Abstract

Taking into account the deviation from the Condon approximation the influence of torsial mode on the nonthermal electron transfer dynamics is studied. Within the framework of the second-order time-dependent perturbation on the electronic coupling an analytical expression for probability of the nonthermal electron transfer from excited donor-acceptor systems is derived.

Details

Title
Torsial oscillator effect on the probability of nonthermal electron transfer
Author
Scherbakova Ekaterina Valerievna; Kazyanova, Margarita Vladimirovna; Mikhailova, Valentina Alexandrovna
Section
CHEMICAL PHYSICS
Publication year
2011
Publication date
Sep 2011
Publisher
Volgograd State University
ISSN
2409-1782
Source type
Scholarly Journal
Language of publication
English; Russian
ProQuest document ID
2095436983
Copyright
© 2011. This work is licensed under http://creativecommons.org/licenses/by/4.0/ (the “License”). Notwithstanding the ProQuest Terms and conditions, you may use this content in accordance with the terms of the License.