-like α-FeOOH films on the wood surface by a hydrothermal method. Colloids Surf. A; 2012; 403, pp. 29-34. [DOI: https://dx.doi.org/10.1016/j.colsurfa.2012.03.051]

89. Gao, L.; Xiao, S.; Gan, W.; Zhan, X.; Li, J. Durable superamphiphobic wood surfaces from Cu₂O film modified with fluorinated alkyl silane. RSC Adv.; 2015; 5, pp. 98203-98208. [DOI: https://dx.doi.org/10.1039/C5RA19433D]

90. Qing, Y.; Liu, M.; Wu, Y.; Jia, S.; Wang, S.; Li, X. Investigation on stability and moisture absorption of superhydrophobic wood under alternating humidity and temperature conditions. Results Phys.; 2017; 7, pp. 1705-1711. [DOI: https://dx.doi.org/10.1016/j.rinp.2017.05.002]

91. Chang, H.; Tu, K.; Wang, X.; Liu, J. Fabrication of mechanically durable superhydrophobic wood surfaces using polydimethylsiloxane and silica nanoparticles. RSC Adv.; 2015; 5, pp. 30647-30653. [DOI: https://dx.doi.org/10.1039/C5RA03070F]

92. Shah, S.M.; Zulfiqar, U.; Hussain, S.Z.; Ahmad, I.; Habib, R.; Hussain, I.; Subhani, T. A durable superhydrophobic coating for the protection of wood materials. Mater. Lett.; 2017; 203, pp. 17-20. [DOI: https://dx.doi.org/10.1016/j.matlet.2017.05.126]

93. Lu, Y.; Xiao, S.; Gao, R.; Li, J.; Sun, Q. Improved weathering performance and wettability of wood protected by CeO₂ coating deposited onto the surface. Holzforschung; 2014; 68, pp. 345-351. [DOI: https://dx.doi.org/10.1515/hf-2013-0119]

94. Tu, K.; Kong, L.; Wang, X.; Liu, J. Semitransparent, durable superhydrophobic polydimethylsiloxane/SiO₂ nanocomposite coatings on varnished wood. Holzforschung; 2016; 70, pp. 1039-1045. [DOI: https://dx.doi.org/10.1515/hf-2016-0024]

95. Wang, Z.; Sun, Z.; Chen, X.; Zou, W.; Jiang, X.; Sun, D.; Yu, M. Color fastness enhancement of dyed wood by Si-sol@PDMS based superhydrophobic coating. Colloids Surf. A; 2022; 651, 129701. [DOI: https://dx.doi.org/10.1016/j.colsurfa.2022.129701]

96. Yang, R.; Liang, Y.; Hong, S.; Zuo, S.; Wu, Y.; Shi, J.; Cai, L.; Li, J.; Mao, H.; Ge, S. et al. Novel low-temperature chemical vapor deposition of hydrothermal delignified wood for hydrophobic property. Polymers; 2020; 12, 1757. [DOI: https://dx.doi.org/10.3390/polym12081757]

97. Zhu, Y.; Li, H.; Huang, W.; Lai, X.; Zeng, X. Facile fabrication of superhydrophobic wood aerogel by vapor deposition method for oil-water separation. Surf. Interfaces; 2023; 37, 102746. [DOI: https://dx.doi.org/10.1016/j.surfin.2023.102746]

98. Yin, H.; Sedighi Moghaddam, M.; Tuominen, M.; Dėdinaitė, A.; Wålinder, M.; Swerin, A. Wettability performance and physicochemical properties of UV exposed superhydrophobized birch wood. Appl. Surf. Sci.; 2022; 584, 152528. [DOI: https://dx.doi.org/10.1016/j.apsusc.2022.152528]

99. Xie, L.; Tang, Z.; Jiang, L.; Breedveld, V.; Hess, D.W. Creation of superhydrophobic wood surfaces by plasma etching and thin-film deposition. Surf. Coat. Technol.; 2015; 281, pp. 125-132. [DOI: https://dx.doi.org/10.1016/j.surfcoat.2015.09.052]

100. Seo, K.; Kim, M.; Kim, D.H. Candle-based process for creating a stable superhydrophobic surface. Carbon; 2014; 68, pp. 583-596. [DOI: https://dx.doi.org/10.1016/j.carbon.2013.11.038]

101. Zhang, X.; Xiao, F.; Feng, Q.; Zheng, J.; Chen, C.; Chen, H.; Yang, W. Preparation of SiO₂ nanoparticles with adjustable size for fabrication of SiO₂/PMHS ORMOSIL superhydrophobic surface on cellulose-based substrates. Prog. Org. Coat.; 2020; 138, 105384. [DOI: https://dx.doi.org/10.1016/j.porgcoat.2019.105384]

102. Tan, X.; Zang, D.; Qi, H.; Liu, F.; Cao, G.; Ho, S.-H. Fabrication of green superhydrophobic/superoleophilic wood flour for efficient oil separation from water. Processes; 2019; 7, 414. [DOI: https://dx.doi.org/10.3390/pr7070414]

103. Bao, W.; Zhang, M.; Jia, Z.; Jiao, Y.; Cai, L.; Liang, D.; Li, J. Cu thin films on wood surface for robust superhydrophobicity by magnetron sputtering treatment with perfluorocarboxylic acid. Eur. J. Wood Wood Prod.; 2019; 77, pp. 115-123. [DOI: https://dx.doi.org/10.1007/s00107-018-1366-0]

104. Xing, T.; Dong, C.; Wang, X.; Hu, X.; Liu, C.; Lv, H. Biodegradable, superhydrophobic walnut wood membrane for the separation of oil/water mixtures. Front. Chem. Sci. Eng.; 2022; 16, pp. 1377-1386. [DOI: https://dx.doi.org/10.1007/s11705-022-2157-z]

105. Chang, H.; Tu, K.; Wang, X.; Liu, J. Facile preparation of stable superhydrophobic coatings on wood surfaces using silica-polymer nanocomposites. BioResources; 2015; 10, pp. 2585-2596. [DOI: https://dx.doi.org/10.15376/biores.10.2.2585-2596]

106. Wang, S.; Liu, C.; Liu, G.; Zhang, M.; Li, J.; Wang, C. Fabrication of superhydrophobic wood surface by a sol–gel process. Appl. Surf. Sci.; 2011; 258, pp. 806-810. [DOI: https://dx.doi.org/10.1016/j.apsusc.2011.08.100]

107. Li, Y.; Xiong, Z.; Zhang, M.; He, Y.; Yang, Y.; Liao, Y.; Hu, J.; Wang, M.; Wu, G. Development of highly durable superhydrophobic and UV-resistant wood by E-beam radiation curing. Cellulose; 2021; 28, pp. 11579-11593. [DOI: https://dx.doi.org/10.1007/s10570-021-04266-y]

108. Tsvetkova, I.N.; Krasil’nikova, L.N.; Khoroshavina, Y.V.; Galushko, A.S.; Frantsuzova Yu, V.; Kychkin, A.K.; Shilova, O.A. Sol-gel preparation of protective and decorative coatings on wood. J. Sol-Gel Sci. Technol.; 2019; 92, pp. 474-483. [DOI: https://dx.doi.org/10.1007/s10971-019-04996-3]

109. Wang, X.; Chai, Y.; Liu, J. Formation of highly hydrophobic wood surfaces using silica nanoparticles modified with long-chain alkylsilane. Holzforschung; 2013; 67, pp. 667-672. [DOI: https://dx.doi.org/10.1515/hf-2012-0153]

110. Xia, M.; Yang, T.; Chen, S.; Yuan, G. Fabrication of superhydrophobic Eucalyptus wood surface with self-cleaning performance in air and oil environment and high durability. Colloid Interfac. Sci.; 2020; 36, 100264. [DOI: https://dx.doi.org/10.1016/j.colcom.2020.100264]

111. Shupe, T.; Piao, C.; Lucas, C. The termiticidal properties of superhydrophobic wood surfaces treated with ZnO nanorods. Eur. J. Wood Wood Prod.; 2012; 70, pp. 531-535. [DOI: https://dx.doi.org/10.1007/s00107-011-0563-x]

112. Wang, K.; Wang, Z.; Dong, Y.; Zhang, S.; Li, J. Coordination-driven controlled assembly of polyphenol-metal green coating on wood micro-grooved surfaces: A novel approach to stable superhydrophobicity. Polymers; 2017; 9, 347. [DOI: https://dx.doi.org/10.3390/polym9080347] [PubMed: https://www.ncbi.nlm.nih.gov/pubmed/30971024]

113. Lu, Q.; Hu, Y. The superhydrophobicity of LbL assembly of SiO₂/wood composite materials and the formation mechanism. J. Funct. Mater.; 2016; 47, pp. 7109-7113.

114. Lu, X.; Hu, Y. Layer-by-layer deposition of TiO₂ nanoparticles in the wood surface and its superhydrophobic performance. BioResources; 2016; 11, pp. 4605-4620. [DOI: https://dx.doi.org/10.15376/biores.11.2.4605-4620]

115. David, M.E.; Ion, R.-M.; Andrei, R.; Grigorescu, R.; Iancu, L.; Filipescu, M. Superhydrophobic coatings based on cellulose acetate for pinewood preservation. J. Sci. Arts; 2020; 1, pp. 171-182.

116. Wu, Y.; Jia, S.; Wang, S.; Qing, Y.; Yan, N.; Wang, Q.; Meng, T. A facile and novel emulsion for efficient and convenient fabrication of durable superhydrophobic materials. Chem. Eng. J.; 2017; 328, pp. 186-196. [DOI: https://dx.doi.org/10.1016/j.cej.2017.07.023]

117. Liu, F.; Wang, S.; Zhang, M.; Ma, M.; Wang, C.; Li, J. Improvement of mechanical robustness of the superhydrophobic wood surface by coating PVA/SiO₂ composite polymer. Appl. Surf. Sci.; 2013; 280, pp. 686-692. [DOI: https://dx.doi.org/10.1016/j.apsusc.2013.05.043]

118. Yu, N.; Xiao, X.; Ye, Z.; Pan, G. Facile preparation of durable superhydrophobic coating with self-cleaning property. Surf. Coat. Technol.; 2018; 347, pp. 199-208. [DOI: https://dx.doi.org/10.1016/j.surfcoat.2018.04.088]

119. Wang, Y.; Tang, Z.; Lu, S.; Zhang, M.; Liu, K.; Xiao, H.; Huang, L.; Chen, L.; Wu, H.; Ni, Y. Superhydrophobic wood grafted by poly(2-(perfluorooctyl)ethyl methacrylate) via ATRP with self-cleaning, abrasion resistance and anti-mold properties. Holzforschung; 2020; 74, pp. 799-809. [DOI: https://dx.doi.org/10.1515/hf-2019-0184]

120. Wang, K.; Dong, Y.; Yan, Y.; Qi, C.; Zhang, S.; Li, J. Preparation of mechanical abrasion and corrosion resistant bulk highly hydrophobic material based on 3-D wood template. RSC Adv.; 2016; 6, pp. 98248-98256. [DOI: https://dx.doi.org/10.1039/C6RA19549K]

121. Shen, Y.; Wu, Y.; Shen, Z.; Chen, H. Fabrication of self-healing superhydrophobic surfaces from water-soluble polymer suspensions free of inorganic particles through polymer thermal reconstruction. Coatings; 2018; 8, 144. [DOI: https://dx.doi.org/10.3390/coatings8040144]

122. Wang, J.; Lu, Y.; Chu, Q.; Ma, C.; Cai, L.; Shen, Z.; Chen, H. Facile construction of superhydrophobic surfaces by coating fluoroalkylsilane/silica composite on a modified hierarchical structure of wood. Polymers; 2020; 12, 813. [DOI: https://dx.doi.org/10.3390/polym12040813] [PubMed: https://www.ncbi.nlm.nih.gov/pubmed/32260345]

123. Bai, X.; Shen, Y.; Tian, H.; Yang, Y.; Feng, H.; Li, J. Facile fabrication of superhydrophobic wood slice for effective water-in-oil emulsion separation. Sep. Purif. Technol.; 2019; 210, pp. 402-408. [DOI: https://dx.doi.org/10.1016/j.seppur.2018.08.010]

124. Yang, M.; Chen, X.; Lin, H.; Han, C.; Zhang, S. A simple fabrication of superhydrophobic wood surface by natural rosin based compound via impregnation at room temperature. Eur. J. Wood Wood Prod.; 2018; 76, pp. 1417-1425. [DOI: https://dx.doi.org/10.1007/s00107-018-1319-7]

125. Liu, Z.; Cao, J. Fabrication of superhydrophobic wood surface with a silica/silicone oil complex emulsion. Wood Res.; 2018; 63, pp. 353-364.

126. Kolyaganova, O.; Klimov, V.V.; Bryuzgin, E.V.; Le, M.D.; Kharlamov, V.O.; Bryuzgina, E.B.; Navrotsky, A.V.; Novakov, I.A. Modification of wood with copolymers based on glycidyl methacrylate and alkyl methacrylates for imparting superhydrophobic properties. J. Appl. Polym. Sci.; 2022; 139, 51636. [DOI: https://dx.doi.org/10.1002/app.51636]

127. Lu, Q.; Jiang, H.; Cheng, R.; Xia, S.; Zhan, K.; Yi, T.; Morrell, J.J.; Yang, L.; Du, G.; Gao, W. Preparation of superhydrophobic wood surfaces via in-situ synthesis of Cu₂(OH)₃Cl nano-flowers and impregnating PF&STA to improve chemical and mechanical durability. Ind. Crops Prod.; 2021; 172, 113952.

128. Cai, Y.; Yu, Y.; Wu, J.; Wang, K.; Dong, Y.; Qu, J.; Hu, J.; Zhang, L.; Fu, Q.; Li, J. et al. Durable, flexible, and super-hydrophobic wood membrane with nanopore by molecular cross-linking for efficient separation of stabilized water/oil emulsions. EcoMat; 2022; 4, e12255. [DOI: https://dx.doi.org/10.1002/eom2.12255]

129. Jia, S.; Chen, H.; Luo, S.; Qing, Y.; Deng, S.; Yan, N.; Wu, Y. One-step approach to prepare superhydrophobic wood with enhanced mechanical and chemical durability: Driving of alkali. Appl. Surf. Sci.; 2018; 455, pp. 115-122. [DOI: https://dx.doi.org/10.1016/j.apsusc.2018.05.169]

130. Chen, Y.; Wang, H.; Yao, Q.; Fan, B.; Wang, C.; Xiong, Y.; Jin, C.; Sun, Q. Biomimetic taro leaf-like films decorated on wood surfaces using soft lithography for superparamagnetic and superhydrophobic performance. J. Mater. Sci.; 2017; 52, pp. 7428-7438. [DOI: https://dx.doi.org/10.1007/s10853-017-0976-y]

131. Yang, Y.; He, H.; Li, Y.; Qiu, J. Using nanoimprint lithography to create robust, buoyant, superhydrophobic PVB/SiO₂ coatings on wood surfaces inspired by red roses petal. Sci. Rep.; 2019; 9, 9961. [DOI: https://dx.doi.org/10.1038/s41598-019-46337-y] [PubMed: https://www.ncbi.nlm.nih.gov/pubmed/31292503]

132. Yang, Y.; Shen, H.; Qiu, J. Fabrication of biomimetic robust self-cleaning superhydrophobic wood with canna-leaf-like micro/nanostructure through morph-genetic method improved water-, UV-, and corrosion resistance properties. J. Mol. Struct.; 2020; 1219, 128616. [DOI: https://dx.doi.org/10.1016/j.molstruc.2020.128616]

133. Jia, S.; Lu, X.; Luo, S.; Qing, Y.; Yan, N.; Wu, Y. Efficiently texturing hierarchical epoxy layer for smart superhydrophobic surfaces with excellent durability and exceptional stability exposed to fire. Chem. Eng. J.; 2018; 348, pp. 212-223. [DOI: https://dx.doi.org/10.1016/j.cej.2018.04.195]

134. Zhao, Y.; Qu, D.; Yu, T.; Xie, X.; He, C.; Ge, D.; Yang, L. Frost-resistant high-performance wood via synergetic building of omni-surface hydrophobicity. Chem. Eng. J.; 2020; 385, 123860. [DOI: https://dx.doi.org/10.1016/j.cej.2019.123860]

135. Wang, K.; Liu, X.; Tan, Y.; Zhang, W.; Zhang, S.; Li, J. Two-dimensional membrane and three-dimensional bulk aerogel materials via top-down wood nanotechnology for multibehavioral and reusable oil/water separation. Chem. Eng. J.; 2019; 371, pp. 769-780. [DOI: https://dx.doi.org/10.1016/j.cej.2019.04.108]

136. Jian, Y.; Lu, S.; Tang, W.; Shao, M.; San, F.; Wan, H.; Xie, L. Preparation of superhydrophobic coatings with alkyltrichlorosilanes for Pinus kesiya wood. J. Wood Chem. Technol.; 2022; 42, pp. 409-418. [DOI: https://dx.doi.org/10.1080/02773813.2022.2114498]

137. El-Naggar, M.E.; Aldalbahi, A.; Khattab, T.A.; Hossain, M. Facile production of smart superhydrophobic nanocomposite for wood coating towards long-lasting glow-in-the-dark photoluminescence. Luminescence; 2021; 36, pp. 2004-2013. [DOI: https://dx.doi.org/10.1002/bio.4137]

138. Yang, R.; Cao, Q.; Liang, Y.; Hong, S.; Xia, C.; Wu, Y.; Li, J.; Cai, L.; Sonne, C.; Le, Q.V. et al. High capacity oil absorbent wood prepared through eco-friendly deep eutectic solvent delignification. Chem. Eng. J.; 2020; 401, 126150. [DOI: https://dx.doi.org/10.1016/j.cej.2020.126150]

139. Jia, S.; Lu, Y.; Luo, S.; Qing, Y.; Wu, Y.; Parkin, I.P. Thermally-induced all-damage-healable superhydrophobic surface with photocatalytic performance from hierarchical BiOCl. Chem. Eng. J.; 2019; 366, pp. 439-448. [DOI: https://dx.doi.org/10.1016/j.cej.2019.02.104]

140. Si, Y.; Guo, Z. Superhydrophobic nanocoatings: From materials to fabrications and to applications. Nanoscale; 2015; 7, pp. 5922-5946. [DOI: https://dx.doi.org/10.1039/C4NR07554D]

141. Zhu, R.; Liu, M.; Hou, Y.; Zhang, L.; Li, M.; Wang, D.; Fu, S. One-pot preparation of fluorine-free magnetic superhydrophobic particles for controllable liquid marbles and robust multifunctional coatings. ACS Appl. Mater. Interfaces; 2020; 12, pp. 17004-17017. [DOI: https://dx.doi.org/10.1021/acsami.9b22268]

142. Tang, X.; Huang, W.; Xie, Y.; Xiao, Z.; Wang, H.; Liang, D.; Li, J.; Wang, Y. Superhydrophobic hierarchical structures from self-assembly of cellulose-based nanoparticles. ACS Sustain. Chem. Eng.; 2021; 9, pp. 14101-14111. [DOI: https://dx.doi.org/10.1021/acssuschemeng.1c03876]

143. Zhang, K.; Xu, F.; Gao, Y. Superhydrophobic and oleophobic dual-function coating with durablity and self-healing property based on a waterborne solution. Appl. Mater. Today; 2021; 22, 100970. [DOI: https://dx.doi.org/10.1016/j.apmt.2021.100970]

144. Yu, X.; Liu, X.; Shi, X.; Zhang, Z.; Wang, H.; Feng, L. SiO₂ nanoparticle-based superhydrophobic spray and multi-functional surfaces by a facile and scalable method. Ceram. Int.; 2019; 45, pp. 15741-15744. [DOI: https://dx.doi.org/10.1016/j.ceramint.2019.05.014]

145. Latthe, S.S.; Sutar, R.S.; Kodag, V.S.; Bhosale, A.K.; Kumar, A.M.; Kumar Sadasivuni, K.; Xing, R.; Liu, S. Self-cleaning superhydrophobic coatings: Potential industrial applications. Prog. Org. Coat.; 2019; 128, pp. 52-58. [DOI: https://dx.doi.org/10.1016/j.porgcoat.2018.12.008]

146. Ghasemlou, M.; Daver, F.; Ivanova, E.P.; Adhikari, B. Bio-inspired sustainable and durable superhydrophobic materials: From nature to market. J. Mater. Chem. A; 2019; 7, pp. 16643-16670. [DOI: https://dx.doi.org/10.1039/C9TA05185F]

147. Yang, H.; Wang, S.; Wang, X.; Chao, W.; Wang, N.; Ding, X.; Liu, F.; Yu, Q.; Yang, T.; Yang, Z. et al. Wood-based composite phase change materials with self-cleaning superhydrophobic surface for thermal energy storage. Appl. Energy; 2020; 261, 114481. [DOI: https://dx.doi.org/10.1016/j.apenergy.2019.114481]

148. Ntelia, E.; Karapanagiotis, I. Superhydrophobic Paraloid B72. Prog. Org. Coat.; 2020; 139, 105224. [DOI: https://dx.doi.org/10.1016/j.porgcoat.2019.105224]

149. Moghaddam, M.S.; Heydari, G.; Tuominen, M.; Fielden, M.; Haapanen, J.; Mäkelä, J.M.; Wålinder, M.E.P.; Claesson, P.M.; Swerin, A. Hydrophobisation of wood surfaces by combining liquid flame spray (LFS) and plasma treatment: Dynamic wetting properties. Holzforschung; 2016; 70, pp. 527-537. [DOI: https://dx.doi.org/10.1515/hf-2015-0148]

150. Huang, J.; Lyu, S.; Fu, F.; Wu, Y.; Wang, S. Green preparation of a cellulose nanocrystals/polyvinyl alcohol composite superhydrophobic coating. RSC Adv.; 2017; 7, pp. 20152-20159. [DOI: https://dx.doi.org/10.1039/C6RA27663F]

151. Chen, J.; Zhu, Z.; Zhang, H.; Fu, S. Superhydrophobic light-driven actuator based on self-densified wood film with a sandwich-like structure. Compos. Sci. Technol.; 2022; 220, 109278. [DOI: https://dx.doi.org/10.1016/j.compscitech.2022.109278]

152. Jnido, G.; Ohms, G.; Viöl, W. One-step deposition of polyester/TiO₂ coatings by atmospheric pressure plasma jet on wood surfaces for UV and moisture protection. Coatings; 2020; 10, 184. [DOI: https://dx.doi.org/10.3390/coatings10020184]

153. Zhan, K.; Lu, Q.; Xia, S.; Guo, C.; Zhao, S.; Gao, W.; Yang, L.; Morrell, J.J.; Yi, T.; Xie, L. et al. A cost effective strategy to fabricate STA@PF@Cu₂O hierarchical structure on wood surface: Aimed at superhydrophobic modification. Wood Sci. Technol.; 2021; 55, pp. 565-583. [DOI: https://dx.doi.org/10.1007/s00226-021-01269-7]

154. Fu, Y.; Yu, H.; Sun, Q.; Li, G.; Liu, Y. Testing of the superhydrophobicity of a zinc oxide nanorod array coating on wood surface prepared by hydrothermal treatment. Holzforschung; 2012; 66, pp. 739-744. [DOI: https://dx.doi.org/10.1515/hf-2011-0261]

155. Wang, S.; Liu, C.; Du, H.; Ma, H.; Xie, C.; Wang, C. An alkaline hydrothermal method to synthesize superhydrophobic wood. Adv. Mater. Res.; 2011; 295–297, pp. 1680-1683.

156. Gan, W.; Gao, L.; Sun, Q.; Jin, C.; Lu, Y.; Li, J. Multifunctional wood materials with magnetic, superhydrophobic and anti-ultraviolet properties. Appl. Surf. Sci.; 2015; 332, pp. 565-572. [DOI: https://dx.doi.org/10.1016/j.apsusc.2015.01.206]

157. Wang, C.; Piao, C.; Lucas, C. Synthesis and characterization of superhydrophobic wood surfaces. J. Appl. Polym. Sci.; 2011; 119, pp. 1667-1672. [DOI: https://dx.doi.org/10.1002/app.32844]

158. Ding, Z.; Lin, W.; Yang, W.; Chen, H.; Zhang, X. A silicone resin coating with water-repellency and anti-fouling properties for wood protection. Polymers; 2022; 14, 3062. [DOI: https://dx.doi.org/10.3390/polym14153062]

159. Tu, K.; Wang, X.; Kong, L.; Chang, H.; Liu, J. Fabrication of robust, damage-tolerant superhydrophobic coatings on naturally micro-grooved wood surfaces. RSC Adv.; 2016; 6, pp. 701-707. [DOI: https://dx.doi.org/10.1039/C5RA24407B]

160. Janesch, J.; Arminger, B.; Gindl-Altmutter, W.; Hansmann, C. Superhydrophobic coatings on wood made of plant oil and natural wax. Prog. Org. Coat.; 2020; 148, 105891. [DOI: https://dx.doi.org/10.1016/j.porgcoat.2020.105891]

161. Łukawski, D.; Lekawa-Raus, A.; Lisiecki, F.; Koziol, K.; Dudkowiak, A. Towards the development of superhydrophobic carbon nanomaterial coatings on wood. Prog. Org. Coat.; 2018; 125, pp. 23-31. [DOI: https://dx.doi.org/10.1016/j.porgcoat.2018.08.025]

162. Chen, Z.; Su, X.; Wu, W.; Chen, S.; Zhang, X.; Wu, Y.; Xie, H.; Li, K. Superhydrophobic PDMS@TiO₂ wood for photocatalytic degradation and rapid oil-water separation. Surf. Coat. Technol.; 2022; 434, 128182. [DOI: https://dx.doi.org/10.1016/j.surfcoat.2022.128182]

163. Han, X.; Wang, Z.; Zhang, Q.; Pu, J. A simple and efficient method to fabricate superhydrophobic wood with enhanced mechanical durability. Forest; 2019; 10, 750. [DOI: https://dx.doi.org/10.3390/f10090750]

164. Guo, H.; Fuchs, P.; Casdorff, K.; Michen, B.; Chanana, M.; Hagendorfer, H.; Romanyuk, Y.E.; Burgert, I. Bio-inspired superhydrophobic and omniphobic wood surfaces. Adv. Mater. Interfaces; 2017; 4, 1600289. [DOI: https://dx.doi.org/10.1002/admi.201600289]

165. Yao, Q.; Wang, C.; Fan, B.; Wang, H.; Sun, Q.; Jin, C.; Zhang, H. One-step solvothermal deposition of ZnO nanorod arrays on a wood surface for robust superamphiphobic performance and superior ultraviolet resistance. Sci. Rep.; 2016; 6, 35505. [DOI: https://dx.doi.org/10.1038/srep35505] [PubMed: https://www.ncbi.nlm.nih.gov/pubmed/27775091]

166. Wang, K.; Dong, Y.; Zhang, W.; Zhang, S.; Li, J. Preparation of stable superhydrophobic coatings on wood substrate surfaces via mussel-inspired polydopamine and electroless deposition methods. Polymers; 2017; 9, 218. [DOI: https://dx.doi.org/10.3390/polym9060218] [PubMed: https://www.ncbi.nlm.nih.gov/pubmed/30970897]

167. Deng, S.; Jia, S.; Deng, X.; Qing, Y.; Luo, S.; Wu, Y. New insight into island-like structure driven from hydroxyl groups for high-performance superhydrophobic surfaces. Chem. Eng. J.; 2021; 416, 129078. [DOI: https://dx.doi.org/10.1016/j.cej.2021.129078]

168. Gao, L.; Lu, Y.; Li, J.; Sun, Q. Superhydrophobic conductive wood with oil repellency obtained by coating with silver nanoparticles modified by fluoroalkyl silane. Holzforschung; 2015; 70, pp. 63-68. [DOI: https://dx.doi.org/10.1515/hf-2014-0226]

169. Wang, N.; Wang, Q.; Xu, S.; Qu, L.; Shi, Z. Robust superhydrophobic wood surfaces with mechanical durability. Colloids Surf. A; 2021; 608, 125624. [DOI: https://dx.doi.org/10.1016/j.colsurfa.2020.125624]

170. Mirvakili, M.N.; Hatzikiriakos, S.G.; Englezos, P. Superhydrophobic lignocellulosic wood fiber/mineral networks. ACS Appl. Mater. Interfaces; 2013; 5, pp. 9057-9066. [DOI: https://dx.doi.org/10.1021/am402286x]

171. Wu, X.; Yang, F.; Gan, J.; Zhao, W.; Wu, Y. A flower-like waterborne coating with self-cleaning, self-repairing properties for superhydrophobic applications. J. Mater. Res. Technol.; 2021; 14, pp. 1820-1829. [DOI: https://dx.doi.org/10.1016/j.jmrt.2021.07.096]

172. Liu, F.; Gao, Z.; Zang, D.; Wang, C.; Li, J. Mechanical stability of superhydrophobic epoxy/silica coating for better water resistance of wood. Holzforschung; 2015; 69, pp. 367-374. [DOI: https://dx.doi.org/10.1515/hf-2014-0077]

173. Wang, K.; Dong, Y.; Yan, Y.; Zhang, S.; Li, J. Mussel-inspired chemistry for preparation of superhydrophobic surfaces on porous substrates. RSC Adv.; 2017; 7, pp. 29149-29158. [DOI: https://dx.doi.org/10.1039/C7RA04790H]

174. Budunoglu, H.; Yildirim, A.; Guler, M.O.; Bayindir, M. Highly transparent, flexible, and thermally stable superhydrophobic ORMOSIL aerogel thin films. ACS Appl. Mater. Interfaces; 2011; 3, pp. 539-545. [DOI: https://dx.doi.org/10.1021/am101116b]

175. Celia, E.; Darmanin, T.; Taffin de Givenchy, E.; Amigoni, S.; Guittard, F. Recent advances in designing superhydrophobic surfaces. J. Colloid Interface Sci.; 2013; 402, pp. 1-18. [DOI: https://dx.doi.org/10.1016/j.jcis.2013.03.041]

176. Wang, X.; Liu, S.; Chang, H.; Liu, J. Sol-gel deposition of TiO₂ nanocoatings on wood surfaces with enhanced hydrophobicity and photostability. Wood Fiber Sci.; 2014; 46, pp. 109-117.

177. Cao, M.; Tang, M.; Lin, W.; Ding, Z.; Cai, S.; Chen, H.; Zhang, X. Facile fabrication of fluorine-free, anti-icing, and multifunctional superhydrophobic surface on wood substrates. Polymers; 2022; 14, 1953. [DOI: https://dx.doi.org/10.3390/polym14101953]

178. Lin, W.; Zhang, X.; Cai, Q.; Yang, W.; Chen, H. Dehydrogenation-driven assembly of transparent and durable superhydrophobic ORMOSIL coatings on cellulose-based substrates. Cellulose; 2020; 27, pp. 7805-7821. [DOI: https://dx.doi.org/10.1007/s10570-020-03288-2]

179. Ma, T.; Li, L.; Mei, C.; Wang, Q.; Guo, C. Construction of sustainable, fireproof and superhydrophobic wood template for efficient oil/water separation. J. Mater. Sci.; 2021; 56, pp. 5624-5636. [DOI: https://dx.doi.org/10.1007/s10853-020-05615-1]

180. Du, X.; Li, J.S.; Li, L.X.; Levkin, P.A. Porous poly(2-octyl cyanoacrylate): A facile one-step preparation of superhydrophobic coatings on different substrates. J. Mater. Chem. A; 2013; 1, pp. 1026-1029. [DOI: https://dx.doi.org/10.1039/C2TA00934J]

181. Wang, C.; Zhang, M.; Xu, Y.; Wang, S.; Liu, F.; Ma, M.; Zang, D.; Gao, Z. One-step synthesis of unique silica particles for the fabrication of bionic and stably superhydrophobic coatings on wood surface. Adv. Powder Technol.; 2014; 25, pp. 530-535. [DOI: https://dx.doi.org/10.1016/j.apt.2013.08.007]

182. Gao, Z.; Ma, M.; Zhai, X.; Zhang, M.; Zang, D.; Wang, C. Improvement of chemical stability and durability of superhydrophobic wood surface via a film of TiO₂ coated CaCO₃ micro-/nano-composite particles. RSC Adv.; 2015; 5, pp. 63978-63984. [DOI: https://dx.doi.org/10.1039/C5RA04000K]

183. Wang, K.; Dong, Y.; Yan, Y.; Zhang, W.; Qi, C.; Han, C.; Li, J.; Zhang, S. Highly hydrophobic and self-cleaning bulk wood prepared by grafting long-chain alkyl onto wood cell walls. Wood Sci. Technol.; 2017; 51, pp. 395-411. [DOI: https://dx.doi.org/10.1007/s00226-016-0862-9]

184. Wang, S.; Shi, J.; Liu, C.; Xie, C.; Wang, C. Fabrication of a superhydrophobic surface on a wood substrate. Appl. Surf. Sci.; 2011; 257, pp. 9362-9365. [DOI: https://dx.doi.org/10.1016/j.apsusc.2011.05.089]

185. Yang, Y.; Shan, L.; Shen, H.; Qiu, J. Manufacturing of robust superhydrophobic wood surfaces based on PEG–functionalized SiO₂/PVA/PAA/fluoropolymer hybrid transparent coating. Prog. Org. Coat.; 2021; 154, 106186. [DOI: https://dx.doi.org/10.1016/j.porgcoat.2021.106186]

186. Yi, Z.; Zhao, B.; Liao, M.; Qin, Z. Fabrication of superhydrophobic wood surface by etching polydopamine coating with sodium hydroxide. Coatings; 2020; 10, 847. [DOI: https://dx.doi.org/10.3390/coatings10090847]

187. Younis, S.A.; El-Sayed, M.; Moustafa, Y.M. Modeling and optimization of oil adsorption from wastewater using an amorphous carbon thin film fabricated from wood sawdust waste modified with palmitic acid. Environ. Process.; 2017; 4, pp. 147-168. [DOI: https://dx.doi.org/10.1007/s40710-016-0202-y]

188. Zhu, Z.; Fu, S.; Lucia, L.A. A fiber-aligned thermal-managed wood-based superhydrophobic aerogel for efficient oil recovery. ACS Sustain. Chem. Eng.; 2019; 7, pp. 16428-16439. [DOI: https://dx.doi.org/10.1021/acssuschemeng.9b03544]

189. Li, Y.; Chen, C.; Song, J.; Yang, C.; Kuang, Y.; Vellore, A.; Hitz, E.; Zhu, M.; Jiang, F.; Yao, Y. et al. Strong and superhydrophobic wood with aligned cellulose nanofibers as a waterproof structural material. Chin. J. Chem.; 2020; 38, pp. 823-829. [DOI: https://dx.doi.org/10.1002/cjoc.202000032]

190. Kavalenka, M.N.; Hopf, A.; Schneider, M.; Worgull, M.; Hölscher, H. Wood-based microhaired superhydrophobic and underwater superoleophobic surfaces for oil/water separation. RSC Adv.; 2014; 4, pp. 31079-31083. [DOI: https://dx.doi.org/10.1039/C4RA04029E]

191. Raphael, W.; Martel, T.; Landry, V.; Tavares, J.R. Surface engineering of wood substrates to impart barrier properties: A photochemical approach. Wood Sci. Technol.; 2018; 52, pp. 193-207. [DOI: https://dx.doi.org/10.1007/s00226-017-0973-y]

192. Manoudis, P.N.; Karapanagiotis, I.; Tsakalof, A.; Zuburtikudis, I.; Panayiotou, C. Superhydrophobic composite films produced on various substrates. Langmuir; 2008; 24, pp. 11225-11232. [DOI: https://dx.doi.org/10.1021/la801817e] [PubMed: https://www.ncbi.nlm.nih.gov/pubmed/18720965]

193. Wu, X.; Yang, F.; Gan, J.; Kong, Z.; Wu, Y. A superhydrophobic, antibacterial, and durable surface of poplar wood. Nanomaterials; 2021; 11, 1885. [DOI: https://dx.doi.org/10.3390/nano11081885] [PubMed: https://www.ncbi.nlm.nih.gov/pubmed/34443716]

194. Zhang, L.; Zhou, A.G.; Sun, B.R.; Chen, K.S.; Yu, H.-Z. Functional and versatile superhydrophobic coatings via stoichiometric silanization. Nat. Commun.; 2021; 12, 982. [DOI: https://dx.doi.org/10.1038/s41467-021-21219-y] [PubMed: https://www.ncbi.nlm.nih.gov/pubmed/33579959]

195. Yin, H.; Moghaddam, M.S.; Tuominen, M.; Eriksson, M.; Järn, M.; Dėdinaitė, A.; Wålinder, M.; Swerin, A. Superamphiphobic plastrons on wood and their effects on liquid repellence. Mater. Des.; 2020; 195, 108974. [DOI: https://dx.doi.org/10.1016/j.matdes.2020.108974]

196. Feng, J.; Chen, J.; Chen, M.; Su, X.; Shi, Q. Effects of biocide treatments on durability of wood and bamboo/high density polyethylene composites against algal and fungal decay. J. Appl. Polym. Sci.; 2017; 134, 45148. [DOI: https://dx.doi.org/10.1002/app.45148]

197. Schultz, T.P.; Nicholas, D.D.; Preston, A.F. A brief review of the past, present and future of wood preservation. Pest Manag. Sci.; 2007; 63, pp. 784-788. [DOI: https://dx.doi.org/10.1002/ps.1386]

198. He, Z.; Wu, H.; Shi, Z.; Kong, Z.; Ma, S.; Sun, Y.; Liu, X. Facile preparation of robust superhydrophobic/superoleophilic TiO₂ decorated polyvinyl alcohol sponge for efficient oil/water separation. ACS Omega; 2022; 7, pp. 7084-7095. [DOI: https://dx.doi.org/10.1021/acsomega.1c06775]

199. He, Z.; Wu, H.; Shi, Z.; Duan, X.; Ma, S.; Chen, J.; Kong, Z.; Chen, A.; Sun, Y.; Liu, X. Mussel-inspired durable superhydrophobic/superoleophilic MOF-PU sponge with high chemical stability, efficient oil/water separation and excellent anti-icing properties. Colloids Surf. A; 2022; 648, 129142. [DOI: https://dx.doi.org/10.1016/j.colsurfa.2022.129142]

200. Fan, J.-B.; Song, Y.; Wang, S.; Meng, J.; Yang, G.; Guo, X.; Feng, L.; Jiang, L. Directly coating hydrogel on filter paper for effective oil–water separation in highly acidic, alkaline, and salty environment. Adv. Funct. Mater.; 2015; 25, pp. 5368-5375. [DOI: https://dx.doi.org/10.1002/adfm.201501066]

201. Liu, M.; Hou, Y.; Li, J.; Guo, Z. Stable superwetting meshes for on-demand separation of immiscible oil/water mixtures and emulsions. Langmuir; 2017; 33, pp. 3702-3710. [DOI: https://dx.doi.org/10.1021/acs.langmuir.7b00658] [PubMed: https://www.ncbi.nlm.nih.gov/pubmed/28345927]

202. Daksa Ejeta, D.; Wang, C.-F.; Kuo, S.-W.; Chen, J.-K.; Tsai, H.-C.; Hung, W.-S.; Hu, C.-C.; Lai, J.-Y. Preparation of superhydrophobic and superoleophilic cotton-based material for extremely high flux water-in-oil emulsion separation. Chem. Eng. J.; 2020; 402, 126289. [DOI: https://dx.doi.org/10.1016/j.cej.2020.126289]

203. Zhao, M.; Tao, Y.; Wang, J.; He, Y. Facile preparation of superhydrophobic porous wood for continuous oil-water separation. J. Water Process Eng.; 2020; 36, 101279. [DOI: https://dx.doi.org/10.1016/j.jwpe.2020.101279]

204. Wu, J.; Cui, Z.; Yu, Y.; Han, H.; Tian, D.; Hu, J.; Qu, J.; Cai, Y.; Luo, J.; Li, J. A 3D smart wood membrane with high flux and efficiency for separation of stabilized oil/water emulsions. J. Hazard. Mater.; 2023; 441, 129900. [DOI: https://dx.doi.org/10.1016/j.jhazmat.2022.129900]

205. Cheng, R.; Yang, Y.; Liu, Q.; Wang, L.; Xia, S.; Lu, Q.; Jiang, H.; Zhan, K.; Morrell, J.J.; Wan, H. et al. In-situ growth strategy to fabricate superhydrophobic wood by Na₃(Cu₂(CO₃)₃OH)∙4H₂O for oil/water separation. Colloids Surf. A; 2023; 656, 130338. [DOI: https://dx.doi.org/10.1016/j.colsurfa.2022.130338]

206. Góral, Z.; Mastalska-Popławska, J.; Izak, P.; Rutkowski, P.; Gnyla, J.; Majka, T.M.; Pielichowski, K. Impact of melamine and its derivatives on the properties of poly(vinyl acetate)-based composite wood adhesive. Eur. J. Wood Wood Prod.; 2021; 79, pp. 177-188. [DOI: https://dx.doi.org/10.1007/s00107-020-01618-6]

207. He, Z.; Xie, H.; Wu, H.; Chen, J.; Ma, S.; Duan, X.; Chen, A.; Kong, Z. Recent advances in MXene/polyaniline-based composites for electrochemical devices and electromagnetic interference shielding applications. ACS Omega; 2021; 6, pp. 22468-22477. [DOI: https://dx.doi.org/10.1021/acsomega.1c02996]

208. Wang, Z.; Sun, Z.; Sun, D.; Zou, W.; Yu, M.; Yao, L. Thermally induced response self-healing superhydrophobic wood with self-cleaning and photocatalytic performance. Cellulose; 2022; 29, pp. 9407-9420. [DOI: https://dx.doi.org/10.1007/s10570-022-04839-5]

209. He, Z.; Zhuo, Y.; Wang, F.; He, J.; Zhang, Z. Design and preparation of icephobic PDMS-based coatings by introducing an aqueous lubricating layer and macro-crack initiators at the ice-substrate interface. Prog. Org. Coat.; 2020; 147, 105737. [DOI: https://dx.doi.org/10.1016/j.porgcoat.2020.105737]

210. He, Z.; Xiao, S.; Gao, H.; He, J.; Zhang, Z. Multiscale crack initiator promoted super-low ice adhesion surfaces. Soft Matter.; 2017; 13, pp. 6562-6568. [DOI: https://dx.doi.org/10.1039/C7SM01511A]

211. He, Z.; Zhuo, Y.; He, J.; Zhang, Z. Design and preparation of sandwich-like PDMS sponges with super-low ice adhesion. Soft Matter.; 2018; 14, pp. 4846-4851. [DOI: https://dx.doi.org/10.1039/C8SM00820E] [PubMed: https://www.ncbi.nlm.nih.gov/pubmed/29845173]

212. Wu, X.H.; Zheng, S.L.; Bellido-Aguilar, D.A.; Silberschmidt, V.V.; Chen, Z. Transparent icephobic coatings using bio-based epoxy resin. Mater. Des.; 2018; 140, pp. 516-523. [DOI: https://dx.doi.org/10.1016/j.matdes.2017.12.017]

Word count: 18894

Show less

© 2023 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/). Notwithstanding the ProQuest Terms and Conditions, you may use this content in accordance with the terms of the License.

Abstract

Translate

Wood is a renewable material that has been widely utilized as indoor and outdoor construction and decoration material in our daily life. Although wood has many advantages (i.e., light weight, high strength, low price and easy machinability), it has some drawbacks that influence dimensional stability, cracking and decay resistance in real practical applications. To mitigate these issues, superhydrophobic surfaces have been introduced to wood substrates, creating superhydrophobic wood surfaces (SHWSs) that can improve stability, water resistance, ultraviolet radiation resistance and flame retardancy. Herein, the recent developments and future perspectives of SHWSs are reviewed. Firstly, the preparation methods of SHWSs are summarized and discussed in terms of immersion, spray-coating, hydrothermal synthesis, dip-coating, deposition, sol-gel process and other methods, respectively. Due to the characteristics of the above preparation methods and the special properties of wood substrates, multiple methods are suggested to be combined to prepare SHWSs rather than each individual method. Secondly, the versatile practical applications of SHWSs are introduced, including anti-fungi/anti-bacteria, oil/water separation, fire-resistance, anti-ultraviolet irradiation, electromagnetic interference shielding, photocatalytic performance, and anti-icing. When discussing these practical applications, the advantages of SHWSs and the reason why SHWSs can be used in such applications are also mentioned. Finally, we provide with perspectives and outlooks for the future developments and applications of SHWSs, expecting to extend the utilization of SHWSs in our daily life and industry.

Details

Title

Superhydrophobic Wood Surfaces: Recent Developments and Future Perspectives

Author

Gao, Xianming; Wang, Mingkun; He, Zhiwei

First page

877

Publication year

2023

Publication date

2023

Publisher

MDPI AG

e-ISSN

20796412

Source type

Scholarly Journal

Language of publication

English

DOI

https://doi.org/10.3390/coatings13050877

ProQuest document ID

2819439855

Superhydrophobic Wood Surfaces: Recent Developments and Future Perspectives

Jump to:

Full Text

Abstract

Details

Suggested sources